Development of the Chesapeake Bay Watershed Total Maximum Daily Load Allocation

Nutrient load allocations and subsequent reductions in total nitrogen and phosphorus have been applied in the Chesapeake watershed since 1992 to reduce hypoxia and to restore living resources. In 2010, sediment allocations were established to augment nutrient allocations supporting the submerged aquatic vegetation resource. From the initial introduction of nutrient allocations in 1992 to the present, the allocations have become more completely applied to all areas and loads in the watershed and have also become more rigorously assessed and tracked. The latest 2010 application of nutrient and sediment allocations were made as part of the Chesapeake Bay total maximum daily load and covered all six states of the Chesapeake watershed. A quantitative allocation process was developed that applied principles of equity and efficiency in the watershed, while achieving all tidal water quality standards through an assessment of equitable levels of effort in reducing nutrients and sediments. The level of effort was determined through application of two key watershed scenarios: one where no action was taken in nutrient control and one where maximum nutrient control efforts were applied. Once the level of effort was determined for different jurisdictions, the overall load reduction was set watershed‐wide to achieve dissolved oxygen water quality standards. Further adjustments were made to the allocation to achieve the James River chlorophyll‐a standard.     

Monitored and Modeled Correlations of Sediment and Nutrients with Chesapeake Bay Water Clarity

This article analyzes the correlations of the observed and modeled light attenuation coefficient, Kd, with in situ total suspended solids (TSS) and chlorophyll‐a concentrations in Chesapeake Bay (CB) tidal waters, and with sediment and nutrient loads from the Chesapeake watershed. Light attenuation is closely related to in situ TSS and chlorophyll‐a concentrations, however, the strength of the correlation differs among the CB segments. There are distinct differences between saline and tidal fresh segments in the main Bay, but less distinction among saline and tidal fresh segments in the tidal tributaries. The correlation between Kd with sediment and nutrient loads is complicated by the lag times of TSS and the chlorophyll‐a responses to reductions in nutrient and sediment loads from the watershed, and also due to the diverse load sources. Three sets of model sensitivity scenarios were performed with: (1) differential sediment and nutrient loads; (2) selective sediment source types; and (3) geographically isolated inputs. The model results yield similar findings as those based on observed data and provide information regarding the effect of sediment on specific water bodies. Based on the model results a method was developed to determine sediment and nutrient load reductions needed to achieve the water clarity standards of the CB segments.     

Computing Atmospheric Nutrient Loads to the Chesapeake Bay Watershed and Tidal Waters

Application of integrated Chesapeake Bay models of the airshed, watershed, and estuary support air and water nitrogen controls in the Chesapeake. The models include an airshed model of the Mid‐Atlantic region which tracks the estimated atmospheric deposition loads of nitrogen to the watershed, tidal Bay, and adjacent coastal ocean. The three integrated models allow tracking of the transport and fate of nitrogen air emissions, including deposition in the Chesapeake watershed, the subsequent uptake, transformation, and transport to Bay tidal waters, and their ultimate influence on Chesapeake water quality. This article describes the development of the airshed model, its application to scenarios supporting the Chesapeake Total Maximum Daily Load (TMDL), and key findings from the scenarios. Key findings are that the atmospheric deposition loads are among the largest input loads of nitrogen in the watershed, and that the indirect nitrogen deposition loads to the watershed, which are subsequently delivered to the Bay are larger than the direct loads of atmospheric nitrogen deposition to Chesapeake tidal waters. Atmospheric deposition loads of nitrogen deposited in coastal waters, which are exchanged with the Chesapeake, are also estimated. About half the atmospheric deposition loads of nitrogen originate from outside the Chesapeake watershed. For the first time in a TMDL, the loads of atmospheric nitrogen deposition are an explicit part of the TMDL load reductions.     

