Identifying the major sources contributing to air pollution is a problem of fundamental importance in developing effective air quality management plans. Multivariate receptor modeling aims to achieve this goal by unfolding the air pollution data into components associated with different sources based on factor analysis models. We analyze the PM10 data obtained from 17 monitoring sites in Seoul to locate the major source regions using multivariate receptor modeling. The model uncertainty caused by the unknown number of sources and identifiability conditions is assessed by posterior probability of each model. The estimated source spatial profiles seem to be consistent with our prior expectation about the PM10 sources in Seoul. 相似文献
Particulate matter (PM) is both a major driver of climate change and a source of toxicity for health. In the upper atmosphere, particulate matter modifies the earth radiation budget, cloud formation and acts as a reaction center for air pollutants. In the lower atmosphere, particulate matter changes atmospheric visibility and alters biogeochemical cycles and meteorology. Most critical effects are observed in ambient air, where particulate matter degrades human health. Here we review the sources, spatial and temporal variability, and toxicity of PM10, the particulate matter having particle sizes 10 micrometers or less in diameter, in world regions. For that we analyzed information from the world wide web and databases from government organizations after the year 2000. Findings show that PM10 is a major risk in both developed and developing countries. This risk is more severe in Asian countries compared to Europe and USA, where decreasing trends are recorded during the last two decades. Meteorological factors modify particulate matter variations at local and regional levels. PM2.5/PM10 ratio provides information of particulate matter sources under different environment conditions. Crustal matter, road traffic and combustion of fuels are major sources of particulate matter pollution. Health studies indicate that long-term exposure to particulate matter has multiple health effects in people from all age groups. Identification of possible sources and their control with regular epidemiological monitoring could decrease the impact of particulate matter pollution. 相似文献
Air quality in an urban atmosphere is regulated by both local and distant emission sources. For air quality management in urban areas, identification of sources and their relationships with local meteorology and air pollutants are essential. The critical condition of air quality in Indo-Gangetic plain is well known, but lack of data on both local and distant emission sources limits the scope of improving air quality in this region. Concentrations of particulate matter of size lower than 10 μm (PM10) were assessed in the highly urbanized Varanasi city situated in middle Indo-Gangetic plain of India from 2014 to 2017, to identify the distant air pollution sources based on trajectory statistical models and local sources by conditional bivariate probability function. Modifying effects of meteorology and air pollutants on PM10 were also explored. Mean PM10 concentration for the study period was 244.8 ± 135.8 μg m?3, which was 12 times higher than the WHO annual guideline. Several distinct sources of traffic as the major source of PM10 were identified in the city. Trajectory statistical models like cluster analysis, potential source contribution function and concentration-weighted trajectory showed significant contributions from north-west and eastern directions in the transport of polluted air masses to the city. Dew point, wind speed, temperature and ventilation coefficient are the major factors in PM10 formation and dispersion. 相似文献
Urban energy consumption is one of the most important causes of air pollution. Air pollution-oriented ecological risk assessment is of great significance to the promotion of urban environmental protection. This paper focuses on ecological risk in Xiamen city caused by air pollutant discharge from urban energy consumption. The Long-range Energy Alternatives Planning model was used to establish two scenarios of energy consumption in Xiamen city, and based on different scenarios, we estimated urban energy consumption and discharge quantity of air pollutant (DQAP). A box model and an expert scoring method were used to calculate the air pollution burden (APB) of SO2, NO2, CO, PM10 and PM2.5 and to obtain the probabilities of different air pollution loads. An ecological risk assessment model was developed and utilized to predict Xiamen city’s ecological risks in 2020. The results showed that under an energy-saving scenario, the ecological risks for PM2.5, SO2 and NO2 are high, whereas the ecological risks for CO and PM10 are low. Under a baseline scenario, the ecological risks for PM2.5, SO2 and NO2 are moderate, whereas the ecological risks for CO and PM10 are low. In addition, the APB of SO2, NO2, CO, and PM2.5, but not of PM10, is predicted to rise. In the simulation, energy generation from coal is the main source of air pollution. Although the DQAP from automobiles is not high, it is predicted to rise year-on-year. In summary, the ecological risk due to pollution in Xiamen city is high, and the main pollutants are SO2, NO2 and PM2.5. 相似文献
The Eulerian Chemistry-Transport Model BelEUROS was used to calculate the concentrations of airborne PM10 and PM2.5 over Europe. Both primary as well as secondary particulate matter in the respirable size-range was taken into account. Especially PM2.5 aerosols are often formed in the atmosphere from gaseous precursor compounds. Comprehensive computer codes for the calculation of gas phase chemical reactions and thermodynamic equilibria between compounds in the gas-phase and the particulate phase had been implemented into the BelEUROS-model. Calculated concentrations of PM10 and PM2.5 are compared to observations, including both the spatial and daily, temporal distribution of particulate matter in Belgium for certain monitoring locations and periods. The concentrations of the secondary compounds ammonium, nitrate and sulfate have also been compared to observed values. BelEUROS was found to reproduce the observed concentrations rather well. The model was applied to assess the contribution of emissions derived from the sector agriculture in Flanders, the northern part of Belgium, to PM10- and PM2.5-concentrations. The results demonstrate the importance of ammonia emissions in the formation of secondary particulate matter. Hence, future European emission abatement policy should consider more the role of ammonia in the formation of secondary particles. 相似文献
