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1.
改性沸石吸附水中有机物的试验研究   总被引:11,自引:0,他引:11  
本试验采用溴化十六烷基三甲胺(HDTMA)制备改性沸石,研究了改性沸石吸附水中有机物的影响因素.结果表明,改性沸石对2,4-二氯苯酚(2,4-DCP)具有很好的吸附效果,绘制了改性沸石吸附2,4-DCP的吸附等温线。  相似文献   

2.
气相色谱-质谱法表征炼油厂外排废水中的有机组分   总被引:6,自引:0,他引:6  
将水中的有机组分划分为悬浮性有机物(SOC)、溶解性可吸附有机物(EOC)及溶解性不可吸附有机物(NEOC)三类.分别用G3型耐酸滤过漏斗及GDX-502树脂分离和富集了某炼油厂生化处理外排废水中的SOC及EOC,漏斗滤出的和GDX-502树脂富集的有机物分别用二氯甲烷洗脱和Soxhlet提取,提取物经干燥、浓缩后,用GC/MS进行分析.结果表明该废水TOC为27.4mg/L,SOC、EOC及NEOC分别占44.5%、28.1%及27.4%.SOC中共鉴定出有机组分44种,包括正构烷烃21种、异构烷烃15种、烯烃6种及环烷烃2种,其中Ci5-C28正构烷烃的含量相对较高;EOC中共鉴定出有机组分78种,包括脂肪烃18种、芳烃12种、苯酚类10种、吡啶类7种、醇6种、酮10种、醛2种、酞酸酯3种及其它化合物10种,其中苯酚类、邻苯二甲酸正丁酯及1-甲基环己醇含量相对较高.  相似文献   

3.
炼焦过程中挥发性有机物成分谱特征初步研究   总被引:16,自引:0,他引:16  
通过吸附管采样和热脱附/GC/MS分析研究了土焦炉生产过程中挥发性有机物排放和机械炼焦厂外大气中挥发性有机物分布.土法炼焦过程中TVOC排放高达1782.2μg/m3.成分分析显示,土法炼焦烟气和机械炼焦厂外大气中挥发性有机物包含苯系物、烷烃、卤代烃和萜烯类,其中以苯系物为主,分别占75.63%和72.25%.BTEX比值分析显示,炼焦排放挥发性有机物的特征有别于汽车等交通排放.  相似文献   

4.
监测方法研究用改进的凯氏法测定生物样品和水样中总氮方法的探讨邢书才 杨  ( 1  1)………………………………………微波消化—固相萃取光度法测定生物样品中铜的研究台 希 胡秋芬 杨光宇 尹家元 艾华林 ( 1  3)…………水中苯、苯酚在有机膨润土上的共同吸附作用研究苏玉红 付军怀 ( 1  6 )………………………………………………双波长标准加入法测微量镍丁邦琴 ( 1  10 )…………………………………………………………………………………原子吸收光谱法测定废气中的锡陈 谦 毛志瑛 ( 1  12 )……………………………………  相似文献   

5.
有机物对环境的污染日益受到各国的关注,尤其是多氯代二苯并-p-二类(PCDDs)、多氯代二苯呋喃(PCDFs)和PCBs等。在我国新修订的“污水综合排放标准”中,也增加了许多有机氯化物项目;本文就二类等有机氯化物的环境监测分析方法作以概括介绍。  相似文献   

6.
以多溴联苯醚典型单体2,2′,4,4′?四溴联苯醚(BDE?47)为研究对象,阐明了其在土壤矿物质与有机质上的吸附解吸行为及特征。结果表明:土壤中无机矿物质对BDE?47的吸附贡献不大,而有机质是调控BDE?47在土壤中吸附行为的关键组分;有机质对BDE?47的吸附能力与其有机碳含量和物理化学特性相关;BDE?47在腐殖酸上的解吸存在显著的滞后现象。  相似文献   

7.
采用热脱附和气相色谱-质谱联用技术研究了深圳市宝安区环境空气中挥发性有机物的组成,从中鉴定出18种有机化合物,并通过对其中5种苯系物的定量分析结果,讨论了宝安区环境空气有机污染状况。  相似文献   

8.
对常州某废弃农药生产场地地下水中挥发性有机物污染状况和健康风险进行了调查评价。结果表明,该场地地下水中挥发性有机物污染以苯系物、氯代苯类和氯代烃类为主;部分点位地下水健康风险评价结果超出可接受范围,可能危害人体。  相似文献   

9.
废气净化装置排气中有机污染物的气相色谱/质谱分析   总被引:2,自引:0,他引:2  
利用活性炭对有机污染物具有较强的吸附和定量解吸的能力,对废气净化装置排气中的有机污染物进行吸附采样、溶剂解吸及气相色谱/质谱分析,可以克服气相色谱法依赖标样保留值定性的不足,扩大了定性范围,提高了准确度。  相似文献   

10.
采用质量分数为1%的生物炭(C)和生物炭负载膨润土( CB )改良嘉陵江、渠江和涪江(川渝段)8个不同河岸土样,并以土柱实验模拟铜在各改良土样中的迁移和形态变化特征(原土样作为对照)。结果表明:C和CB 的添加均有利于沿岸土对铜的吸附,吸附能力和穿透时间表现为CB 改良土样>C改良土样>原土样;各改良沿岸土样对铜吸附能力表现为上游土样强于下游。供试土柱中铜累积量为16.43 g/kg~56.54 g/kg,且表现为CB改良土样>C改良土样>原土样的趋势。铜结合形态以碳酸盐结合态比例最大,铁锰氧化态次之,可交换态和有机态较少。  相似文献   

