Preparation and performance of arsenate (V) adsorbents derived from concrete wastes

Solid adsorbent materials, prepared from waste cement powder and concrete sludge were assessed for removal of arsenic in the form of arsenic (As(V)) from water. All the materials exhibited arsenic removal capacity when added to distilled water containing 10–700 mg/L arsenic. The arsenic removal isotherms were expressed by the Langmuir type equations, and the highest removal capacity was observed for the adsorbent prepared from concrete sludge with heat treatment at 105 °C, the maximum removal capacity being 175 mg-As(V)/g. Based on changes in arsenic and calcium ion concentrations, and solution pH, the removal mechanism for arsenic was considered to involve the precipitation of calcium arsenate, Ca₃(AsO₄)₂. The enhanced removal of arsenic for the adsorbent prepared from concrete sludge with heat treatment was thought to reflect ion exchange by ettringite. The prepared adsorbents, derived from waste cement and concrete using simple procedures, may offer a cost effective approach for arsenic removal and clean-up of contaminated waters, especially in developing countries.     

Plutonium isotopes concentration in seawater and bottom sediment off the Pacific coast of Aomori sea area during 1991-2005

A radioactivity survey was launched in 1991 to determine the background levels of ^239+240Pu in the marine environment off a commercial spent nuclear fuel reprocessing plant before full operation of the facility. Particular attention was focused on the ²⁴⁰Pu/²³⁹Pu atom ratio in seawater and bottom sediment to identify the origins of Pu isotopes. The concentration of ^239+240Pu was almost uniform in surface water, decreasing slowly over time. Conversely, the ^239+240Pu concentration varied markedly in the bottom water and was dependent upon the sampling point, with higher concentrations of ^239+240Pu observed in the bottom water sample at sampling points having greater depth. The ²⁴⁰Pu/²³⁹Pu atom ratio in the seawater and sediment samples was higher than that of global fallout Pu, and comparable with the data in the other sea area around Japan which has likely been affected by close-in fallout Pu originating from the Pacific Proving Grounds. The ²⁴⁰Pu/²³⁹Pu atom ratio in bottom sediment samples decreased with sea depth. The land-originated Pu is not considered as the reason of the increasing ^239+240Pu concentration and also decreasing the ²⁴⁰Pu/²³⁹Pu atom ratio with sea depth, and further study is required to clarify it.     

(137)Cs concentration in zooplankton and its relation to taxonomic composition in the western North Pacific Ocean

To study the role of zooplankton in the transport of (137)Cs in the ocean, zooplankton samples were collected in October 2005 and June 2006 in the western North Pacific Ocean. The peak zooplankton biomass was observed in the surface layer, and gelatinous plankton was more abundant in October 2005 than in June 2006 reflecting exchange of water masses. The concentrations of (137)Cs in zooplankton varied from 11 to 24 mBq kg wet(-1) and were higher in October 2005 than in June 2006. The elevated abundance of gelatinous zooplankton probably led to higher concentration of (137)Cs in zooplankton in October 2005. Annual export fluxes of (137)Cs by ontogenetic vertical migrant copepods were estimated to be 0.8 and 0.6 mBq m(-2) year(-1) at 200 and 1000 m depths, respectively; this suggested that transport of (137)Cs by zooplankton may be no trivial pathway.     

Prediction of response of zooplankton biomass to climatic and oceanic changes

This paper examines the long-term variation in zooplankton biomass in response to climatic and oceanic changes, using a neural network as a nonlinear multivariate analysis method. Zooplankton data collected from 1951 to 1990 off the shore of northeastern Japan were analyzed. We considered patterns of the Kuroshio and the Oyashio, sea surface temperature, and meteorological parameters as environmental factors that affect zooplankton biomass. Back propagation neural networks were trained to generate mapping functions between environmental variables and zooplankton biomass. The performance of the network models was tested by varying the numbers of input and hidden units. Changes in zooplankton biomass could be predicted from environmental conditions. The neural network yielded predictions with smaller errors than those of predictions determined by linear multiple regression. The sensitivity analysis of networks was used to extract predictive knowledge. The air pressure, sea surface temperature, and some indices of atmospheric circulation were the primary factors for predictions. The patterns of the Kuroshio and the Oyashio demonstrated different effects among sea areas.     

Mineral content of drinking water in lowland papua

This study presents concentration of nine minerals (Na, K, Mg, Ca, Cl, Mn, Zn, Cd, Pb) in 31 drinking water samples collected in the Papua New Guinea lowland, where coastal villagers draw water from artificial wells blended with sea water, riverside villagers utilize brackish river water, and inland villagers fetch creek or swamp water whose chemical composition is close to rain water. During the dry season, the coastal well water contains 500 mgL⁻¹ of sodium and 50–90 μgL⁻¹ of lead. The inland creek or swamp water contains very small amount of minerals; on the average, for instance, 0.64 mgL⁻¹ of magnesium, 0.84 mgL⁻¹ of calcium, and 4.78 mgL⁻¹ of water hardness (as CaCO₃). From some epidemiological evidence in industrialized countries, these mineral concentrations are judged to be indicative of high risk of cardiovascular disorders.     

Evolution of male dimorphic allometry in a population of the Japanese horned beetle <Emphasis Type="Italic">Trypoxylus dichotomus septentrionalis</Emphasis>

I conducted a detailed morphological analysis of the Japanese horned beetle Trypoxylus dichotomus septentrionalis to clarify the allometric relationship between horn length and body size and examined its mating success and reproductive behaviour in the field. The relationship between horn and body size was not discontinuous at the switch point body size, but the slope of the linear relationship changed at the switch point. Shape of the allometric relationship was initially steep and became flatten around the switch point in both linear and log scales; that is, minor males showed a positive relationship and major males showed a negative one. Major males gained more mating success than minor males. Within major males, individuals with larger horn or body size had higher mating success than individuals with smaller ones. Within minor males there were no differences in horn and body size between mated and unmated individuals. Although sneak-like behaviours were exhibited by both morphs, it is likely that these behaviours rarely lead to direct benefit. These results suggest that dimorphic allometry of T. dichotomus is consistent with the hypothesis of a continuous reaction norm that meets a ceiling, which restrains further allometric growth.