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1.
六六六热解废渣中2,3,7,8—取代PCDDs和PCDFs的测定   总被引:4,自引:3,他引:4  
包志成  康君行 《环境化学》1994,13(5):409-414
采用HPLC和GC/MS法对六六六热解废渣中的PCDDs和PCDFs进行了测定,使用此种方法,于废渣中检出了所有2,3,7,8-取代的同系物。此外,还根据各CDDs,CDFs的毒性当量因子TEFs,计算了废渣的毒性当量TEQs,约为612-924μg/g。分析表明,OCDD是含量最丰富的导构体,而1,2,3,4,6,7,8-HpCDD,1,2,3,4,6,7,8-HpCDF和1,2,3,4,7,8  相似文献   

2.
ICP—MS法对国标小麦粉中15种稀土元素的定值研究   总被引:2,自引:0,他引:2  
刘虎生  王耐芬 《环境化学》1997,16(2):98-102
本文报道采用HNO3+HClO4溶样,小麦粉标样GBW08503中15种超痕量稀土元素定值的ICP-MS应用研究,造反了仪器最佳操作参数,选择Re内标可补偿基体效应,方法检出限为0.007-0.026ng.ml^-1,加标回收率为95-103%,RSD为2.5-4.8%,方法快速、灵敏、准确。  相似文献   

3.
不同消毒剂对水中脊髓灰质炎病毒灭活的比较   总被引:4,自引:1,他引:3  
将脊髓灰质炎病毒( Polio V) 及不同消毒剂投加到模拟水样中,按不同接触时间1 ,3 ,10 ,30 min 取样,空斑定量. 当模拟水有机质含量 C O D 为20 mg/ L,病毒浓度n( P F U) ≈1 ×105 m L- 1 时,分别投加氯制剂有效氯ρ( Cl)16 mg/ L,接触30 min ;ρ( Cl O2) = 8 .0 mg/ L,30 min ; Cl+ Cl O2 联合消毒剂(5 .0 + 5 .0) mg/ L,30 min ;ρ( O3) = 1 .22 mg/ L,10 min 时;可使病毒彻底灭活. 它们使 Polio V 达到99 .99 % 灭活的浓度时间乘积( ρ×t) 值分别是662 .5 ,129 .5 ,200 .0 和3 .2 mg L- 1 min . 消毒效果( 顺序) 为 O3 > Cl O2 > Cl+ Cl O2 > Cl. 联合消毒灭活 Polio V 的效果为 Cl 的3 .3 倍,表明将 Cl 与 Cl O2 联合应用具有协同效应,优于传统的单一加氯消毒方式  相似文献   

4.
张统  张志仁 《环境化学》1999,18(5):476-481
本文根据酵母废液的水质特点,采用了常温升流式厌氧污泥床处理工艺,即温度在26.8-28.0℃,进水COD为7129-9823mg·l^-1时,达到CDO去除率66.0-71.0%,同时,沼气产率为2.4-3.0L·l^-1·d^-1,沼气中烷含量为61.5-69.1%。该法耗能小,沼气可回收,经济效果明显。  相似文献   

5.
成熟蕃茄匀浆后,经硫酸铵盐析,DEAE-SephadexA-50离子交换层析,SepadexG-100凝胶过滤和Melibiose-Agarose亲和层析,获得了α-D-半乳糖苷酶(C.E.3.2.1.11)。酶制剂经PAGE检测为一条带;SDS-G-PAGE测得酶Mr为34000;比活力52.9U/mg·;提纯倍数为52901产率为45%.酶专-催化以α-D-半乳糖为末端a-(1,3)连接的糖苷键,以PNPG(对硝基苯-α-D-半乳糖昔)为废物,酶催化反应的Km=0.11mmol/L,Vmax为67μmol·mg1-·min-1.t稳定范是0~35℃;PH稳定范围是4.0~7.0.最适pH为5.1.半乳糖是酶的竞争性抑制剂;Cu2+、Zn2+、Mn2+、Fe3+、Ag+和EDTA对酶活性无影响.纯酶制剂可作为B型血向O型血转化的工具酶液.  相似文献   

