全文获取类型
收费全文 | 439篇 |
免费 | 15篇 |
国内免费 | 143篇 |
专业分类
安全科学 | 37篇 |
废物处理 | 24篇 |
环保管理 | 60篇 |
综合类 | 210篇 |
基础理论 | 82篇 |
污染及防治 | 134篇 |
评价与监测 | 19篇 |
社会与环境 | 13篇 |
灾害及防治 | 18篇 |
出版年
2023年 | 9篇 |
2022年 | 27篇 |
2021年 | 19篇 |
2020年 | 8篇 |
2019年 | 19篇 |
2018年 | 13篇 |
2017年 | 22篇 |
2016年 | 19篇 |
2015年 | 27篇 |
2014年 | 28篇 |
2013年 | 48篇 |
2012年 | 45篇 |
2011年 | 41篇 |
2010年 | 30篇 |
2009年 | 22篇 |
2008年 | 26篇 |
2007年 | 24篇 |
2006年 | 42篇 |
2005年 | 8篇 |
2004年 | 13篇 |
2003年 | 10篇 |
2002年 | 10篇 |
2001年 | 10篇 |
2000年 | 18篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 8篇 |
1996年 | 12篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有597条查询结果,搜索用时 218 毫秒
21.
Zhanguo Liang Jun Mu Ying Mu Jiaming Shi Wenjing Hao Xuewei Dong Hongquan Yu 《环境科学学报(英文版)》2013,(S1):S106-S109
We have created a new method of ZnS nanospheres synthesis. By interface-mediated precipitation method (IMPM), monodisperse ZnS nanoparticles was synthesized on the particle surface of sulfate-reducing bacterium nutritious agar culture. Sulfate-reducing bacterium (SRB) was used as a sulfide producer because of its dissimilatory sulfate reduction capability, meanwhile produced a variety of amino acids acting as templates for nanomaterials synthesis. Then zinc acetate was dispersed into nutritious agar plate. Subsequently agar plate was broken into particles bearing much external surface, which successfully mediated the synthesis of monodisperse ZnS nanoparticles. The morphology of monodisperse ZnS nanospheres and SRB were examined by scanning electron microscopy (SEM), and the microstructure was investigated by X-ray diffraction (XRD). The thermostability of ZnS nanoparticles was determined by thermo gravimetric-differential thermo gravimetric (TG-DTG). The maximum absorption wavelengh was analysed with an ultravioletvisible spectrophotometer within a range of 199-700 nm. As a result, monodisperse ZnS nanoparticles were successfully synthesized, with an average diameter of 80 nm. Maximum absorption wavelengh was 228 nm, and heat decomposed temperature of monodisperse ZnS nanoparticles was 596℃. 相似文献
22.
根据作者从事环境评价工作的经验,结合北京市的城市建设项目的案例,说明在公众参与工作中结合中国城市基层组织特点,发挥基层组织作用,能够有效使公众参与环境保护、体现公众环境知情权、制止群体事件的发生,进一步做好公众参与工作。 相似文献
23.
黄河入河沙漠颗粒物对磷酸盐的吸附特征 总被引:1,自引:0,他引:1
研究了黄河入河沙漠颗粒物在天然水(河水和海水)中对磷酸盐的吸附行为,用改进的Langmuir和Freundlich等温吸附模型对实验数据进行了拟合.结果表明,①改进的Langmuir等温吸附模型更适用于描述黄河入河沙漠颗粒物对磷酸盐的吸附特征,其物理意义更明确,得到的拟合参数更合理;②颗粒物对磷的最大吸附容量Qmax变化范围为41.322~357.143mg.kg-1,其中居延海颗粒物Y2的Qmax最大.Qmax与颗粒物(Y1~Y5)的有机质有着极显著的正相关关系;③除巴丹吉林沙漠颗粒物Y1外,颗粒物的临界磷平衡浓度EPC0值均大于其相应水体的磷浓度.Y1在黄河水中吸附磷的EPC0小于相应水体的磷浓度0.0100.053 mg.L-1,而在渤海海水中却大于相应水体的磷浓度0.1090.074 mg.L-1,表明Y1吸附了黄河水中的磷,进入渤海后Y1原有吸附可交换态磷NAP转移到海水中.其它颗粒物与相应水体进行磷交换的过程中存在着解吸磷的现象,具有向相应水体释放磷的能力;④黄河入河沙漠颗粒物对磷酸盐的吸附等温线是过溶液浓度轴0.00的交叉型等温线,这种新型交叉型吸附-解吸模型较好地解释了其吸附特征和天然粒子的双重性作用. 相似文献
24.
Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period 总被引:3,自引:0,他引:3
Fei Lu Le Yang Xiaoke Wang Xiaonan Duan Yujing Mu Wenzhi Song Feixiang Zheng Junfeng Niu Lei Tong Hua Zheng Yongjuan Zhou Jiangxiao Qiu Zhiyun Ouyang 《环境科学学报(英文版)》2011,23(12):2029-2033
Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir. 相似文献
25.
