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1.
以高有机硫北宿烟煤为研究对象,在对石灰石中各组分进行固硫试验的基础上,对固硫能力较强的CaCO3,Na2CO3和K2CO3在不同温度,不同固硫剂用量条件下进行了固硫试验研究,并利用改进的自动测硫仪对CaCO3,NaCO3和K2CO3作固硫剂时固硫型煤的硫析出特性进行了研究。 相似文献
2.
汽车尾气中NOx再燃烧过程的动力学 总被引:1,自引:0,他引:1
为了阐明汽车尾气中NOx再燃烧的动力学进程,以甲醛和NO2作为探针分子,通过FT-IR跟踪研究了反应体系不听民 HCO自由基与NO2反应的动力学。结果表明,反应的主要产物中包括CO、CO2、NO、HONO和H2O等分子,经长时间的反应,当体系中的NO2基本耗尽时,才有少量的N2O生成,这些产物分子分别是在几个不同的途径的连串反应在形成的。从体系中CO和CO2的生成量,测定了主反应的歧化反应速率比, 相似文献
3.
用TPD,TPSR-MS活性评价等方法,用Cu-Zn-Al催化剂,对CO2加氢合成甲醇的原料气掺入适量CO2进行了研究。结果表明CO2能占据催化剂表面部分CO2的吸附位,能抑制CO2加氢的逆水汽变换反应和促进甲醇合成,从而大大提高了CO2加事成甲醇的选择性和收率。 相似文献
4.
运用微反技术考察了CrOX负载型催化剂对CO+O2和CO+NO反应的催化活性。研究了微量Pd加和CrOX基双组元催化剂对上述反应的催化活性,中间产物N2O生成和N2生成的影响。 相似文献
5.
汽车排气净化催化剂的研究 总被引:5,自引:0,他引:5
研究了CuO/r-Al2O3催化剂对正已烷的氧化活性及CuO负载量对活性的影响;通过CO-流动法技术考察了在CuO/r-Al2O3上添加稀土CeO2在贫氧和富氧条件下对CO的氧化活性。结果表明稀土CeO2的添加提高了催化剂在贫氧条件下的氧化活性;该催化剂台架试验结果亦表明,催化剂具有较好的一氧化碳(CO)和烃类(HC)的氧化能力。 相似文献
6.
半导体复合系光催化降解水溶性染料研究 总被引:15,自引:0,他引:15
研究了半导体复合体系ZnO-CuO-H2O2-air对水溶性染料活性艳红X-3B等六种有机物质的光催化降解处理,得到了较高的脱色效果和COD去除率。讨论了不同染料光解难易的原因以及脱色率和COD去除率的差异。 相似文献
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Fe^2+—H2O2氧化法处理氨基J酸工业废水的研究 总被引:13,自引:0,他引:13
用Fe^2+-H2O2氧化法处理氨基J酸工业废水。结果表明,当溶液pH=1-3,H2O2和Fe^2+用量分别为H2O2:Fe^2+10:1,H2O2:CODCr=2g:g时,J酸废水的CODCr去除率达66.7%,氨基去除率达68.4%。处理后的废水BOD5/CODCr=0.5,已达到生化处理的要求。该法可作为氨基J酸废水的预处理方法。 相似文献
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10.
O3—H2O2组合法处理染料中间体废水的研究 总被引:4,自引:0,他引:4
报道了O3-H2O2组合法处理含有磺酸基团的萘系染料中间体废水的试验结果。对COD约为1600mg/l的某高浓度染料中间体废水,用5.1gO3/l和2.0gH2O2/l进行处理,可达到约60%的COD及色度去除率,并使BOD/COD的比值超过0.3,为后续生化处理创造了条件。 相似文献
11.
Kushwaha Omkar Singh Uthayakumar Haripriyan Kumaresan Karthigaiselvan 《Environmental science and pollution research international》2023,30(10):24927-24948
Environmental Science and Pollution Research - In this study, we are reporting a novel prediction model for forecasting the carbon dioxide (CO2) fixation of microalgae which is based on the hybrid... 相似文献
12.