6.
王爱霞  刘静玲 《环境化学》1995,14(3):269-273
本文采用PT-C18色谱预处理柱,以8-羟基喹啉为螯合剂,流动注射在线分离富集与原子吸收联机,成功地测定了环境样品中的铅。1min富集(4.2ml)的检出限为7.5μg1^-1,相对标准偏差1.7%。  相似文献   

7.
单甲脒饱和蒸气压的测定和估算   总被引:1,自引:0,他引:1  
用气体的法测单甲脒在15,25,35和45℃时的饱和蒸气分别为0.202,0.5546,1.95,6.29Pa;亨利常数计算值分别为6.30×10^-4,1.67×10^-3,5.68×10^0-3和1.78×10&-2,根据Clausius Clapeyron方程求出单甲脒在常温下气化热为89.2kJ.mol^-1。  相似文献   

8.
二氧化氯发生技术的试验研究   总被引:7,自引:0,他引:7  
鲁秀国  黄君礼 《环境化学》2000,19(5):441-446
本文进行了二氧化氯发生技术的实验研究,给出了适宜的反应条件,即NaClO3浓度为25.9%,还原剂A浓度为2.65%,曝气量0.8L空气.min^-1,反应温度60℃,反应时间30min时,ClO2的收率为82.1%,纯度大于95.0%。  相似文献   

9.
本试验采集了湖南省八种主要母质发育的23个农田土壤耕层样本,其中水田土壤16个,旱地土壤7个.将土壤氮分为七级.即交换性NH4+十NO3-,水解性NH4+,氨基糖氮,可溶性碱稳定态氮,酸溶性腐殖质态氮,固定态NH4+,难溶性腐殖质态氮。分析结果表明,土壤中交换性NH4+十NO3-的含量为22.0土9.0mg/kg,占全氮的1.7土0.7%;水解性NH4+为324.4土109.5mg/kg,占全氮的23.9±5.6%;氨基糖氮为118.9土43.0mg/kg,占全氮的9.1土3.2%;可溶性碱稳定态氮为497.1土205.8mg/kg,占全氮的36.2土8.3%;酸溶性腐殖质态氮为29.2土10.2mg/kg,占全氮的13土0.8%;固定态NH4+为47.2土24.3mg/kg,占全氮的3.6±1.7%;难溶性腐殖质态氮为341.3土270.8mg/kg,占全氮的22.2土11.6%。  相似文献   

10.
土壤中结合态苯氧羧酸类除草剂的测定   总被引:9,自引:0,他引:9  
利用超临界CO2流体萃取的方法提取2甲4氯(MCPA),2,4-D和除草醚在三种土壤中的结合残留.结果表明,在培养200d的时间内,MCPA的结合残留量为1.0l-5.12mg·kg-1,占添加总量的2.0-10.1%;2,4-D的结合残留量为0.24-2.65mg·kg-1,占添加总量的0.5-5.3%;除草醚的结合残留量为6.53-19.30mg·kg-1,占添加总邑的12.9—38.2%.农药结合态与游离态含量的比值随时间的延长而增加.  相似文献   

11.
Protected areas (PAs) are often implemented without consideration of already existing PAs, which is likely to cause an overrepresentation of certain biophysical conditions. We assessed the representativeness of the current PA network with regard to the world's biophysical conditions to highlight which conditions are underprotected and where these conditions are located. We overlaid terrestrial and marine PAs with information on biophysical conditions (e.g., temperature, precipitation, and elevation) and then quantified the percentage of area covered by the PA network. For 1 variable at a time in the terrestrial realm, high temperature, low precipitation, and medium and very high elevation were underrepresented. For the marine realm, low and medium sea surface temperature (SST), medium and high sea surface salinity (SSS), and the deep sea were underrepresented. Overall, protection was evenly distributed for elevation across the terrestrial realm and SST across the marine realm. For 2 variables at a time, cold and very dry terrestrial environments had mostly low protection, which was also the case for low SST and low and medium SSS across most depths for marine environments. Low protection occurred mostly in the Sahara and the Arabian Peninsula for the terrestrial realm and along the Tropic of Capricorn and toward the poles for the marine realm. Although biodiversity measures are of prime importance for the design of PA networks, highlighting biophysical gaps in current PAs adds a frequently overlooked perspective. These gaps may weaken the potential of PAs to conserve biodiversity. Thus, our results may provide useful insights for researchers, practitioners, and policy makers to establish a more comprehensive global PA network.  相似文献   