Chesapeake Bay eutrophication: scientific understanding, ecosystem restoration, and challenges for agriculture

Chesapeake Bay has been the subject of intensive research on cultural eutrophication and extensive efforts to reduce nutrient inputs. In 1987 a commitment was made to reduce controllable sources of nitrogen (N) and phosphorous (P) by 40% by the year 2000, although the causes and effects of eutrophication were incompletely known. Subsequent research, modeling, and monitoring have shown that: (i) the estuarine ecosystem had been substantially altered by increased loadings of N and P of approximately 7- and 18-fold, respectively; (ii) hypoxia substantially increased since the 1950s; (iii) eutrophication was the major cause of reductions in submerged vegetation; and (iv) reducing nutrient sources by 40% would improve water quality, but less than originally thought. Strong public support and political commitment have allowed the Chesapeake Bay Program to reduce nutrient inputs, particularly from point sources, by 58% for P and 28% for N. However, reductions of nonpoint sources of P and N were projected by models to reach only 19% and 15%, respectively, of controllable loadings. The lack of reductions in nutrient concentrations in some streams and tidal waters and field research suggest that soil conservation-based management strategies are less effective than assumed. In 1997, isolated outbreaks of the toxic dinoflagellate Pfiesteria piscicida brought attention to the land application of poultry manure as a contributing factor to elevated soil P and ground water N concentrations. In addition to developing more effective agricultural practices, emerging issues include linking eutrophication and living resources, reducing atmospheric sources of N, enhancing nutrient sinks, controlling sprawling suburban development, and predicting and preventing harmful algal blooms.     

Deriving Chesapeake Bay Water Quality Standards

Achieving and maintaining the water quality conditions necessary to protect the aquatic living resources of the Chesapeake Bay and its tidal tributaries has required a foundation of quantifiable water quality criteria. Quantitative criteria serve as a critical basis for assessing the attainment of designated uses and measuring progress toward meeting water quality goals of the Chesapeake Bay Program partnership. In 1987, the Chesapeake Bay Program partnership committed to defining the water quality conditions necessary to protect aquatic living resources. Under section 303(c) of the Clean Water Act, States and authorized tribes have the primary responsibility for adopting water quality standards into law or regulation. The Chesapeake Bay Program partnership worked with U.S. Environmental Protection Agency to develop and publish a guidance framework of ambient water quality criteria with designated uses and assessment procedures for dissolved oxygen, water clarity, and chlorophyll a for Chesapeake Bay and its tidal tributaries in 2003. This article reviews the derivation of the water quality criteria, criteria assessment protocols, designated use boundaries, and their refinements published in six addendum documents since 2003 and successfully adopted into each jurisdiction's water quality standards used in developing the Chesapeake Bay Total Maximum Daily Load.     

炼油化工污水处理中活性污泥膨胀原因分析

针对工业废水采用普通活性污泥法处理易出现的丝状菌型污泥膨胀,分析和总结出五种主要膨胀类型:低负荷型、低溶解氧型、营养缺乏型、高硫化物型、pH值不平衡型。对污泥负荷、溶解氧、污水种类、营养成分及pH值和温度的变化等因素对污泥膨胀中菌胶团和丝状菌生长的相互影响进行阐述,给出污泥膨胀理论,并对不同类型的污泥膨胀提出相应的控制方法。     

Water quality modeling to determine minimum instream flow for fish survival in tidal rivers

The Hsintien Stream is one of the major branches of the Danshuei River system, which runs through the metropolitan capital city of Taipei, Taiwan and receives a large amount of wastewater. The dissolved oxygen concentration is generally low in the tidal portion of the Hsintien Stream. Hypoxia/anoxia occurs often, particularly during the low-flow period when the Feitsui Reservoir, Chingtan Dam and Chihtan Dam impound the freshwater for municipal water supply. Fish kills happen from time to time. This paper describes the application of a numerical hydrodynamic and water quality model to the Danshuei River system, with special attention to the tidal portion of the Hsintien Stream. The model is recalibrated with the prototype conditions of the year 2000. The hydrodynamic portion of the model is recalibrated with measured surface elevation and velocity at various stations in the river system. The water quality portion of the model is recalibrated with respect to the field data provided by Taiwan EPA. The input data of point and nonpoint sources are also estimated. The model simulates the concentrations of various forms of nutrients, CBOD and dissolved oxygen. A series of sensitivity runs was conducted to investigate the effects of point source loadings and river flow on the DO level in the river. It is demonstrated that the augmentation of river flow has as much effect on raising DO level as the reduction of point source loadings. The completion of the Taipei sewer project is expected to reduce the point source loadings by at least 75%. Under these reduced loadings, if the daily instream flow is maintained above the monthly Q75 flow throughout the year, the minimum DO concentration in the river would not fall below 1mg/L, which is the suffocation level for most fish species in the Hsintien Stream. (Q75 is the flow which is equaled or exceeded 75% of the days in the month.) The Feitsui Reservoir, Chingtan Dam and Chihtan Dam may impound water during the high flow periods and release freshwater to maintain the flow at the Q75 value in the Hsintien Stream during the drought periods.     

