Risk assessment of heavy metal(loid)s via Spinacia oleracea ingestion after sewage water irrigation practices in Vehari District

Environmental Science and Pollution Research - The use of sewage water as an irrigation source can be beneficial in agricultural practices, however, it may result in human health risks due to the...     

Impacts of climatic disasters in coastal Bangladesh: why does private adaptive capacity differ?

This paper quantitatively assesses the influences of various demographic and socio-economic factors, past adaptive behavioral factors, access to weather/climate information, and spatial/locational factors on coastal populations’ perceived adaptive capacity against major impacts of hydro-meteorological disasters on their livelihood. A total of 285 respondents from three coastal villages in Bangladesh were randomly interviewed between January and April 2009. Respondents rated their perceived adaptive capacity against 25 anticipated impacts of sea-level rise (SLR)-induced events on their livelihood. By employing the principal component analysis (PCA), perceived adaptive capacity was grouped into five major categories. Then, an adaptive capacity index for each of five major impacts, namely, “infrastructure damage and disrupted mobility,” “food and nutritional insecurity,” “low earning and higher cost of maintenance,” “loss of employment in offshore activities,” and “crisis of potable water and public health risk,” was prepared. How adaptive capacity against each of these major five categories of impacts differs due to the influence of various factors was assessed by employing the multivariate analysis of variance (MANOVA) technique. The MANOVAs show that age, sex, level of education, type of occupation, farmland holdings, past adaptive behavior against rainfall, salinity intrusion, freshwater crises, use of radio for weather information, and the distance of the homestead from the shoreline have varying levels of influence on respondents’ perceived adaptive capacity against each of the five major categories of impacts. Others factors have moderate to limited influences. The policy implication is that specific programs, rather than a generic one-size fits all program, must be initiated for enhancement of adaptive capacity against specific impacts.     

Composting of municipal solid waste by different methods improved the growth of vegetables and reduced the health risks of cadmium and lead

Environmental Science and Pollution Research - Reutilization of putrescible municipal solid wastes (MSW) in agriculture can provide valuable plant nutrients. However, it may pose serious...     

The role of endogenous nitric oxide in melatonin-improved tolerance to lead toxicity in maize plants

Melatonin (MT) and nitric oxide (NO) are known as scavengers of free radicals and an antioxidant against biotic and abiotic stresses in plant defense systems. However, whether NO interplays role in MT-induced antioxidant defense remains to be determined in the plants exposed to lead (Pb) toxicity. So, two experiments were designed to evaluate the role of NO in MT-mediated tolerance of maize plants to Pb stress. In the initial experiment, prior to starting different treatments, a solution of 0.05- or 0.10-mM MT was sprayed every other day for a period of 10 days to the leaves of maize plants exposed to Pb stress (0.1-mM PbCl₂). Pb toxicity significantly caused reduction in plant biomass (both fresh and dry), PSII maximum efficiency (F_v/F_m), total chlorophyll, leaf potassium (K), calcium (Ca), and leaf water potential, but it resulted in increased levels of proline, hydrogen peroxide (H₂O₂), malondialdehyde (MDA), electron leakage (EL), leaf Pb, and endogenous NO. An addition experiment was set up to further understand whether NO played role in mitigation of Pb toxicity in maize plants by MT using scavengers of NO and cPTIO combined with the MT treatments. MT-induced tolerance to Pb toxicity was totally eliminated by cPTIO by reversing endogenous NO. The present results clearly indicated that MT mediated the endogenous NO to improve tolerance of maize plants to Pb toxicity. This evidence was also supported by the increases of H₂O₂ and MDA and reduces some antioxidant enzyme activities tested as well as the plant growth inhibition and increased leaf Pb content by application of MT combined with cPTIO.

     

Sorption of alpha and beta hydrophobic endosulfan in a Vertisol from southeast region of Turkey

Endosulfan has been applied to control numerous insects in a variety of food and non-food crops. Limited information is available on dynamics of this pesticide in the soil. The objective of this research was to determine the adsorption–desorption behavior of the alpha (α) and beta (β) endosulfan in a Vertisol from the southeast region of Turkey, where cotton is the main crop in the large irrigated lowlands. The α and β endosulfan were adsorbed considerably and Freundlich adsorption–desorption isotherms fitted the α and β endosulfan data (R² > 0.98). Freundlich adsorption coefficients (K_f) for the α endosulfan ranged between 21.63 and 16.33 while for the β endosulfan they were between 14.01 and 17.98 for the Ap and Bw2 horizons. The difference of K_f values of α and β endosulfan for two horizons were explained with the slight difference in the amount of organic matter and clay, but considerable difference in Fe contents of the two horizons. Alpha and β endosulfan K_fd values were 118.03 and 45.81 for the Ap and 48.08 and 68.71 for the Bw2 horizons. Higher adsorption and desorption behavior of the endosulfan isomers for the same horizon was attributed to poor physical bonding between the endosulfan molecule and the surfaces of fundamental soil particles. This fact is thought to increase the effective use of endosulfan in agriculture with a possibility of its movement to the surface and groundwater in the Vertisol studied.     