12.
Summary The adaptation of defensive secretions to their target organisms was examined for the abdominal gland secretions ofBledius furcatus, B. spectabilis andB. arenarius. Therefore the target organisms of the secretion of theseBledius species (i.e. their predators) had to be identified. At the collection sites examined these were the earwigLabidura riparia, the antCataglyphis bicolor, the flyLispe candicans, different carabids of the generaPogonus, Dichirotrichus, Dyschirius, Bembidion andCalathus and the wading birdsHaematopus ostralegus andCalidris alba. The secretion of the abdominal glands contains the toxin ptoluquinone dissolved in either-dodecalactone and 1-undecene (B. furcatus andB. spectabilis) or in octanoic acid and octyloctanoate (B. arenarius). The ratio of these solvents is species-specific. Application experiments using some of the natural insect predators (L. riparia, C. bicolor, Pogonus, Di. gustavii, Dyschirius) revealed that these solvent ratios provided a more effective deterrent than other possible ratios. Thus by combining the solvents in certain ratios, the capability of cuticular penetration and therefore the effectiveness of the defensive secretions are adapted to their natural targets.  相似文献   

13.
The politics of development includes subtexts of choice, as underpinned by community consensus (or lack of it), against the larger backdrop of a liberal democracy, with its intricate power structures that influence the choice of concepts and often lead to complicity rather than consent. A dilemma exists between the understanding of field-level practitioners and that of academics, whose understandings of progress differ. Progress can (and often does) imply long-term change across generations whereas development is often more a matter of crisis management and delivering tangible results to end-users. This makes it a bone of contention across political systems, irrespective of local or global dynamics. Development can emerge as a tool to be wielded for power and further political mileage at the expense of progress. Progress cannot be studied as a counterpoint to development as the sense of history is often missing in development interventions. Development tends to be piecemeal as its very logic often stems from the rationale of power. This is not to suggest, however, that development is only about politics; it is definitely more than the politics of everyday life and involves all of civil society that requires its critical and immediate attention. In this sense, it has become a priority for politicians with an underlying agenda designed to out-manouevre dissent and all statements of protest.  相似文献   

14.
Conservation science is a crisis discipline in which the results of scientific enquiry must be made available quickly to those implementing management. We assessed the extent to which scientific research published since the year 2000 in 20 conservation science journals is publicly available. Of the 19,207 papers published, 1,667 (8.68%) are freely downloadable from an official repository. Moreover, only 938 papers (4.88%) meet the standard definition of open access in which material can be freely reused providing attribution to the authors is given. This compares poorly with a comparable set of 20 evolutionary biology journals, where 31.93% of papers are freely downloadable and 7.49% are open access. Seventeen of the 20 conservation journals offer an open access option, but fewer than 5% of the papers are available through open access. The cost of accessing the full body of conservation science runs into tens of thousands of dollars per year for institutional subscribers, and many conservation practitioners cannot access pay‐per‐view science through their workplace. However, important initiatives such as Research4Life are making science available to organizations in developing countries. We urge authors of conservation science to pay for open access on a per‐article basis or to choose publication in open access journals, taking care to ensure the license allows reuse for any purpose providing attribution is given. Currently, it would cost $51 million to make all conservation science published since 2000 freely available by paying the open access fees currently levied to authors. Publishers of conservation journals might consider more cost effective models for open access and conservation‐oriented organizations running journals could consider a broader range of options for open access to nonmembers such as sponsorship of open access via membership fees. Obtención de Acceso Abierto a la Ciencia de la Conservación  相似文献   