The objective of this paper is to propose a hybrid approach for the source apportionment of primary and secondary species of PM2.5 in the city of Tangshan. The receptor-based PMF (Positive Matrix Factorization) is integrated with the emission inventory (EI) to form the first hybrid method for the source apportionment of the primary species. The hybrid CAMx-PSAT-CP (Comprehensive Air Quality Model with Extensions–Particulate Source Apportionment Technology–Chemical Profile) approach is then proposed and used for the source apportionment of the secondary species. The PM2.5 sources identified for Tangshan included the soil dust, the metallurgical industry, power plants, coalfired boilers, vehicles, cement production, and other sources. It is indicated that the PM2.5 pollution is a regional issue. Among all the identified sources, the metallurgy industry was the biggest contribution source to PM2.5, followed by coal-fired boilers, vehicles and soil dust. The other-source category plays a crucial role for PM2.5, particularly for the formation of secondary species and aerosols, and these other sources include non-specified sources such as agricultural activities, biomass combustion, residential emissions, etc. The source apportionment results could help the local authorities make sound policies and regulations to better protect the citizens from the local and regional PM2.5 pollution. The study also highlights the strength of utilizing the proposed hybrid approaches in the identification of PM2.5 sources. The techniques used in this study show considerable promise for further application to other regions as well as to identify other source categories of PM2.5.
Investigations on the fluctuation in PM10 air pollution in Volos, a medium-sized industrialized port city in the Mediterranean, are presented for the 5-year period between 2009 and 2014. The levels detected have been examined in relation to legislatively set limits, sampling year, and day of the week. A PM10 spring sampling campaign has been performed in 2014 and metals and other elements in the PM10 mass have been quantified. Source origin has been attempted for the latter sampling campaign and human health risk has been assessed. Results show compliance with the mean annual value of 40 μg m?3 of 2008/50/EC for the city; however, exceedances of the daily quality standard of 50 μg m?3 were frequently recorded. Shifts in PM10 concentrations and in contributing sources have been recorded; nevertheless, longer duration data series are needed for safe deductions. Element measurements have enabled source identification for early summer of 2014, with Earth's crust minerals and anthropogenic sources being the main factors. Cumulative non-carcinogenic risk may exceed the threshold value of 1. Possible involvement of sea salt aerosol and desert dust long-range transport has also been assessed. These results may furnish databases on PM pollution of Greek cities as well as other Mediterranean urban centers with similar characteristics. 相似文献
A total of 168 PM10 samples were collected during the year of 2005 at eight sites in the city of Wuxi in China. Fifteen chemical elements, three water-soluble ions, total carbon and organic carbon were analyzed. Six source categories were identified and their contributions to ambient PM10 in Wuxi were estimated using a nested chemical mass balance method that reduces the effects of colinearity on the chemical mass balance model. In addition, the concentrations of secondary aerosols, such as secondary organic carbon, sulfate and nitrate, were quantified. The spatially averaged PM10 was high in the spring and winter (123 ??g·m?3 and low in the summer-fall (90 ??g·m?3). According to the result of source apportionment, resuspended dust was the largest contributor to ambient PM10, accounting for more than 50% of the PM10 mass. Coal combustion (14.6%) and vehicle exhaust (9.4%) were also significant source categories of ambient PM10. Construction and cement dust, sulfates, secondary organic carbon, and nitrates made contributions ranging between 4.1% and 4.9%. Other source categories such as steel manufacturing dust and soil dust made low contributions to ambient PM10. 相似文献
Indoor and outdoor air pollution is known to contribute to increased lung cancer incidence. This study is the first to address the contribution of home heating fuel and geographical course particulate matter (PM10) concentrations to lung cancer rates in New Hampshire, USA. First, Pearson correlation analysis and geographically weighted regression were used to investigate spatial relationships between outdoor PM10 and lung cancer rates. While the aforementioned analyses did not indicate a significant contribution of PM10 to lung cancer in the state, there was a trend towards a significant association in the northern and southwestern regions of the state. Second, case-control data were used to estimate the contributions of indoor pollution and secondhand smoke to the risk of lung cancer with adjustment for confounders. Increased risk was found among those who used wood or coal to heat their homes for more than 10 winters before the age of 18, with a significant increase in risk per winter. Resulting data suggest that further investigation of the relationship between heating-related air pollution levels and lung cancer risk is needed. 相似文献
