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目的 探究不同温湿度条件下微米硼的氧化层结构特征。方法 利用高温水浴浸泡处理去除原料微米硼的表面氧化层,然后在恒温恒湿条件下对微米硼进行加速氧化,利用扫描电子显微镜、透射电子显微镜和X射线光电子能谱对加速氧化后硼颗粒的氧化层厚度及组成进行分析,总结表面氧化层结构及成分组成变化规律,揭示温湿度条件下微米硼的氧化机制。结果 微米硼经高温水浴浸泡处理后,表面氧化层去除率达到50%。随着加速氧化时间的延长,硼颗粒氧化层的厚度逐渐增大,由内向外硼颗粒表面可以用B-BxOy-B2O3三层结构来表示,BxOy总是伴随着B2O3同时出现的,且随着氧化反应的进行,颗粒表面BxOy的含量将超过B的含量。结论 不同温湿度条件下微米硼的氧化机制为O2向B颗粒内部单向扩散的反应机制,B先与O2反应,形成低氧化物BxOy,BxOy进而与O2反应生成B2O3。随着氧化层厚度的增加,O2向B颗粒内部扩散的阻力增大,氧化反应速率随之降低。相比湿度的影响,温度的升高可显著加快硼表面氧化层的形成;温度一定时,湿度的增加可促进硼氧化层的形成。 相似文献
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发射场液体推进剂个体防护体系的研究与设计 总被引:1,自引:0,他引:1
为了确保发射场液体推进剂作业人员的身体健康和生命安全,本文以安全系统工程理论为依据,结合液体推进剂作业要求以及防护装具现状,研究并建立了发射场推进剂作业个体三级防护体系。 相似文献
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Davide Manca 《Journal of Loss Prevention in the Process Industries》2013,26(6):974-981
Safety reports are mandatory documents in member states of European Union whenever any threshold limits of amounts of either stored or processed hazardous substances are exceeded. After a short introduction to EU Seveso Directives on major-accident hazards involving dangerous substances and to the transposition and implementation by member states, with a brief comment on last 2012/18/EU Directive (also known as Seveso III directive), the paper focuses on drafting of safety reports for industrial activities involving solid explosives. Specifically, the quantitative assessment of consequences from detonation is tackled respect to the side-on overpressure and the debris production. Both direct and inverse problems are illustrated to determine respectively the overpressure value at a given distance, and the explosive amount that allows respecting the regulations. Their solution is based on either analytic or numerical techniques and being based on recent scientific publications on the matter either evaluates or zeroes nonlinear algebraic equations. The availability of these equations avoids grounding the consequences assessment on diagrams and nomograms that otherwise would lead to interpretation and usage errors besides avoiding the automatic solution of the inverse problem. The paper focuses also on details such as embankment, crater, munitions, rocket propellant, building structure, and wall material that, at different levels, play a role in the assessment of detonation consequences. A discussion on debris formation, the available literature, and the evaluation of the impact probability of fragments on both fixed and moving targets closes the paper. 相似文献
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采用X射线光电子能谱(XPS)法研究了HTPB推进剂在80℃热空气烘箱内分别老化0周、13周和24周的元素组成、化学价态及含量变化。通过拟合C,O,N,Cl等元素的XPS谱图,推测该推进剂在常温(25℃)贮存老化初期应是氧化交联,后期则出现降解断链,并认为NH4ClO4缓慢分解,攻击C C不饱和双键,使得C C双键含量降低是HTPB推进剂老化失效的主要原因。Al粉被包裹在推进剂粘合剂内部,XPS法未能检出Al粉。由于Al粉比较稳定,不参与推进剂老化过程,故XPS仍可用于HTPB推进剂老化机理研究。 相似文献
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固体发动机装药热安全性数值分析 总被引:3,自引:1,他引:2
目的研究固体火箭发动机遭受火烤时的安全性。方法建立发动机有限元模型,计算推进剂在慢速烤燃和快速烤燃工况下的温度分布和爆炸延迟时间。结果推进剂慢烤47 h后达到临界温度,其值为352℃;快烤推进剂加热697 s后达到临界温度,临界温度为355℃。结论推进剂在快速烤燃模式下的热扩散速率大于慢速烤燃工况下,但是温度梯度则相反。两种工况下推进剂达到临界温度后开始反应的位置不同,推进剂厚度决定了其储热能力。 相似文献
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The safety of the solid propellant molding process is vital for the stable production of high-quality propellants. Failure events caused by abnormal parameters in the molding process may have catastrophic consequences. In this paper, a Bayesian network (BN) model is proposed to assess the safety of the solid propellant granule-casting molding process. Fault tree analysis (FTA) is developed to construct a causal link between process variables and process failures. Subsequently, expert experience and fuzzy set theory (FST) are used to obtain failure probabilities of the basic events (BEs). Based on the mapping rules, FTA provides BN with reliable prior knowledge and a network structure with interpretability. Finally, when new evidence is obtained, the probability is updated with the diagnostic reasoning capability of BN. The results of the sensitivity analysis and diagnostic inference were combined to identify key parameters in the granule-casting molding process, including curing temperature, vacuum degree, extrusion, calendering roll distance, length setting value, holding time, and polish time. The results of this paper can provide effective supporting information for managers to conduct process safety analysis. 相似文献
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本文以某发射场为例,通过主要危险源辨识、作业单元划分、现场调查和监测统计,利用风险指数评估法对液体推进剂职业中毒风险进行量化评价,结果表明:液体推进剂作业存在极度和高度职业中毒风险,发射场液体推进剂作业职业中度风险主要来源于液体推进剂及氮气;液体推进剂设备维修、应急救援及进罐作业存在极度职业中毒风险,转注/加注、取样为高度风险,化验及"三废"处理属于中度风险。根据评价结果并借鉴以往事故经验教训,指出职业中毒伤害与工程控制、个体防护措施和安全意识密切相关,不使用或不能正确使用呼吸防护装备是引发职业中毒的主要原因,并提出针对性的防护措施建议。 相似文献
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