15.
As landscapes continue to fall under human influence through habitat loss and fragmentation, fencing is increasingly being used to mitigate anthropogenic threats and enhance the commercial value of wildlife. Subsequent intensification of management potentially erodes wildness by disembodying populations from landscape-level processes, thereby disconnecting species from natural selection. Tools are needed to measure the degree to which populations of large vertebrate species in formally protected and privately owned wildlife areas are self-sustaining and free to adapt. We devised a framework to measure such wildness based on 6 attributes relating to the evolutionary and ecological dynamics of vertebrates (space, disease and parasite resistance, exposure to predation, exposure to limitations and fluctuations of food and water supply, and reproduction). For each attribute, we set empirical, species-specific thresholds between 5 wildness states based on quantifiable management interventions. We analysed data from 205 private wildlife properties with management objectives spanning ecotourism to consumptive utilization to test the framework on 6 herbivore species representing a range of conservation statuses and commercial values. Wildness scores among species differed significantly, and the proportion of populations identified as wild ranged from 12% to 84%, which indicates the tool detected site-scale differences both among populations of different species and populations of the same species under different management regimes. By quantifying wildness, this framework provides practitioners with standardized measurement units that link biodiversity with the sustainable use of wildlife. Applications include informing species management plans at local scales; standardizing the inclusion of managed populations in red-list assessments; and providing a platform for certification and regulation of wildlife-based economies. Applying this framework may help embed wildness as a normative value in policy and mitigate the shifting baseline of what it means to truly conserve a species.  相似文献   

16.
Abstract: In the United States, as elsewhere, a growing debate pits national energy policy and homeland security against biological conservation. In rural communities the extraction of fossil fuels is often encouraged because of the employment opportunities it offers, although the concomitant itinerant workforce is often associated with increased wildlife poaching. We explored possible positive and negative factors associated with energy extraction in the Greater Yellowstone Ecosystem (GYE), an area known for its national parks, intact biological diversity, and some of the New World's longest terrestrial migrations. Specifically, we asked whether counties with different economies—recreation (ski), agrarian (ranching or farming), and energy extractive (petroleum)—differed in healthcare (gauged by the abundance of hospital beds) and in the frequency of sexual predators. The absolute and relative frequency of registered sex offenders grew approximately two to three times faster in areas reliant on energy extraction. Healthcare among counties did not differ. The strong conflation of community dishevel, as reflected by in‐migrant sexual predators, and ecological decay in Greater Yellowstone is consistent with patterns seen in similar systems from Ecuador to northern Canada, where social and environmental disarray exist around energy boomtowns. In our case, that groups (albeit with different aims) mobilized campaigns to help maintain the quality of rural livelihoods by protecting open space is a positive sign that conservation can matter, especially in the face of rampant and poorly executed energy extraction projects. Our findings further suggest that the public and industry need stronger regulatory action to instill greater vigilance when and where social factors and land conversion impact biological systems.  相似文献   

17.
Summary Acanthoscelides obtectus (Say) is one of the most damaging pests of kidney beans,Phaseolus vulgaris L. worldwide. However, aromatic plants from the families Lamiaceae, Lauraceae, Myrtaceae and Poaceae can protect kidney beans by direct or delayed insecticidal effect, through increased adult mortality and inhibition of beetle reproduction (both oviposition and adult emergence). The efficiency of hydrodistillated and intact plants fromThymus vulgaris andT. serpyllum, Mentha piperata, Rosmarinus officinalis, Satureia hortensis, Eucalyptus globulus, Laurus nobilis, Origanum vulgare, andCymbopogon nardus was compared. For both extracts,Origanum vulgare had the best effect. The insecticidal effect was induced by more than the essential oils because no significant difference was noticed between distilled and intact plants extract. Inhibition of reproduction was particularly important. These results suggest that lipidic as well as non lipidic, allelochemicals, such as phenolics, or non-protein amino-acids, or flavonoids may be involved in the toxicity of aromatic plants to this beetle.  相似文献   

