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排序方式: 共有1748条查询结果,搜索用时 31 毫秒
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Qing Xie Jingwen Chen Jianping Shao Changer Chen Hongxia Zhao Ce Hao 《Chemosphere》2009,76(11):1486-1490
Photolysis of deca-bromodiphenyl ether (BDE-209) was investigated in tetrahydrofuran, dichloromethane, isopropanol, acetone, ethanol, methanol, acetonitrile and dimethylsulfoxide. Noticeable differences of the photolytic rates and quantum yields were found in the diverse solvents. Different to the previous deductions, hydrogen donating efficiency and electron donating efficiency of solvents were not the decisive factors for the photolytic rate in this study, which was proved by the fast photolysis of BDE-209 in CCl4, a solvent without hydrogen and difficult to donate electrons. Besides hydrogen addition process, intermolecular polymerization might occur during the photolysis. Density functional theory (DFT) calculation was performed to understand the molecular properties of BDE-209 in different solvents. The lowest singlet vertical excitation energy (Eex) and the average formal charge on Br () of BDE-209, reflecting the difficulty for the excitation of BDE-209 and for the departing of Br atom, respectively, were changed by the reaction fields formed by the different solvents. Eex and linearly correlated with the photolytic activity (log k). This study is helpful to better understand the photolytic behavior of BDE-209 in different media. 相似文献
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公众灾害风险可接受性与避灾意愿的初探——以川渝地区旱灾风险为例 总被引:2,自引:0,他引:2
在综述前人研究的基础上,以川渝地区旱灾为例,通过实地调查与访谈,从公众可接受的旱灾损失与频率、假定旱灾风险情景下的避险意愿等角度,对公众旱灾风险可接受性进行了初步探讨。结果表明,公众合理可接受的旱灾损失与频率分别在26.5%~52.8%与32.0%~64.3%区间范围内;并以一般旱灾、严重旱灾风险情景为限制线,确定了公众合理可接受风险区域;随着灾害损失风险增加,公众规避风险投资意愿呈现出中间高两头低的趋势,当灾害损失达到约50%~70%时,公众避险投资意愿达到最高,意愿避险投资占可能损失的比重约为62%。鉴于川渝地区的旱灾形势,今后旱灾风险管理的关键,一是加强对旱灾的监测与预警预报;二是完善旱灾风险的常规化管理,发展高效灌溉农业,充分利用客水资源,完善提高现有农田水网建设;三是积极探索公众-企业-政府多方共同参与的高效风险管理模式。 相似文献
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Michael J. White Daniel E. Storm Michael D. Smolen Hailin Zhang 《Journal of the American Water Resources Association》2009,45(2):397-406
Abstract: Assessment tools to evaluate phosphorus loss from agricultural lands allow conservation planners to evaluate the impact of management decisions on water quality. Available tools to predict phosphorus loss from agricultural fields are either: (1) qualitative indices with limited applicability to address offsite water quality standards, or (2) models which are prohibitively complex for application by most conservation planners. The purpose of this research was to develop a simple interface for a comprehensive hydrologic/water quality model to allow its usage by farmers and conservation planners. The Pasture Phosphorus Management (PPM) Calculator was developed to predict average annual phosphorus (P) losses from pastures under a variety of field conditions and management options. PPM Calculator is a vastly simplified interface for the Soil and Water Assessment Tool (SWAT) model that requires no knowledge of SWAT by the user. PPM Calculator was validated using 33 months of data on four pasture fields in northwestern Arkansas. This tool has been extensively applied in the Lake Eucha/Spavinaw Basin in northeastern Oklahoma and northwestern Arkansas. PPM Calculator allows conservation planners to take advantage of the predictive capacity of a comprehensive hydrologic water quality model typically reserved for use by hydrologists and engineers. This research demonstrates the applicability of existing water quality models in the development of user friendly P management tools. 相似文献
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浅谈新疆风电场水土保持措施配置——以新疆华电小草湖风电场二场一期工程为例 总被引:1,自引:0,他引:1
风能作为一种清洁无污染的可再生能源,已经被广泛运用到电力事业的发展中来。近年来,新疆的风力发电发展迅速,风电场建设过程中不可避免地会对土壤及植被造成一定的破坏,人为地加剧了水土流失。概述了风电项目水土流失特点,以新疆华电小草湖风电场工程为例,结合项目区具体特点,分区设置防治措施。通过工程措施、植物措施与临时措施的有机结合,有效地防止水土流失。 相似文献
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