胶州湾水质自动站周边水质及运行效果分析

据2016年胶州湾水质自动监测的数据结果,分析了水质变化趋势,并统计和评价其水质超标情况。结果表明:2016-04—11水质自动站海域溶解氧质量浓度和pH 的日均值均达到二类海水水质标准,达标率为100%;活性磷酸盐年均值为0.023mg/L,无机氮年均值为0.154mg/L,以硝酸盐为主(64.9%);无机氮和活性磷酸盐超标率均为16.7%,而且集中在降雨量较大的8月、9月,营养盐指标超标基本与海泊河的淡水输入有关;叶绿素a质量浓度与溶解氧、pH 和浊度呈显著正相关,浮游植物光合作用对该海域表层海水的水质参数影响较大;自动站监测和人工监测的营养盐在年际变化上呈现较一致的趋势,说明运用水质自动站监测该海域的营养盐变化趋势较为准确。     

Mapping Three‐Dimensional Water‐Quality Data in the Chesapeake Bay Using Geostatistics1

Abstract:  Data interpretation and visualization software tools with geostatistical capabilities were adapted, customized, and tested to assist the Chesapeake Bay Program in improving its water‐quality modeling protocols. Tools were required to interpolate, map, and visualize three‐dimensional (3D) water‐quality data, with the capability to determine estimation errors. Components of the software, originally developed for ground‐water modeling, were customized for application in estuaries. Additional software components were developed for retrieval, and for pre‐ and post‐ processing of data. The Chesapeake Bay Program uses the 3D mapped data for input to the Bay water‐quality model that projects the future health of the Bay and its tidal tributary system. In determining water‐quality attainment criteria, 3D kriging estimation errors are needed as a statistical measure of uncertainty. Furthermore, given the high cost of installing and operating new monitoring stations, geostatistical techniques can assist the Chesapeake Bay Program in the identification of suitable data collection locations. Following the evaluation, selection, and development of the software components phase, 3D ordinary kriging techniques with directional semi‐variograms to account for anisotropy were successfully demonstrated for mapping 3D fixed station water‐quality data, such as dissolved oxygen and salinity. Additionally, an improved delineation tool was implemented to simulate the upper and lower pycnocline boundary surfaces allowing the segregation of the interpolated 3D data into three separate zones for a better characterization of the pycnocline layer.     

Interactions of warming and altered nutrient load timing on the phenology of oxygen dynamics in Chesapeake Bay

The effects of nutrient loading on estuaries are well studied, given the multitude of negative water quality and ecosystem effects that have been attributed to excess nitrogen and phosphorus. A current gap in this knowledge involves the sensitivity of seasonal cycles of estuarine biogeochemical processes to direct (warming) and indirect influences (nutrient load timing) of climate change. We used a coupled hydrologic–biogeochemical model to investigate changes in the phenology of hypoxia and related biogeochemical processes in Chesapeake Bay under three different hydrologic regimes. Shifts to earlier nutrient load timing during idealized simulations reduced the overall annual hypoxic volume, resulting from discernable, but relatively small reductions in phytoplankton biomass and both sediment and water-column respiration. Simulated increases in water temperature caused an increase in spring/early summer hypoxic volume associated with elevated respiration rates, but an associated exhaustion of organic matter in the early summer caused a decrease in late summer/fall hypoxic volume due to lowered respiration. Warming effects on hypoxia were larger than nutrient timing effects in scenarios where warming was restricted to spring and when it was applied to all months of the year. These idealized simulations begin the process of understanding the potential impacts of future climatic changes in the seasonal timing of key biogeochemical processes associated with eutrophication.     