18.
A bioblitz inexpensively and quickly generates biodiversity data, but bioblitzes are often conducted with haphazard, unreplicated sampling. Results tend to be taxonomically, geographically, or temporally biased, lack metadata, and consist of lists of observed taxa that do not enable further analyses or correction for imperfect detection. A rapid, recurring, structured survey (RRSS) uses a structured sampling design and temporal and spatial replication to survey randomly selected sites on a conservation property. We participated in a loosely structured bioblitz and a subsequent RRSS at Big Canoe Creek Nature Preserve in Springville (St. Clair County), Alabama (USA) to compare observed richness derived from the 2 survey approaches. The RRSS data structure enabled us to fit models that accounted for imperfect detection to estimate abundances, occupancy probabilities, and habitat associations. The loosely structured bioblitz data could not be used in such models. We present a new integrated multispecies abundance model that we applied to avian RRSS data. Our model extension enables estimation for the community, employs data augmentation to estimate the number of undetected species, and incorporates covariates. The RRSS generated a more comprehensive and less biased list of observed taxonomic richness than the loosely structured bioblitz (e.g., 73 vs. 45 bird species and 104 vs. 63 insect families from the RRSS vs. loosely structured bioblitz, respectively). Models fit to the RRSS data identified seasonal patterns in avian community composition and allowed for estimation of habitat–occupancy relationships for insect taxa. The RRSS protocol has potential for broad transferability as a standardized, quick, and inexpensive way to inventory biodiversity and estimate ecological parameters while providing an outreach opportunity.  相似文献   

19.
Land-use change via human development is a major driver of biodiversity loss. To reduce these impacts, billions of dollars are spent on biodiversity offsets. However, studies evaluating offset project effectiveness that examine components such as the overall compliance and function of projects remain rare. We reviewed 577 offsetting projects in freshwater ecosystems that included the metrics project size, type of aquatic system (e.g., wetland and creek), offsetting measure (e.g., enhancement, restoration, and creation), and an assessment of the projects’ compliance and functional success. Project information was obtained from scientific and government databases and gray literature. Despite considerable investment in offsetting projects, crucial problems persisted. Although compliance and function were related to each other, a high level of compliance did not guarantee a high degree of function. However, large projects relative to area had better function than small projects. Function improved when projects targeted productivity or specific ecosystem features and when multiple complementary management targets were in place. Restorative measures were more likely to achieve targets than creating entirely new ecosystems. Altogether the relationships we found highlight specific ecological processes that may help improve offsetting outcomes.  相似文献   

20.
Summary Interactions were studied among alkaloid-containing legumes (Erythrina corallodendrum andSpartium junceum) and non-toxic plants (Citrus sinensis, Cucurbita moschata andEuphorbia tirucalli), several polyphagous homopterans,Aphis craccivora (Aphididae),Icerya purchasi, I. aegyptiaca (Margarodidae),Lepidosaphes ulmi (Diaspididae) andPlanococcus citri (Pseudococcidae), and some major natural enemies of these homopterans. Significant reductions in survival due to negative effects of alkaloid containing as compared with non-alkaloidal plants were recorded for the predatorsRodolia cardinalis andChilocorus bipustulatus, but not forCryptolaemus montrouzieri (Coleoptera: Coccinellidae),Chrysoperla carnea (Neuroptera: Chrysopidae) andSympherobius sanctus (Neuroptera: Sympherobiidae). The development time of the larvae or pupae ofR. cardinalis, C. carnea andS. sanctus was longer on the toxic plants than on the non-toxic ones. The percentage of parasitism ofA. craccivora collected from the non-alkaloidal plantsVicia palaestina andMelilotus albus was much higher than that onS. junceum. The parasitoid complexes ofA. craccivora differed between both plant groups. The nutritive value of honeydew ofI. purchasi andA. craccivora, as expressed by the life span ofEncyrtus infelix (Hymenoptera: Encyrtidae) adults, was also investigated. Life spans were significantly longer when the wasps fed on honeydew produced on non-alkaloidal plants (C. sinensis andPittosporum tobira) than on alkaloid containing plants whenI. purchasi — but notA. craccivora — was the producer. It is suggested that the chemical defense ofE. corallodendrum andS. junceum is exploited by polyphagous phytophages to reduce predation. In nature, population growth and density of four of the investigated homopterans are conspicuously high when they developed on the alkaloid containing plant species, and very low on non-alkaloid plants. The efficiency of their natural enemies may be reduced by sequestration of alkaloids (or other toxic plant compounds) or their transfer into excreted honeydew. Therefore it is assumed that a generalist phytophagous homopteran may be protected from its natural enemies, although at different rates of efficiency, if it can safely sequester the host allelochemical when it develops on toxic species within its host range.  相似文献   

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