Processes affecting the movement of organochlorine pesticides (OCPs) between soil and air in an industrial site in Turkey

Soil and atmospheric concentrations, dry deposition and soil-air gas exchange of organochlorine pesticides (OCPs) were investigated at an industrial site in Aliaga, Izmir, Turkey. Current-use pesticides, endosulfan and chlorpyrifos, had the highest atmospheric levels in summer and winter. Summertime total (gas + particle) OCP concentrations in air were higher, probably due to increased volatilization at higher temperatures and seasonal local/regional applications of current-use pesticides. Particle deposition fluxes were generally higher in summer than in winter. Overall average dry particle deposition velocity for all the OCPs was 4.9 ± 4.1 cm s⁻¹ (average ± SD). ΣDDXs (sum of p,p′-DDT, p,p′-DDD, and p,p′-DDE) were the most abundant OCPs in Aliaga soils (n = 48), probably due to their heavy historical use and persistence. Calculated fugacity ratios and average net gas fluxes across the soil-air interface indicated volatilization for α-CHL, γ-CHL, heptachlorepoxide, cis-nonachlor, trans-nonachlor, and p,p′-DDT in summer, and for α-CHL, γ-CHL, trans-nonachlor, endosulfan sulfate, and p,p′-DDT in winter. For the remaining OCPs, soil acted as a sink during both seasons. Comparison of the determined fluxes showed that dry particle, gas-phase, and wet deposition are significant OCP input mechanisms to the soil in the study area.     

Potential concerns related to using octadecyltrichlorosilane (OTS) in rendering soils and porous ceramics hydrophobic

The treatment of hydrophilic porous ceramics to render them hydrophobic and wetting to non-aqueous phase liquids (NAPLs) is frequently needed in multiphase flow experiments to control the flow or to measure the pressure of the NAPL. In addition, research dealing with soil wettability implies a need for hydrophobic or NAPL-wet soils. The traditional procedure, which has been widely used in literature, to render hydrophilic porous ceramics and soils hydrophobic is achieved by placing the hydrophilic solid in a 5% (by volume) octadecyltrichlorosilane (OTS) solution in ethanol followed by rinsing in ethanol. This research assesses the use of this procedure as it was found that this treatment procedure resulted in excess OTS on the surface of treated hydrophobic solids which can dissolve in an organic phase and in turn alter the wettability condition of adjacent hydrophilic soils. A modified procedure, which results in hydrophobic solids free of excess OTS, is presented.     

Feasibility of incorporating waste grass clippings (Lolium perenne L.) in particleboard composites

This study investigated some of the important physical (thickness swelling) and mechanical (modulus of rupture, modulus of elasticity and internal bond) properties of single-layer particleboard panels made from eucalyptus (Eucalyptus camaldulensis Dehn.), waste of grass clippings (Lolium perenne L.) and combinations of the two. The chemical properties (pH, holocelluse and alpha cellulose contents, and water, alcohol-benzene and 1% sodium hydroxide solubilities) of the raw materials were also determined. Panels with a 6:94 ratio of grass-to-eucalyptus particles had the required mechanical properties for interior fitments including furniture and general uses. Boards manufactured with 100% grass clippings exhibited the lowest quality. The overall panel properties improved with a lower percentage of grass clippings added. Based on initial results, it also appears that grass should compose no more than 13% to achieve acceptable panel properties for interior fitments and general uses.     

Determination of Au(III) and Pd(II) ions by flame atomic absorption spectrometry in some environmental samples after solid phase extraction

A simple and sensitive solid phase extraction method was developed for simultaneous separation and preconcentration of gold and palladium ions with N-(4-methylphenyl)-2-{[(4-phenyl-5-pyridine-4-yl-4H-1,2,4-triazol-3-yl)thio]acetyl}hydrazine carbo thioamide complex on Amberlite XAD-1180 resin before their determination by flame atomic absorption spectrometry. Some analytical parameters such as HNO₃ concentration of the sample solution, amount of complexing agent, sample volume, eluent type and volume, effects of foreign ions and adsorption capacity of the resin were investigated for quantitative recovery of gold and palladium ions. The effects of some anions and cations were also examined. Under optimum conditions, the detection limits for gold and palladium ions were found to be 0.29 and 0.19 μg L^?1, respectively. The preconcentration factor for gold and palladium was 250. After being validated by standard addition and analysis of standard reference material, the procedure was successfully applied to the analysis of sea and stream water, anodic slime, gold ore, soil and electronic waste.