地下水超采综合治理的农户评价、原因分析与改进建议

通过在河北省衡水市的实地调研,从农户评价、原因分析、改进建议三个方面对5大类22项地下水超采治理措施进行了研究。农户评价结果表明:农户比较清楚水利工程建设、种植结构调整、农艺节水技术这三类措施,比较不清楚农业水权水价改革、服务体系建设这两类措施;农户对水利工程建设、种植结构调整这两类措施的评价为较好,对农艺节水技术、服务体系建设这两类措施的评价为一般,对农业水权水价改革这类措施的评价为较差。原因分析结果表明:与农业生产的相关性越直接紧密,农户越清楚该治理措施,节水机制越直接明确、农户参与动机越强,农户对该治理措施的评价越好。因此,在制定地下水超采治理措施时,应当设计直接且明确的节水机制,充分考虑农民的参与动机和保障农民的利益,以及加大对与农业生产相关性弱的治理措施的宣传。改进地下水超采治理,需要遵循综合施策的思想,采取分类改进的策略,改进建议如下:(1)需要加强水利设施的维修和管护,避免出现重建设、轻管护的情形,需要综合考虑引水指标、蓄水能力、季节性、恢复渠灌面积等因素来评估水利工程建设未来的压采潜力。(2)应当基于水资源承载力评估耕地休耕的潜力和规模,在现阶段粮食相对充裕的背景下,建议在地下水严重超采区进一步扩大休耕规模,完善补偿机制和加大财政投入力度。(3)需要反思和调整现有的农业水权水价政策,在中国特定国情条件下,不提倡农业用水确权过细,不提倡农户之间的水权交易。农业水价发挥作用面临较多障碍,应当先期解决农业用水计量困难、农业水费征缴困难两大基础性难题。(4)应当改变农户对减少灌溉的减产预期,引导农户科学、适量灌溉,同时增加农户迫切需求的技术服务的供给。     

基于GIS与栅格数据的安徽省人居环境自然适宜性测评

科学度量人居环境自然背景的适宜性，有助于合理引导人口分布与流动，促进区域人口、资源环境协调发展。运用GIS技术，以250 m×250 m栅格为基本单元，选取气候、地形、水文、地被、自然灾害等因子，构建人居环境自然适宜性评价模型，定量测评安徽省人居环境自然适宜程度，剖析各类型区的适宜性和限制性。研究表明：安徽省人居环境指数介于33.64～74.58之间，人居环境自然适宜性总体较好，绝大部分地区适宜人类居住，适宜性在空间上大体呈现南高北低的态势，与现有人口分布格局相反。一般适宜区面积最广，占安徽省总面积的46.08%；比较适宜区次之，占31.29%；高度适宜区占22.54%；临界适宜区面积最小，仅占0.08%。安徽省近61.16%的人口分布在一般适宜区，高度适宜区与比较适宜区人口所占比例不足40%，临界适宜区人口极为稀少。地形起伏度和水文指数是造成全省人居环境自然适宜性分异的主要因子，测评结果较为客观地反映了安徽省人居环境的自然本底。全省人口生存与发展的空间较大，人口流动与集聚的适宜范围较广。 关键词： 人居环境；自然适宜性；栅格；GIS；安徽省     

杭州:以绿色创建拓展环境教育平台

正绿色创建系列工程为环保理念的传播和实践进学校、进家庭、进企业、进社区提供了有效的载体,为各个单位、部门直接参与和广大市民亲身体验环境保护提供了良好的平台。要绿水青山,还是要金山银山?这在杭州,从来都不是一道非此即彼的选择题。多年来,杭州市一直把保护环境放在突出位置,自2000年就开展的绿色创建活动,引领着杭州市生产生活的绿色化潮流。2003年启动的生态市建设工作中,以绿色学校、环境教育基地、绿色医院等为重点的"绿色     