Using flue gas desulfurization gypsum to remove dissolved phosphorus from agricultural drainage waters

High levels of accumulated phosphorus (P) in soils of the Delmarva Peninsula are a major source of dissolved P entering drainage ditches that empty into the Chesapeake Bay. The objective of this study was to design, construct, and monitor a within-ditch filter to remove dissolved P, thereby protecting receiving waters against P losses from upstream areas. In April 2007, 110 Mg of flue gas desulfurization (FGD) gypsum, a low-cost coal combustion product, was used as the reactive ingredient in a ditch filter. The ditch filter was monitored from 2007 to 2010, during which time 29 storm-induced flow events were characterized. For storm-induced flow, the event mean concentration efficiency for total dissolved P (TDP) removal for water passing through the gypsum bed was 73 ± 27% confidence interval (α = 0.05). The removal efficiency for storm-induced flow by the summation of load method was 65 ± 27% confidence interval (α = 0.05). Although chemically effective, the maximum observed hydraulic conductivity of FGD gypsum was 4 L s(-1), but it decreased over time to <1 L s(-1). When bypass flow and base flow were taken into consideration, the ditch filter removed approximately 22% of the TDP load over the 3.6-yr monitoring period. Due to maintenance and clean-out requirements, we conclude that ditch filtration using FGD gypsum is not practical at a farm scale. However, we propose an alternate design consisting of FGD gypsum-filled trenches parallel to the ditch to intercept and treat groundwater before it enters the ditch.     

Hypoxia in the Gulf of Mexico

Seasonally severe and persistent hypoxia, or low dissolved oxygen concentration, occurs on the inner- to mid-Louisiana continental shelf to the west of the Mississippi River and Atchafalaya River deltas. The estimated areal extent of bottom dissolved oxygen concentration less than 2 mg L-1 during mid-summer surveys of 1993-2000 reached as high as 16,000 to 20,000 km2. The distribution for a similar mapping grid for 1985 to 1992 averaged 8000 to 9000 km2. Hypoxia occurs below the pycnocline from as early as late February through early October, but is most widespread, persistent, and severe in June, July, and August. Spatial and temporal variability in the distribution of hypoxia exists and is, at least partially, related to the amplitude and phasing of the Mississippi and Atchafalaya discharges and their nutrient flux. Mississippi River nutrient concentrations and loadings to the adjacent continental shelf have changed dramatically this century, with an acceleration of these changes since the 1950s to 1960s. An analysis of diatoms, foraminiferans, and carbon accumulation in the sedimentary record provides evidence of increased eutrophication and hypoxia in the Mississippi River delta bight coincident with changes in nitrogen loading.     

TMDL Balance: A Model for Coastal Water Pollutant Loadings

Bacterial contamination accounts for more than 60% of the impairments included on the 2008 Texas 303(d) List. Many of these bacterial impairments are along the Texas Gulf Coast because coastal waters often are regulated for oyster harvesting, which have strict water quality standards. Under the Clean Water Act, each one of these impaired waterbodies requires a total maximum daily load (TMDL) study to be performed. A recent, statewide study recommended the development and application of simple modeling approaches to address the majority of Texas's bacteria TMDLs, including “… simple load duration curve, GIS [geographic information systems], and/or mass balance models.” We developed the TMDL Balance model in response to this recommendation. TMDL Balance is a steady state, mass balance, GIS‐based model for simulating pollutant loads and concentrations in coastal systems. The model uses plug‐flow reactor and continuously‐stirred tank reactor equations to route spatially distributed point and nonpoint source loads through a watershed via overland flow, non‐tidal flow, and tidal flow, decaying the loads via first‐order kinetics. In this paper, we explain the development of the watershed loading portion of the TMDL Balance model, demonstrating the methodology through a case study: computing bacterial loads in the Copano Bay watershed of southeast Texas. The application highlights an example of distributing bacterial sources spatially based on land use data.     