11.
国内外二恶英研究初探   总被引:5,自引:0,他引:5  
总结了国际上近年来环境中二恶英的研究成果及进展概况。主要分挤二恶英的毒性及来源,综合国内外有关二恶英的绝大部分研究成果,并简要提出二恶英的防治措施。  相似文献   

12.
新疆生态环境质量综合评价研究   总被引:8,自引:2,他引:8  
合适的评价指标体系对正确评价区域的生态环境质量起关键的决定性作用。本文综合前人的研究成果,应用RS和GIS技术,采用综合指数评价法,对全疆区域的生态环境质量进行评价、排序及分级,由此得出符合实际的全疆生态环境质量状况。结果表明,全疆生态环境质量总体较差,北疆生态环境质量优于南疆,北疆西部生态环境质量优于北疆东部地区。  相似文献   

13.
对城市生活垃圾的分类回收、处理进行了探讨,对完善城市基础设施建设,改善投资环境将起到重要作用。  相似文献   

14.
塔里木河上游阿克苏地区土地利用变化研究   总被引:3,自引:0,他引:3  
利用2000—2002年新疆阿克苏地区TM影像解译结果,对阿克苏地区土地利用现状及动态变化进行了分析,进而对该地区主要生态环境问题及相应对策做了简要论述。  相似文献   

15.
Our laboratory investigation aimed at assessing to what extent suspended particles could adsorb formaldehyde, allowing it, when inhaled, to penetrate deeper into the lung. We used two types of pure soot, N-220 and N-660 (the former being a highly active oil furnace soot with smaller particles and a larger surface area than the latter), because of their chemical inactivity and the adsorptive properties. The results obtained in experimental conditions showed that soot particles could bind 2.3 to 50.2% of formaldehyde, depending on the particle size, relative humidity, amount of particles and the duration of the contact. The recovery of formaldehyde from the particles was also tested. Further investigation is planned under realistic conditions.  相似文献   

16.
Female masculinisation (FM) in gastropods (imposex, intersex and ovo-testis) has been documented in > 260 species globally. Biomonitoring studies use FM to indirectly assess the presence of tributyltin (TBT), a once popular biocide in antifouling paint, which has since been regulated. Laboratory studies confirm that FM in gastropods can be induced not only by TBT, but other tin (Sn) compounds, Sn "cocktails", steroids, and other contaminants such as Aroclor 1260. Even though FM in gastropods in the field has been attributed to TBT from boating activity, there is evidence that imposex occurred prior to the advent use of TBT in the 1960s, and for some species imposex occurs naturally. There are roughly 42 species that do not elicit a FM response even if they are exposed to TBT under laboratory conditions, collected sympatrically with other species displaying FM, and/or have TBT in their tissues. A geographic analysis of field studies in four regions indicates that the bulk of studies were conducted in Europe > Asia and Oceania > North America > Latin America. More data are needed regarding FM in Africa, the Middle East, and Latin America since data regarding the masculinisation of female gastropods in these areas are lacking. The most studied gastropod species used in TBT biomonitoring studies is the dogwhelk, Nucella lapillus. This review summarizes the progression of the literature from 1962 to 2009 outlining how the terminology, science, and theories have evolved over time.  相似文献   

17.
Integrated Environmental Assessment (IEA) can be loosely defined as policy‐relevant, multidisciplinary research on environmental issues. Many, diverse activities in this broad field are ongoing, but the approaches lack the structure, standardization and quality control common in disciplinary research. IEA has three stages: “structuring the problem”, “analyzing the problem” and “communicating the findings and insights”. Each stage has its inherent difficulties, not least because problem definition and analysis are neither separable nor unambiguous nor unique. Difficulties are exacerbated in the first and third stages by the necessity for science and policy to work together. Difficulties are exacerbated in the second stage by the necessity of different scientific disciplines to cooperate. The European Forum on Integrated Environmental Assessment is an initiative to improve scientific quality and policy‐relevance of IEA, by organizing two series of workshops, one looking in detail at current and desired scientific practices, the other reviewing current and establishing further applications of IEA to environmental issues in Europe. This revised version was published online in July 2006 with corrections to the Cover Date. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

18.
餐饮业油烟的形成与危害及净化技术浅议   总被引:1,自引:0,他引:1  
针对餐饮业油烟污染问题,阐述了餐饮油烟气的形成过程、危害以及目前国内市场上流通的几种油烟净化方法,并根据吐鲁番地区的实际监测情况对其进行探讨。  相似文献   

19.
研究发现 ,三种不同配制方法的磷酸盐缓冲液 ,用于异烟酸 -吡唑啉酮分光光度法测定氰化物时 ,无显著性差异 ;对吡啶 -巴比妥酸分光光度法 ,由于盐效应的影响 ,采用小剂量配制的缓冲液 ,反应的相关性好且灵敏度高  相似文献   

20.
根据对深南东路环境空气的监测及车流量、气象条件的调查,分析机动车及气象因素对深圳市环境空气质量的影响。根据分析可知,机动车尾气是深圳市环境空气中污染物的主要来源,但污染程度不断变化的主要原因是风速,深圳市环境空气中污染物浓度与风速有着非常显著的负相关。  相似文献   

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