Particulate pollution was a critical challenge to the promise of good air quality during the 2008 Beijing Olympic Games, which took place from August 8th to 24th. To ensure good air quality for the Games, several temporary emission control measures were implemented in Beijing and surrounding areas. Ambient particulate matter concentration decreased significantly during the Olympic period; however, it is difficult to distinguish the effectiveness of those control measures since meteorology also affects ambient PM2.5 concentration. In this work, a multiple linear regression model based on continuous field monitoring at a roadside site was conducted to evaluate the effects of meteorology and emission control measures on the reduction of PM2.5 during the 2008 Olympic Games. The hourly data set was divided into two time periods, the no control period, June 22nd to July 4th, and the control period, July 28th to August 21st. The response variable was PM2.5 and the meteorology covariates used in the model were hourly temperature, dew point temperature, wind speed and precipitation. Wind direction was not a significant predictor of PM2.5 levels in either the control or the no control period. Using the meteorologically-based regression coefficients from the two time periods, meteorology was found to contribute to at least a 16% reduction in PM2.5 levels in the roadside microenvironment; while the pollution control measures contributed to at least a 43% reduction in PM2.5 levels. 相似文献
We estimate the effect of short-term air pollution exposure (PM2.5 and ozone) on several categories of crime, with a particular emphasis on aggressive behavior. To identify this relationship, we combine detailed daily data on crime, air pollution, and weather for an eight-year period across the United States. Our primary identification strategy employs extremely high dimensional fixed effects and we perform a series of robustness checks to address confounding variation between temperature and air pollution. We find a robust positive effect of increased air pollution on violent crimes, and specifically assaults, but no relationship between increases in air pollution and property crimes. The effects are present in and out of the home, at levels well below Ambient Air Pollution Standards, and PM2.5 effects are strongest at lower temperatures. The results suggest that a 10% reduction in daily PM2.5 and ozone could save $1.4 billion in crime costs per year, a previously overlooked cost associated with pollution. 相似文献
Intense mining, smelting, and tailing activities of polymetallic ore deposits have affected the environment in Nandan County, Guangxi, China. Samples of particulates with aerodynamic diameters low or equal 10 μm (PM10) were collected in Nandan County to investigate the concentrations of and health risks posed by 17 metals and metalloids in the PM10. The metal and metalloid concentrations were lower than those found in other industrial cities. The mean Cr concentration was 7.48 ng/m3. Significant higher metal and metalloid concentrations were found in PM10 from mining areas (Dachang and Chehe) than from the control area (Liuzhai) (p < 0.05). Principal component analysis indicated that the main sources of Ba, Co, Cr, Fe, K, Mg, Mo, Na, and Sr were resuspension of the soil produced through mineral erosion, the main sources of As, Cd, Cu, Pb, Sb, and Zn were smelting and mining activities, and the main source of Ni was fossil fuel combustion. Higher non-carcinogenic and carcinogenic risks were posed in Dachang and Chehe than in Liuzhai. The non-carcinogenic risks posed to adults and children by individual metals and metalloids in PM10 at all the sites were low, but the non-carcinogenic risks posed to children by all the metals and metalloids together exceeded the safe level (i.e., risk value > 1). The carcinogenic risks posed by Cd, Ni, and Pb were negligible at all sites, while As, Co, and Cr posed potential carcinogenic risks to the residents.
Air pollution poses a serious threat to human health in Asia. This study analyzes the association of air pollutants and greenness with incidence rates of allergic rhinitis in Seoul at the administrative district level to gain insight into district-level urban policies to improve public health. A spatial regression model is constructed to investigate the correlation between allergic rhinitis incidence rates and five air pollutants measured at 128 air pollution monitoring stations around Seoul: sulfur dioxide (SO2), particulate matter less than 10 μm (PM10), ozone (O3), nitrogen dioxide (NO2), and carbon monoxide (CO). The allergic rhinitis incidence data are derived from the National Health Insurance Service’s database that includes the number of allergic rhinitis-related clinic visits by the patients over 20 years of age and living in Seoul. A kriging geostatistical interpolation was used to estimate average air pollution level of 423 administrative districts. To assess pollen concentrations that can affect allergic rhinitis, the average normalized difference vegetation index (NDVI) is measured based on the urban greenness. The model, controlling for built environment and socio-economic attributes, identifies the possibility of a weak association between allergic rhinitis incidence rates and carbon monoxide levels. The NDVI value is negatively correlated with allergic rhinitis incidence rates, implying a complicated aspect in relation to the effect of urban greenness. 相似文献
Seasonal pattern of transport pathways and potential sources of PM2.5 in Chengdu during 2012–2013 were investigated based on hourly PM2.5 data, backward trajectories, clustering analysis, potential source contribution function (PSCF), and concentration-weighted trajectory (CWT) method. The annual hourly mean PM2.5 concentration in Chengdu was 97.4 mg·m–3. 5, 5, 5 and 3 mean clusters were generated in four seasons, respectively. Short-distance air masses, which travelled within the Sichuan Basin with no specific source direction and relatively high PM2.5 loadings (>80 mg·m–3) appeared as important pathways in all seasons. These short pathways indicated that emissions from both local and surrounding regions of Chengdu contributed significantly to PM2.5 pollution. The cities in southern Chengdu were major potential sources with PSCF>0.6 and CWT>90 mg·m–3. The northeastern pathway prevailed throughout the year with higher frequency in autumn and winter and lower frequency in spring and summer. In spring, long-range transport from southern Xinjiang was a representative dust invasion path to Chengdu, and the CWT values along the path were 30-60 mg·m–3. Long-range transport was also observed in autumn from southeastern Xinjiang along a northwesterly pathway, and in winter from the Tibetan Plateau along a westerly pathway. In summer, the potential source regions of Chengdu were smaller than those in other seasons, and no long-range transport pathway was observed. Results of PSCF and CWT indicated that regions in Qinghai and Tibet contributed to PM2.5 pollution in Chengdu as well, and their CWT values increased to above 30 mg·m–3 in winter.