DROUGHT EFFECTS ON WATER QUALITY IN THE SOUTH PLATTE RIVER BASIN,COLORADO1

ABSTRACT: Twenty‐three stream sites representing a range of forested, agricultural, and urban land uses were sampled in the South Platte River Basin of Colorado from July through September 2002 to characterize water quality during drought conditions. With a few exceptions, dissolved ammonia, Kjeldahl nitrogen, total phosphorus, and dissolved orthophosphate concentrations were similar to seasonal historical levels in all land use areas during the drought. At some agricultural sites, decreased dilution of irrigation return flow may have contributed to higher concentrations of some nutrient species, increased primary productivity, and higher dissolved oxygen concentrations. At some urban sites, decreased dilution of base flow and wastewater treatment plant effluent may have contributed to higher dissolved nitrite‐plus‐nitrate concentrations, increased primary productivity, and higher dissolved oxygen concentrations. Total pesticide concentrations in urban and agricultural areas were not consistently higher or lower during the drought. At most forested sites, decreased dilution of ground water‐derived calcium bicarbonate type base flow likely led to elevated pH and specific‐conductance values. Water temperatures at many of the forested sites also were higher, contributing to lower dissolved oxygen concentrations during the drought.     

FLUSHING CHARACTERISTICS OF A MISSISSIPPI DEAD-END CANAL SYSTEM1

ABSTRACT: A study of residential canal system on the Mississippi Gulf Coast and adjacent natural water bodies was conducted to determine the relationship in flushing characteristics between man-made and natural systems. The comparison was based on measurements of temperature, salinity, conductivity, coliform, pH, transparency, biological oxidation demand, dissolved oxygen, bathymetry, tides, water velocity, and Rhodamine dye concentrations. The results indicate that coliform bacteria increase with increasing distance of stations from St. Louis Bay and dissolved oxygen decreases in a similar manner. Biological oxidation demand was low at all stations; showing no differences between natural and man-made systems. The canal system Studied was shallower than adjacent water bodies and water velocities in the canal system are a function of tidal amplitude while velocities in the river are affected by both tides and runoff. The other parameters measured show little or no differences between natural and man-made systems, but reflect overall seasonal changes. Flushing rates between the residential canal systems and an adjacent natural system are equivalent on the basis of decline in dye concentrations measured over a five-day period.     

A Case History of the Science and Management Collaboration in Understanding Hypoxia Events in Long Bay, South Carolina, USA

Communication of knowledge between the scientific and management communities is a difficult process complicated by the distinctive nature of professional career goals of scientists and decision-makers. This article provides a case history highlighting a collaboration between the science and management communities that resulted from a response to a 2004 hypoxia, or low dissolved oxygen, event in Long Bay, off Myrtle Beach, South Carolina. A working group of scientists and decision-makers was established at the time of the event and has continued to interact to develop a firm understanding of the drivers responsible for hypoxia formation in Long Bay. Several factors were found to be important to ensure that these collaborative efforts were productive: (1) genuine interest in collaboratively working across disciplines to examine a problem; (2) commitment by agency leadership, decision-makers, and researchers to create successful communication mechanisms; (3) respect for each others’ perspectives and an understanding how science and management are performed and that they are not mutually exclusive; (4) networking among researchers and decision-makers to ensure appropriate team members are involved in the process; (5) use of decision-maker input in the formulation of research and monitoring projects; and (6) commitment of resources for facilitation to ensure that researchers and decision-makers are communicating effectively.     

Toward Reversal of Eutrophic Conditions in a Subtropical Estuary: Water Quality and Seagrass Response to Nitrogen Loading Reductions in Tampa Bay, Florida, USA

Coastal waters have been significantly influenced by increased inputs of nutrients that have accompanied population growth in adjacent drainage basins. In Tampa Bay, Florida, USA, the population has quadrupled since 1950. By the late 1970s, eutrophic conditions including phytoplankton and macroalgal blooms and seagrass losses were evident. The focus of improving Tampa Bay is centered on obtaining sufficient water quality necessary for restoring seagrass habitat, estimated to have been 16,400 ha in 1950 but reduced to 8800 ha by 1982. To address these problems, targets for nutrient load reductions along with seagrass restoration goals were developed and actions were implemented to reach adopted targets. Empirical regression models were developed to determine relationships between chlorophyll a concentrations and light attenuation adequate for sustainable seagrass growth. Additional empirical relationships between nitrogen loading and chlorophyll a concentrations were developed to determine how Tampa Bay responds to changes in loads. Data show that when nitrogen load reduction and chlorophyll a targets are met, seagrass cover increases. After nitrogen load reductions and maintenance of chlorophyll a at target levels, seagrass acreage has increased 25% since 1982, although more than 5000 ha of seagrass still require recovery. The cooperation of scientists, managers, and decision makers participating in the Tampa Bay Estuary Program’s Nitrogen Management Strategy allows the Tampa Bay estuary to continue to show progress towards reversing many of the problems that once plagued its waters. These results also highlight the importance of a multi-entity watershed management process in maintaining progress towards science-based natural resource goals.     