Application of Ruditapes Philippinarum conglutination mud (RPM) for decolorizing synthetic dye solutions was studied. RPM showed good activity for decolorization of Methylene Blue, Crystal Violet, Malachite Green, and Ink Blue. The amount of the RPM had great effect on the decoloration rate of the dye solutions. However, the decoloration rate did not continue to increase when the amount of mud exceeded the optimum dose. The temperature of the dye solution had a remarkable effect on the decolorization rate of Ink Blue solution, but had little effect on the other three dye solutions. The initial pH of the dye solutions evidently affected the decolorization rate of Malachite Green solution, but had less effect on the other three. The decolorization rate of the dye solutions increased significantly with treatment time within 8 hr, but tended to be steady after 8 hr for Methylene Blue, Crystal Violet and Malachite Green solutions, and after 12 hr for Ink Blue solution. The decolorization efficiencies for the four dye solutions under the optimum conditions were all above 90%. Seventeen strains screened from RPM showed flocculation ability for kaolin clay suspension. Out of them, the flocculation rate of strain ZHT3-9 and strain ZHT4-13 were up to 88.14% and 86.01%, respectively. ZHT3-9 was studied, and its decolorization rate for Methylene Blue, Crystal Violet, and Malachite Green reached 90.02%, 89.21%, and 80.29%, respectively. By morphological, physiological and biochemical characteristics analysis and 16S rRNA sequencing, the strain ZHT3-9 was identified as Arthrobacter sp. 相似文献
26.
Seasonal and diurnal variations of atmospheric peroxyacetyl nitrate, peroxypropionyl nitrate, and carbon tetrachloride in Beijing 总被引:1,自引:0,他引:1
Gen Zhang Yujing Mu Junfeng Liu Chenglong Zhang Yuanyuan Zhang Yujie Zhang Hongxing Zhang 《环境科学学报(英文版)》2014,26(1):65-74
Atmospheric peroxyacetyl nitrate(PAN), peroxypropionyl nitrate(PPN), and carbon tetrachloride(CCl4) were measured from September 2010 to August 2011 in Beijing. PAN exhibited low values from mid-autumn to early spring(October to March) with monthly average concentrations ranging from 0.28 to 0.73 ppbV, and increased from early spring to summer(March to August), ranging from 1.37–3.79 ppbV. The monthly variation of PPN was similar to PAN, with low values(below detection limit to 0.18 ppbV) from mid-autumn to early spring, and a monthly maximum in September(1.14 ppbV). The monthly variation of CCl4was tightly related to the variation of temperature, exhibiting a minimum in winter(69.3 pptV) and a maximum of 180.6 pptV in summer. Due to weak solar intensity and short duration, PAN and O3showed no distinct diurnal patterns from morning to night during winter, whereas for other seasons, they both exhibited maximal values in the late afternoon(ca. 15:00 to 16:00 local time) and minimal values during early morning and midnight. Good linear correlations between PAN and PPN were found in autumn(R = 0.91), spring(R = 0.94), and summer(R = 0.81), with slopes of 0.130, 0.222, and 0.133, respectively, suggesting that anthropogenic hydrocarbons dominated the photochemical formation of PANs in Beijing. Positive correlation between PAN and O3 in summer with the low slopes( O3 / PAN) ranging from 9.92 to 18.0 indicated serious air pollution in Beijing, and strong negative correlation in winter reflected strong O3consumption by NO titration and less thermal decompositin of PAN. 相似文献
27.
28.
29.
Zhenxing Zhang Elias Getahun Mengfei Mu Sangeetha Chandrasekaran 《Journal of the American Water Resources Association》2023,59(3):449-465
Ensuring an adequate, reliable, clean, and affordable water supply for citizens and industries requires informed, long-range water supply planning, which is critically important for water security. A balance between water supply and demand must be considered for a long-term plan. However, water demand projections are often highly uncertain. Climate change could impact the hydrologic processes, and consequently, threaten water supply. Thus, understanding the uncertainties in future water demand and climate is critical for developing a sound water supply plan. In Illinois, regional water supply planning attempts to explore the impacts of future water demand and climate on water supply using scenario analyses and hydrologic modeling. This study is aimed at developing a water supply planning framework that considers both future water demand and climate change impacts. This framework is based on the Soil and Water Assessment Tool to simulate the watershed hydrology and conduct scenario analyses that consider the uncertainties in both future water demand and climate as well as their impacts on water supply. The framework was applied to water supply planning efforts in the Kankakee River watershed. The Kankakee River watershed model was calibrated and validated to observed streamflow records at four long-term United States Geological Survey streamflow gages. Because of the many model parameters involved, the calibration process was automated and was followed by a manual refinement, resulting in good model performance. Long-range water demand projections were prepared by the Illinois State Water Survey. Six future water demand scenarios were established based on a suite of assumptions. Climate scenarios were obtained from the Coupled Model Intercomparison Projection Phase 5 datasets. Three representative concentration pathways (RCPs), RCP2.6, RCP4.5, and RCP8.5, are used in the study. The scenario simulation results demonstrated that climate change appears to have a greater impact on water availability in the study area than water demand. The framework developed in this study can also be used to explore the impacts of uncertainties of water demand and climate on water supply and can be extended to other regions and watersheds. 相似文献
30.
The treatment of chromium-containing leather waste (CCLW), the major solid waste generated at the post-tanning operations of leather processing, has the potential to generate value-added leather chemicals. Various alkali and enzymatic hydrolysis were compared, and calcium oxide was found to be important for effective (but still incomplete) hydrolysis. Three possible reasons are given for the incomplete hydrolysis under alkaline conditions. Data for 19 amino acids are presented for four different treatment products. On the basis of the results, a novel three-step CCLW treatment process is proposed. The gelatin extracted in the first step is chemically modified to produce leather finishing agents. The collagen hydrolysates isolated in the second step are used as proteinic retanning agents by chemical modification. The remaining chrome cake is further hydrolyzed with acids in the third step, and the obtained chromium-containing protein hydrolysates could be used for the preparation of chromium-containing retanning agents for leather industry. The proposed three-step process provides a feasible zero discharge process for the treatment of CCLW. 相似文献