二安替比林甲烷分光光度法测定氯化镁中钛的含量

用盐酸溶解氯化镁样品,以抗坏血酸和焦磷酸钠共同作掩蔽剂,在酸性介质中用二安替比林甲烷分光光度法测定氯化镁中钛的含量,给出了合理的实验条件.     

企业逆向物流与循环经济立法之联系

逆向物流给企业带来效益的同时,也带来了生态物流的理念.逆向物流涉及了经济与生态环境两大系统,显现出了自身的特点与积极因素.逆向物流充分体现了循环经济发展之宗旨.加速循环经济的立法,并以相应立法来推动企业尽快实施物流活动是至关重要的.     

城镇供热管道隐患辨识研究

近年来,因供热管道老化腐蚀、外部自然环境、施工活动等导致的事故时有发生,给居民的冬季供暖造成了严重的危害和影响。本文在分析供热管道自身安全特性的基础上,运用事故树等系统安全分析方法对供热管道隐患进行辨识分析,结合供热管道影响因素明确隐患辨识重点,并针对隐患排查内容及手段等提出对策建议,以支撑供热管道单位更系统、更科学的开展隐患排查治理工作,保障管线的安全运行。     

基于突发事件机理分析的风险评估方法研究及应用

近年来,我国部分城市开展了城市安全风险评估工作。为了能够得到科学的风险评估方法和有效的结果,本文基于突发事件机理分析及单一事件链,对城市安全风险评估方法进行了研究及应用。通过引入控制因子,构建基于突发事件机理分析的单一事件链模型,并将该模型转化为风险评估工作的指标体系,并将该指标体系在某区城市安全风险评估工作中进行了应用,对该区17种单位或场所,涉及到的18类风险,共计201家企业进行风险级别评估。最终得出该区17种单位或场所中每种单位或场所的整体风险等级,以及重大风险数量的占比情况,为该区提出有针对性的风险管控意见奠定了一定基础,并对本文的局限性和下一步研究方向提出一些看法和意见。     

城乡接合部居民楼火灾风险评价及防控对策研究

为了准确探究城乡接合部居民楼火灾事故致因机理,预防与控制城乡接合部日常生产与生活过程中引发火灾事故的有效途径,建立信息面更全、实际性更强的火灾风险评估模型是目前行之有效的手段。基于湖南省某地发生火灾事故的实际情况,根据事故树分析法,以城乡接合部居民楼火灾事故为顶事件构建事故树,计算得到事故树的最小割集、最小径集和结构重要度,研究城乡接合部居民楼火灾事故的发生模式、致因因素及影响程度,为改善城乡接合部居民楼火灾安全提供重要的理论依据,并提出相应的防控措施及对策。     

矿山事故中人员不安全行为的风险分析与防范研究

矿山企业生产系统复杂、生产环节多、地质条件复杂多变、生产条件较为恶劣,要求其不断提高自身的应急管理水平和应急响应能力。本文首先对矿山生产事故的特性进行了分析,划分了人的不安全行为的类型,在此基础上建立了矿井事故致因模型,对事故情况下人员的行为特点、矿工的行为与井下应急场所的关系进行了深入探讨。最后,从安全管理和矿山救护队伍建设两个方面提出了控制矿山事故风险的对策。     

2016—2020年全国化工和危险化学品事故分析研究*

为分析“十三五”期间（2016—2020年）我国化工和危险化学品事故发生情况，统计“十三五”期间化工和危险化学品事故数量及死亡人数，从发生月份、发生区域、行业分布等方面分析事故特征，从事故类别、事故环节、关键作业等方面分析事故原因，总结2011—2020年我国化工和危险化学品事故发展趋势，按照全国4大经济区域研究2013—2020年事故特征。结果表明:“十三五”期间我国化工和危险化学品事故数量呈下降趋势，死亡人数出现波动，总体形势较为平稳。2011—2020年化工和危险化学品事故风险向中西部转移趋势明显，东北、西部地区事故死亡率普遍高于东部地区。研究结果可为相关行业从业者及监管部门提供决策参考。     

Reaction kinetics of waste sulfuric acid using H2O2 catalytic oxidation

The process of recovering waste sulfuric acids using H₂O₂ catalytic oxidation is studied in this paper. Activated carbon was used as catalyst. Main operating parameters, such as temperature, feed rate of H₂O₂, and catalyst dosage, have effects on the removal of impurities from waste sulfuric acids. The reaction kinetics of H₂O₂ catalytic oxidation on impurities are discussed. At a temperature of 90°C, H₂O₂ feeding rate of 50 g (kg waste acid)^?1 per hour, and catalyst dosage of 0.2 wt% (waste acid weight), the removal efficiencies of COD and chrominance were both more than 99%, the recovery ratio of sulfuric acid was more than 95%, and the utilization ratio of H₂O₂ was 88.57%.

Implications: Waste sulfuric acid is a big environmental problem in China. The amount of waste sulfuric acid is huge every year. Many small and medium-sized businesses produced lots of waste acids, but they don’t have an appropriate method to treat and recover them. H₂O₂ catalytic oxidation has been used to treat and recover waste sulfuric acid and activated carbon is the catalyst here. Main parameters, such as temperature, feed rate of H₂O₂, and catalyst dosage, have been investigated. The reaction kinetics are discussed. This method can be economical and feasible for most small and medium-sized businesses.     

Facile Preparation of Chitosan Films for High Performance Removal of Reactive Blue 19 Dye from Aqueous Solution

This study aimed at finding effective strategies for high-performance removal of reactive blue 19 (RB19) dye from aqueous solution. Chitosan (CS) films had been prepared by using solvent casting with mild drying for this purpose. The CS films were characterized by X-ray diffraction, field-emission scanning electron microscopy, and Fourier transform infrared (FTIR) spectroscopy. The performance of RB19 removal using CS were evaluated by varying contact time, solution pH, initial dye concentration, and adsorbent dosage. Adsorption isotherms, kinetics, and desorption were investigated by batch experiments. Results showed that CS films exhibited the optimal adsorption performance for RB19 removal and high maximum adsorption capacities of RB19, which were 799 and 822.4 mg g^?1 at 20 and 40 °C, respectively. Adsorption kinetic data were well described by the pseudo-second-order kinetic model. FTIR analyses further indicated that interactions between RB19 and the CS film occurred during adsorption. The CS films also exhibited satisfactory desorption of RB19 at about 80 % after 30 min of desorption at pH 11. Our study demonstrated that the CS films can be easily prepared and applied for effective removal of RB19 in treatment of wastewater.     

基于IFS-动态加权的地下综合体深基坑施工风险评价

为控制地下综合体深基坑施工风险,提出了一种基于直觉模糊集(IFS)-动态加权的风险评价方法.从地质条件、建筑环境、岩土设计、施工方案和偶然风险5个方面分析地下综合体深基坑施工风险因素,构建了综合风险评价指标体系.采取施工风险5级划分方法,利用IFS理论确定指标风险;以偏大型正态加权函数确定指标权重,得到系统综合风险.以西安市某地下综合体深基坑施工实际为背景,进行方法应用.结果表明,该西安市地下综合体深基坑施工系统风险等级为显著风险.其中,指标"邻近建筑""地下管网"的风险等级为高度风险,"道路交通""基坑边坡稳定性""降排水实施"为显著风险,对此提出了相应的安全措施.