Toxic elements in the atmosphere can enter and accumulate in the human body, seriously impacting human health. In this study, we analyzed a 14-year (1995-2008) measurement of three toxic elements (As, Cd and Cr) in PMlo in Hong Kong, China. The pollution of these toxic elements in Hong Kong was not serious. The trend analysis showed that As and Cr in PM10 increased at a statistically significant level (p〈0.05) during the 14-year period, while the Cd in PM10 did not change significantly. Typical seasonal variations were observed for all three toxic elements, largely in relation to the Asian monsoon. Hourly 10-day backward trajectories were computed and cate- gorised into four groups. The continental air masses showed much higher concentrations of the three toxic elements than the marine air masses. The abundances of As and Cd in the PM10 were much higher in the continental air masses than those in the marine air masses, while the abundances of Cr showed an opposite pattern. The trends of the three toxic elements in East China's air mass were consistent with those in the overall data set ofHong Kong. Examination of the toxic element data recorded at urban sites and a roadside site also indicated a large contribution of external air masses to particulate As and Cd in Hong Kong. These results suggest that the long-range transport from the mainland of China is the dominant contributor to particulate As and Cd, while both local and long-distance sources determine the particulate Cr in Hong Kong. 相似文献
This work evaluates the influence of energy consumption on the future air quality in Beijing, using 2000 as the base year and 2008 as the target year. It establishes the emission inventory of primary PM10, SO2 and NOx related to energy utilization in eight areas of Beijing. The air quality model was adopted to simulate the temporal and spatial distribution of each pollutant concentration in the eight urban areas. Their emission, concentration distribution, and sectoral share responsibility rate were analyzed, and air quality in 2008 was predicted. The industrial sector contributed above 40% of primary PM10 and SO2 resulting from energy consumption, while vehicles accounted for about 65% of NOx. According to the current policy and development trend, air quality in the eight urban areas could become better in 2008 when the average concentrations of primary PM10, SO2 and NO2 related to energy utilization at each monitored site are predicted to be about 25, 50 and 51 μg/m3, respectively. 相似文献
The development of models that provide accurate spatio-temporal predictions of ambient air pollution at small spatial scales is of great importance for the assessment of potential health effects of air pollution. Here we present a spatio-temporal framework that predicts ambient air pollution by combining data from several different monitoring networks and deterministic air pollution model(s) with geographic information system covariates. The model presented in this paper has been implemented in an R package, SpatioTemporal, available on CRAN. The model is used by the EPA funded Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air) to produce estimates of ambient air pollution; MESA Air uses the estimates to investigate the relationship between chronic exposure to air pollution and cardiovascular disease. In this paper we use the model to predict long-term average concentrations of \(\text {NO}_{x}\) in the Los Angeles area during a 10 year period. Predictions are based on measurements from the EPA Air Quality System, MESA Air specific monitoring, and output from a source dispersion model for traffic related air pollution (Caline3QHCR). Accuracy in predicting long-term average concentrations is evaluated using an elaborate cross-validation setup that accounts for a sparse spatio-temporal sampling pattern in the data, and adjusts for temporal effects. The predictive ability of the model is good with cross-validated \(R^2\) of approximately \(0.7\) at subject sites. Replacing four geographic covariate indicators of traffic density with the Caline3QHCR dispersion model output resulted in very similar prediction accuracy from a more parsimonious and more interpretable model. Adding traffic-related geographic covariates to the model that included Caline3QHCR did not further improve the prediction accuracy. 相似文献