排序方式: 共有26条查询结果,搜索用时 15 毫秒
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以Cu-TEPA为模板剂原位水热合成一系列具有优良deNOx特性的Cu-SSZ-13/堇青石整体式催化剂.为进一步改善其氨的选择性催化还原氮氧化物的活性,在制备过程中添加HF对原位制备Cu-SSZ-13/堇青石整体式催化剂进行改性.利用XRD、SEM、XPS、BET、ICP-AES等对样品进行了表征.结果表明,当nHF/nAl在0.015—0.0375时,晶化72 h的Cu-SSZ-13/堇青石表现出了优异的脱硝性能和抗老化性能,其最大转化率为99.8%,NOx转化率保持在90%以上的最宽活性温度窗口为280—640℃,而无HF的新鲜样品的NOx转化率保持在90%以上的活性温度窗口为300—580℃;720℃老化50 h处理后,nHF/nAl=0.015—0.0375样品的NOx转化率保持在90%以上的最宽活性温度窗口为360—520℃,未添加HF的老化样品相应的活性温度窗口为400—500℃.无论新鲜还是老化,nHF/nAl=0.015—0.0375样品在低温段200—300℃和高温段500—700℃的NOx转化率基本都大于未添加HF的样品.结合表征结果,在催化剂原位水热合成过程中HF的加入既提高了样品的相对结晶度和负载量,又增大了样品的比表面积和比孔容,且提高了Cu-SSZ-13/堇青石骨架结构的稳定性,进而在一定程度上改善了Cu-SSZ-13/堇青石的高温脱硝活性和水热稳定性. 相似文献
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开发区环境管理指标体系研究是建立开发区环境管理综合体系的基础性工作,也是考核开发区生态环境建设与管理效果的定量评价工具。本文在探讨环境管理指标体系的确定原则、选择和量化等基础上。提出了一套包括环境保护指标、循环经济指标、绿色管理指标和相关性指标四类指标在内的环境管理综合指标体系。并将该指标体系应用于杭州钱江经济开发区的环境管理实践。结果表明,杭州钱江经济开发区的环境管理完善程度总得分为74.6%,总体上还有待进一步完善,特别是ISO14001管理体系认证和环境质量改善等方面有待进一步加强。 相似文献
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Determination of 4-tert-octylphenol in surface water samples of Jinan in China by solid phase extraction coupled with GC-MS 总被引:1,自引:0,他引:1
Octylphenols, considered as xenoestrogens, mainly exist as 4-tert-octylphenol (OP) in aquatic environments. The high stability and accumulation of OP in aquatic systems have caused endocrine disruption. The OP in surface water in Jinan, China was analyzed by gas chromatography-mass spectrometry (GC-MS) coupled with solid phase extraction (SPE). Water samples were extracted by SPE on a cartridge system containing C-18 as sorbent. To increase sensitivity and selectivity, OP was derivatized to 4-tert-octyl-phenoxy silane. With the use of phenanthrene-d10 as internal standard, the detection limit based on signal-to-noise ratio (S/N = 3) was 0.06 ng/mL. The average recovery was from 84.67% to 109.7%. The precision of the method given as the relative standard deviations (RSD) was within the range 6.24%-12.96%. In the target water samples, the concentrations of OP were as follows: 15.88-71.24 ng/L for Jinxiuchuan Reservoir, 3.850-26.68 ng/L for the city moat, 6.930-41.56 ng/L for Daming Lake, 66.03-474.2 ng/L for Xiaoqing River, 14.66-17.72 ng/L for the Yellow River, and 10.60-26.43 ng/L for Queshan Reservoir. The Xiaoqing River was seriously polluted due to the discharge of wastewater from Jinan. Jinxiuchuan Reservoir had a higher concentration of OP compared with the Yellow River and Queshan Reservoir, which is ascribed to the surrounding human activities. These data are reported for the first time, providing strong support for the control of OP pollution in Jinan. 相似文献
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Geochemistry of heavy metal-contaminated sediments from the Four River inlets of Dongting lake,China
Fang Xiaohong Peng Bo Song Zhaoliang Wu Sicheng Chen Danting Zhao Yafang Liu Jing Dai Yanan Tu Xianglin 《Environmental science and pollution research international》2021,28(22):27593-27613
Environmental Science and Pollution Research - The concentrations of major and trace elements in the sediments from the Four River inlets of Dongting Lake were analysed. The results show that the... 相似文献
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Liu Xiaozhen Li Fuxiang Zhu Zhaoliang Peng Gaoyi Huang Danfei Xie Mingyong 《Environmental science and pollution research international》2022,29(35):52665-52674
Environmental Science and Pollution Research - Biological effect of an individual nonylphenol (NP) isomer extremely relies upon the side chain structure. This research was designed to evaluate the... 相似文献
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城市污泥干燥焚烧一体化处理工艺的研究 总被引:1,自引:0,他引:1
城市污泥的产量日益增加,若不进行处理,不仅浪费土地资源而且污染环境。对污泥中的水分形式和污泥的处理工艺进行了分析,认为污泥的干燥和焚烧是最完全、稳定的处理工艺。提出一种城市污泥干燥焚烧一体化处理工艺,利用污泥自身焚烧产生的热值,提供干燥系统所需的热量,达到整个污泥处理系统能量的基本自给。对该系统的流程和各工艺进行了分析,结果表明该系统的污泥减量大、干燥效率高、运行成本低、尾气排放有效控制。 相似文献
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