Nitrogen and phosphorus attenuation within the stream network of a coastal, agricultural watershed

Streams alter the concentration of nutrients they transport and thereby influence nutrient loading to estuaries downstream; however, the relationship between in-stream uptake, discharge variability, and subsequent nutrient export is poorly understood. In this study, in-stream N and P uptake were examined in the stream network draining a row-crop agricultural operation in coastal North Carolina. The effect of in-stream nutrient uptake on estuarine loading was examined using continuous measurements of watershed nutrient export. From August to December 2003, 52 and 83% of the NH4+ and PO4(3-) loads were exported during storms while concurrent storm flow volume was 34% of the total. Whole-ecosystem mass transfer velocities (Vf) of NH4+ and PO4(3-), measured using short-term additions of inorganic nutrients, ranged from 0.1 to 25 mm min(-1). Using a mass balance approach, this in-stream uptake was found to attenuate 65 to 98% of the NH4+ flux and 78 to 98% of the PO4(3-) flux in small, first-order drainage ditches. For the larger channel downstream, an empirical model based on Vf and discharge was developed to estimate the percentage of the nutrient load retained in-stream. The model predicted that all of the upstream NH4+ and PO4(3-) load was retained during base flow, while 65 and 37% of the NH4+ and PO4(3-) load was retained during storms. Remineralization from the streambed (vs. terrestrial sources) was the apparent source of NH4+ and PO4(3-) to the estuary during base flow. In-stream uptake reduced the dissolved inorganic N to dissolved inorganic P ratio of water exported to the N-limited estuary, thus limiting the potential for estuarine phytoplankton growth.     

FILTERING OF DISSOLVED OXYGEN DATA IN STREAM WATER QUALITY ANALYSIS1

ABSTRACT: In this study a set of equations was developed which can be used to separate the time varying effects from observed dissolved oxygen (DO) data. A steady state DO profile thus derived allows a reasonable stream stimulation such that both the model and the data used in its formulation do not contain DO due to biological activities. Biological DO production and consumption are complex phenomena. By excluding these highly variable processes, this method simplifies stream DO modeling considerably. The net oxygen input due to these processes exist only part of the day, but, in the stream waste assimilative capacity analysiis and waste load allocation, one would focus his attention on critical condition. Hence, unless the change of stream ecology is the main concern, it is desirable to formulate a stream water quality model without this time varying term.     

Water and nutrient transport on a heavy clay soil in a fluvial plain in the Netherlands

In flat areas, transport of dissolved nutrients by water through the soil matrix to groundwater and drains is assumed to be the dominant pathway for nutrient losses to ground- and surface waters. However, long-term data on the losses of nutrients to surface water and the contribution of various pathways is limited. We studied nutrient losses and pathways on a heavy clay soil in a fluvial plain in The Netherlands during a 5-yr period. Average annual nitrogen (N) and phosphorus (P) losses to surface water were 15.1 and 3.0 kg ha(-1) yr(-1), respectively. Losses were dominated by particulate N (50%) and P (70%) forms. Rapid discharge through trenches was the dominant pathway (60-90%) for water and nutrient transport. The contribution of pipe drains to the total discharge of water and nutrients was strongly related to the length of the dry period in the preceding summer. This relationship can be explained by the very low conductivity of the soil matrix and the formation of shrinkage cracks during summer. Losses of dissolved reactive P through pipe drains appear to be dominated by preferential flow based on the low dissolved reactive P concentration in the soil matrix at this depth. Rainfall occurring after manure application played an important role with respect to the annual losses of N and P in spring when heavy rainfall occurred within 2 wk after manure application.