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两种改性剂对多氯联苯污染土壤协同热脱附影响研究 总被引:1,自引:0,他引:1
采用热脱附技术处理多氯联苯污染土壤已经成为了一种主要的场地修复方式。为提高热脱附效率,降低能耗,以典型电力电容器污染土壤为对象,采用2种改性剂(零价纳米铁和氢氧化钠)研究协同热脱附下多氯联苯的去除效率、分布特性及毒性当量。结果表明纳米铁和NaOH存在的条件下,有效提高了多氯联苯和毒性当量的去除效率,在较低温度下尤其显著,因此添加改性剂能够有效地促进热脱附过程。纳米铁的协同热脱附机理为显著强化了热脱附过程的传质传热,同时伴有一定的脱氯降解。NaOH的添加在较低温度下实现了较强的脱氯降解作用,加氢脱氯机理可用来解释协同热脱附过程中多氯联苯的脱氯反应过程。上述研究结果为多氯联苯污染土壤的场地修复提供理论基础。 相似文献
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利用造纸黑液制水煤浆添加剂新技术 总被引:1,自引:0,他引:1
生产水煤浆所需的添加剂,因价格居高不下而影响这种煤基液体燃料的发展。利用碱法造纸黑液和经改造的造纸生产设备,将浓缩黑液稍加酸化、磺化处理后在一定压力、温度下反应,可制成性能良好的添加剂,利用该添加剂生产1吨水煤浆只增加约10元成本。 相似文献
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《环境科学学报(英文版)》2023,35(4):784-793
Despite millions of seafarers and passengers staying on ships each year, few studies have been conducted on the indoor air quality inside ship hulls. In this study, we investigated the levels and size distribution of indoor particulate matter during two cruises of the research vessel “Xuelong” from Shanghai to Antarctica. The results showed that the particle size less than 2.5 µm (PM2.5), and particle size less than 10 µm (PM10) concentrations in different rooms of the ship widely varied. We observed high particulate matter (PM) levels in some of the rooms. The mass concentration distribution was dominated by 1–4 µm particles, which may have been caused by the hygroscopic growth of fine particles. The dominant factors influencing PM concentrations were indoor temperature, relative humidity, and human activity. We quantified contributions of these factors to the levels of indoor particles using a generalized additive model. In clean rooms, the levels of indoor particles were controlled by temperature and relative humidity, whereas in polluted rooms, the levels of indoor particles were mainly influenced by temperature and human activity, which implied that controlling temperature and human activity would efficiently reduce the levels of indoor particles. 相似文献
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化学镀锡添加剂对镀层厚度及表面形貌的影响 总被引:2,自引:0,他引:2
采用电化学等方法研究了硫酸镍和水合肼对化学镀锡层厚度及表面形貌的影响.结果表明,硫酸镍起到了细化镀层的作用.而水合阱的加入使镀锡层的厚度增加. 相似文献
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Great promotion to the reproduction of white rot fungus Phanerochaete chrysosporlum by adding natural lixiviums such as from wood, maize core and potato in liquid medium was found in this research. Incubated in the liquid medium contained 10 mg/L glucose as carbon source with natural lixiviums for three days, the production of myeelium pellet reaches more than 80 g/L, which is 5 times more than that of without natural lixiviums. Incubated in the liquid medium contained 5 mg/L glucose as carbon source with natural lixiviums for three days, the production of myeelium pellet can reach 69.5 g/L, while the production in the medium without natural lixiviums is very low. When the liquid medium contained 1-20 g/L glucose as carbon source, the production of myeelium pellet in 3 d can only reach 12.5 g/L to 14.5 g/L. The fungus in the medium with potato lixiviums are easily contaminated by other microorganisms and in the medium with maize core lixiviums are easily bulking, while in the medium with wood lixiviums are neither easily contaminated nor bulking. Medium with wood lixiviums can produce more pellet than other medium, endure contamination and keep better sedimentation capacity. So that, wood lixivium is borer additive to the culture of white rot fungi in liquid medium. Addition of the mixture of wood, maize core and potato lixiviums is of advantage to the productian of mycelium pellet. The difference of the production in the medium with different amount of wood lixiviums showed little in the first 3 d, while it esnanded after 3 d. Wood lixiviums stimulate the growth of P. chrysosporium instead of supply organies which fungi need. 相似文献
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