A two-stage cyclone using microcentrifuge tubes for personal bioaerosol sampling

Personal aerosol samplers are widely used to monitor human exposure to airborne materials. For bioaerosols, interest is growing in analyzing samples using molecular and immunological techniques. This paper presents a personal sampler that uses a two-stage cyclone to collect bioaerosols into disposable 1.5 ml Eppendorf-type microcentrifuge tubes. Samples can be processed in the tubes for polymerase chain reaction (PCR) or immunoassays, and the use of multiple stages fractionates aerosol particles by aerodynamic diameter. The sampler was tested using fluorescent microspheres and aerosolized fungal spores. The sampler had first and second stage cut-off diameters of 2.6 microm and 1.6 microm at 2 l min(-1)(geometric standard deviation, GSD = 1.45 and 1.75), and 1.8 microm and 1 microm at 3.5 l min(-1)(GSD = 1.42 and 1.55). The sampler aspiration efficiency was >or=98% at both flow rates for particles with aerodynamic diameters of 3.1 microm or less. For 6.2 microm particles, the aspiration efficiency was 89% at 2 l min(-1) and 96% at 3.5 l min(-1). At 3.5 l min(-1), the sampler collected 92% of aerosolized Aspergillus versicolor and Penicillium chrysogenum spores inside the two microcentrifuge tubes, with less than 0.4% of the spores collecting on the back-up filter. The design and techniques given here are suitable for personal bioaerosol sampling, and could also be adapted to design larger aerosol samplers for longer-term atmospheric and indoor air quality sampling.     

“艰辛历程——防灾减灾巡礼”摄影大赛作品选

~~“艰辛历程——防灾减灾巡礼”摄影大赛作品选@余敏恩$福建省泉州市地震局!退休干部 @王忠喜$沈阳市消防局~~     

Fungicidal values of bio-oils and their lignin-rich fractions obtained from wood/bark fast pyrolysis

Pine wood, pine bark, oak wood and oak bark were pyrolyzed in an auger reactor. A total of 16 bio-oils or pyrolytic oils were generated at different temperatures and residence times. Two additional pine bio-oils were produced at the National Renewable Energy Laboratory in a fluidized-bed reactor at different temperatures. All these bio-oils were fractionated to obtain lignin-rich fractions which consist mainly of phenols and neutrals. The pyrolytic lignin-rich fractions were obtained by liquid-liquid extraction. Whole bio-oils and their lignin-rich fractions were studied as potential environmentally benign wood preservatives to replace metal-based CCA and copper systems that have raised environmental concerns. Each bio-oil and several lignin-rich fractions were tested for antifungal properties. Soil block tests were conducted using one brown-rot fungus (Gloeophyllum trabeum) and one white-rot fungus (Trametes versicolor). The lignin-rich fractions showed greater fungal inhibition than whole bio-oils for a impregnation solution 10% concentration level. Water repellence tests were also performed to study wood wafer swelling behavior before and after bio-oil and lignin-rich fraction treatments. In this case, bio-oil fractions did not exhibit higher water repellency than whole bio-oils. Comparison of raw bio-oils in soil block tests, with unleached wafers, at 10% and 25% bio-oil impregnation solution concentration levels showed excellent wood preservation properties at the 25% level. The good performance of raw bio-oils at higher loading levels suggests that fractionation to generate lignin-rich fractions is unnecessary. At this more effective 25% loading level in general, the raw bio-oils performed similarly. Prevention of leaching is critically important for both raw bio-oils and their fractions to provide decay resistance. Initial tests of a polymerization chemical to prevent leaching showed some success.     

Changes in plasma thyroid hormones and cortisol levels in crucian carp (Carassius auratus) exposed to the extracted microcystins

