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21.
Simultaneous removal of Cu(II) and Cr(VI) by Mg–Al–Cl layered double hydroxide and mechanism insight
Mg–Al–Cl layered double hydroxide (Cl-LDH) was prepared to simultaneously remove Cu(II) and Cr(VI) from aqueous solution. The coexisting Cu(II) (20 mg/L) and Cr(VI) (40 mg/L) were completely removed within 30 min by Cl-LDH in a dosage of 2.0 g/L; the removal rate of Cu(II) was accelerated in the presence of Cr(VI). Moreover, compared with the adsorption of single Cu(II) or Cr(VI), the adsorption capacities of Cl-LDH for Cu(II) and Cr(VI) can be improved by 81.05% and 49.56%, respectively, in the case of coexisting Cu(II) (200 mg/L) and Cr(VI) (400 mg/L). The affecting factors (such as solution initial pH, adsorbent dosage, and contact time) have been systematically investigated. Besides, the changes of pH values and the concentrations of Mg2+ and Al3+ in relevant solutions were monitored. To get the underlying mechanism, the Cl-LDH samples before and after adsorption were thoroughly characterized by X-ray powder diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. On the basis of these analyses, a possible mechanism was proposed. The coadsorption process involves anion exchange of Cr(VI) with Cl− in Cl-LDH interlayer, isomorphic substitution of Mg2+ with Cu2+, formation of Cu2Cl(OH)3 precipitation, and the adsorption of Cr(VI) by Cu2Cl(OH)3. This work provides a new insight into simultaneous removal of heavy metal cations and anions from wastewater by Cl-LDH. 相似文献
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研究了MTBE在砂土中的静态吸附以及采用地下水循环井技术(GCW)去除砂土和地下水中MTBE的衰减规律。结果表明:MTBE在砂土中的吸附动力学符合准二级动力学方程,相关系数R2为0.99618,在砂土中的吸附平衡时间为24 h;吸附热力学符合Linear平衡吸附,吸附系数为0.00306 m3/kg。GCW运行30 h后,地下水饱和含水层中MTBE浓度由500 mg/L降至72.5 mg/L,去除率为85.5%;砂土中MTBE的吸附量由0.93 mg/g降至0.03 mg/g,去除率达96.4%。水平方向距GCW越近,MTBE的去除效率越快,垂直方向位于GCW上部的MTBE优先会被去除,最佳修复时间为运行15 h。GCW对砂土和地下水中高浓度MTBE具有良好的修复效果。 相似文献
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为了研究污水灌渠侧渗对土壤的影响,采用气相色谱-电子捕获检测器(GC-ECD)方法对太原市小店污灌区9个剖面土和2个灌溉污水样进行有机氯化合物(OCPs)分析.结果表明退水渠中有机氯农药主要由六六六(HCHs)组成,滴滴涕(DDTs)及其它有机氯农药含量较低或未检出,在8个离渠较近剖面的地表土中ΣOCPs和HCHs含量一定程度上符合随垂直于渠的直线距离增加而逐步降低的趋势,表明污水渠侧渗对土壤存在着一定影响.8个剖面土壤中的HCHs含量随着深度的增加而降低,在水平方向上,同一深度土壤中的HCHs含量也沿远离渠的直线方向逐步递减.研究区土壤中HCHs含量与TOC之间存在较为显著的正相关性,而与pH之间不存在相关性. 相似文献
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类水滑石Mg/Zn/Al焙烧产物对高氯酸盐的吸附 总被引:4,自引:4,他引:0
利用类水滑石Mg/Zn/Al的焙烧产物对ClO-4进行吸附性能研究,通过类水滑石表面结构X射线衍射分析并探讨其吸附等温、动力学模型,并研究了焙烧温度、Mg/Zn/Al质量比、溶液pH值、吸附时间及吸附剂投加量等因素对类水滑石Mg/Zn/Al吸附ClO-4的性能影响.结果表明在500℃下焙烧4 h,Mg/Zn/Al质量比为2∶1∶1的类水滑石对ClO-4去除效果较好,吸附容量最大且对溶液pH值有较好的适用范围.经500℃焙烧的类水滑石吸附ClO-4的动力学拟合结果符合二级反应动力学模型,吸附等温线符合Langmuir及Freundlich吸附等温模型. 相似文献
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生态社会主义是当代西方一种具有重要影响的左翼社会思潮,它致力于生态原则与社会主义的结合,要求超越资本主义与现存的社会主义模式,主张在对资本主义进行批判和建议的基础上,建立新的绿色社会、生态现代化的社会和全面发展的社会。生态社会主义具有历史的进步性与理论和实践上的局限性双重社会价值,我们应当汲取生态社会主义的积极思想,为中国生态文明建设提供有益借鉴。 相似文献
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Quang M. Nguyen Martha W. Gilliland 《Journal of the American Water Resources Association》1988,24(1):103-111
ABSTRACT: Effects of no-flow river conditions on the quantity and quality of water in the Platte River well field of the City of Grand Island, Nebraska, were examined utilizing a finite-difference computer simulation model specifically developed for this well field. Results suggest that the effects of these no-flow periods on water quality may be most important. In particular, the no-flow periods eliminate the hydraulic barrier between the well field and an area north of the River that is contaminated with nitrate (concentrations in the 20 to 40 mg/1 NO3-N range). They also change the direction and velocity of movement of the contaminated ground water. Simulation results indicate that contaminated ground water moves toward the well field with a velocity of 0.42 ft/d after 30 days of no-flow and 1.43 ft/d after 180 days of no-flow. Limiting no-flow conditions to 10 consecutive days would protect the well field. 相似文献
30.
Plumes of atmospheric aerosol have been studied using a rangeof satellite and ground-based techniques. The Sea-viewing WideField-of-view Sensor (SeaWiFS) has been used to observe plumesof sulphate aerosol and Saharan dust around the coast of theUnited Kingdom. Aerosol Optical Thickness (AOT) was retrievedfrom SeaWiFS for two events; a plume of Saharan dusttransported over the United Kingdom from Western Africa and aperiod of elevated sulphate experienced over the Easternregion of the UK. Patterns of AOT are discussed and related tothe synoptic and mesoscale weather conditions. Furtherobservation of the sulphate aerosol event was undertaken usingthe Advanced Very High Resolution Radiometer instrument(AVHRR). Atmospheric back trajectories and weather conditionswere studied in order to identify the meteorologicalconditions which led to this event. Co-located ground-basedmeasurements of PM10 and PM2.5 were obtained for 4sites within the UK and PM2.5/10 ratios were calculatedin order to identify any unusually high or low ratios(indicating the dominant size fraction within the plume)during either of these events. Calculated percentiles ofPM2.5/10 ratios during the 2 events examined show thatthese events were notable within the record, but were in noway unique or unusual in the context of a 3 yr monitoringrecord. Visibility measurements for both episodes have beenexamined and show that visibility degradation occurred duringboth the sulphate aerosol and Saharan dust episodes. 相似文献