The endocrine response of crucian carp injected intraperitoneally with extracted microcystins (MC) was investigated in this study. Fish were injected intraperitoneally either with 0.75% NaCl (control) and Microcystis extract corresponding to 150 and 600 microg microcystins per kg body weight. The plasma levels of triiodothyronine (T(3)), thyroxine (T(4)), free triiodothyronine (FT(3)), free thyroxine (FT(4)), and cortisol were determined at 0, 1, 3, 12, 24, and 48h post-administration of MC-containing extract. Treated fish displayed abnormal behaviors, such as a startle response and disoriented swimming, as well as changes in ventilation rates. Plasma cortisol concentrations of fish in both dose groups significantly increased after administration of extracted MC and remained high throughout the experiment, which suggested that MC elicited a stress response in treated fish. The profiles of cortisol changes in treated fish appeared to be dose dependent, indicating that fish in the high dose group experienced greater MC-induced disturbance. Mortality occurred after 12h in the high dose group. Plasma levels of T(4), T(3), FT(4), and FT(3) did not vary significantly between the control fish. In contrast to this, fish exposed to MC-containing extract showed significant declines in T(3), FT(4), and FT(3) levels in a dose-dependent manner throughout the experiment. Plasma T(4) levels, however, did not vary significantly in the low dose group, whereas they decreased significantly at 48h post injection in the high dose group. This study demonstrates that administration of microcystins-containing extract causes a stress response and reduces the plasma levels of thyroid hormones in crucian carp. These results illustrate that microcystins exerted potent effects on the endocrine system of crucian carp, through activating their hypothalamus-pituitary- interrenal axis and disturbing thyroid function.     

Pre-concentration and separation of heavy metal ions by chemically modified waste paper gel

Iminodiacetic acid was immobilized on waste paper by chemical modification in order to develop a new type of adsorption gel for heavy metal ions. Adsorption behavior of the gel was investigated for a number of metal ions, specifically Cu(II), Pb(II), Fe(III), Ni(II), Cd(II), and Co(II) at acidic pH. From batch adsorption tests, the order of selectivity was found to be as follows: Cu(II)  Fe(III) > Pb(II) > Ni(II)  Co(II) > Cd(II). Column tests were carried out for pairs of metal ions to understand the separation and pre-concentration behavior of the gel. It was found that mutual separation of Ni(II) from Co(II) and that of Pb(II) from Cd(II) can be achieved at pH 3. Similarly, selective separation of Cu(II) from Cu(II)–Fe(III) and Cu(II)–Pb(II) mixtures at pH 1.5 and 2, respectively, was observed by using this new adsorption gel. In all cases, almost complete recovery of the adsorbed metal was confirmed by elution tests with HCl.     

Feasibility study of preparation and certification of reference materials for nitrogen dioxide and sulfur dioxide in diffusive samplers

This paper presents the results of a feasability study for the preparation and certification of reference materials (RMs) for nitrogen dioxide (NO(2)) and sulfur dioxide (SO(2)) in diffusive samplers. RMs for NO(2) were prepared by exposure to gas mixtures in a chamber while the RMs for SO(2) were prepared by liquid spiking. Certification of RMs for NO(2) was found feasible with a certified uncertainty of 5.8% and a proposed shelf life of 5 years. The uncertainty was calculated with contribution from the homogeneity of preparation, stability and transport of the CRMs and from an external verification of the certified value. To reach 5.8% of uncertainty, the contribution of the differences between the results of analysis by ion chromatography and colorimetry must be eliminated. It is proposed to solve this by pre-extracting the samplers with water before analysis. The results of this study indicate that the samplers are stable for at least two years before and after exposure when stored in a refrigerator. By contrast, the certification of RMs for SO(2) was found to not be feasible due to instability problems. This instability was attributed to reaction of sulfate on the walls of the samplers. Alternatively, the preparation of RMs by simultaneous exposure to SO(2) and NO(2) has been tested. Satisfying homogeneities has been reached both for NO(2) and SO(2).     

上流式多级厌氧反应器中厌氧颗粒污泥特性研究

高品质厌氧颗粒污泥是厌氧反应器实现高效、稳定运行的关键和基础.在实现上流式多级厌氧反应器(UMAR)处理木薯变性淀粉废水高效运行的基础上,对厌氧颗粒污泥的浓度分布、粒径分布、沉降速度、产甲垸活性,辅酶F420和生物相等作进一步的研究.根据在实验工艺条件下培养得到的厌氧颗粒污泥的性能,探讨厌氧颗粒污泥的可能形成机制.