Effects of trifluralin on soil microbial populations and the nitrogen fixation activities 总被引:6,自引:0,他引:6
Hang M Zhongyun C Yuhua Z Meichi C 《Journal of environmental science and health. Part. B》2001,36(5):569-579
Effects of trifluralin on soil microbial populations and the nitrogen fixation activity of nitrogen-fixing bacteria Azotobacter chroococcum and Bradyrhizobium japonicum and the decomposition of trifluralin by soil microorganisms were studied. Trifluralin at lower concentrations from 0.5 mg microg(-1) dry soil to lower than 10.0 mg microg(-1) dry soil appeared to stimulate the growth of soil bacteria, actinomycetes, mould, and the pure cultures of Br. japonicum and A. chroococcum. Not only the colony amounts of these two species of nitrogen-fixing bacteria increased, grown on agar medium containing lower concentrations of trifluralin, but also these colonies also enlarged in size and appeared obviously in shorter formation time. However, trifluralin at higher concentrations would inhibit the development of microbial colonies both in amount and size. Trifluralin inhibited the activity of acetylene reduction of A. chroococcum when it was added at the same time of inoculation with A. chroococcum, but it showed a noteworthy stimulation to nitrogen fixation of A.chroococcum when it was put into culture after the cells of the nitrogen-fixing bacterium had grown well. The observation that soil microorganisms could use trifluralin as sole carbon and nitrogen resources for their growth, indicated that microorganisms could decompose trifluralin well. 相似文献
13.
Impact of composting strategies on the treatment of soils contaminated with organic pollutants 总被引:4,自引:0,他引:4
Chemical pollution of the environment has become a major source of concern. Studies on degradation of organic compounds have shown that some microorganisms are extremely versatile at catabolizing recalcitrant molecules. By harnessing this catabolic potential, it is possible to bioremediate some chemically contaminated environmental systems. Composting matrices and composts are rich sources of xenobiotic-degrading microorganisms including bacteria, actinomycetes and lignolytic fungi, which can degrade pollutants to innocuous compounds such as carbon dioxide and water. These microorganisms can also biotransform pollutants into less toxic substances and/or lock up pollutants within the organic matrix, thereby reducing pollutant bioavailability. The success or failure of a composting/compost remediation strategy depends however on a number of factors, the most important of which are pollutant bioavailability and biodegradability. This review discusses the interactions of pollutants with soils; look critically at the clean up of soils contaminated with a variety of pollutants using various composting strategies and assess the feasibility of using composting technologies to bioremediate contaminated soil. 相似文献
14.
Lapinskiene A Martinkus P Rebzdaite V 《Environmental pollution (Barking, Essex : 1987)》2006,142(3):432-437
The goal of this study was to compare diesel fuel to biodiesel fuel by determining the toxicity of analyzed materials and by quantitatively evaluating the microbial transformation of these materials in non-adapted aerated soil. The toxicity levels were determined by measuring the respiration of soil microorganisms as well as the activity of soil dehydrogenases. The quantitative evaluation of biotransformation of analyzed materials was based on the principle of balancing carbon in the following final products: (a) carbon dioxide; (b) humus compounds; (c) the remainder of non-biodegraded analyzed material; and (d) intermediate biodegradation products and the biomass of microorganisms. The results of these studies indicate that diesel fuel has toxic properties at concentrations above 3% (w/w), while biodiesel fuel has none up to a concentration of 12% (w/w). The diesel fuel is more resistant to biodegradation and produces more humus products. The biodiesel is easily biotransformed. 相似文献
15.
Biodegradation of 4-nonylphenol in seawater and sediment 总被引:15,自引:0,他引:15
Ekelund R Granmo A Magnusson K Berggren M Bergman A 《Environmental pollution (Barking, Essex : 1987)》1993,79(1):59-61
Biodegradation of 14C-labelled nonylphenol at the concentration 11 microg litre (-1) in seawater has been estimated by collection and quantification of the formed labelled carbon dioxide. Initially degradation was very slow but when the microorganisms had become adapted, after four weeks at 11 degrees C, the degradation rate increased rapidly and after 58 days about 50% of 14C from NP was found in the CO2 fraction. In the presence of sediment the initial degradation rate was high and did not increase after longer incubation. Lack of oxygen reduced the degradation rate by half in the presence of sediment. 相似文献
16.
Madiha F.M. Farghaly Salah M.A.D. Zayed Soliman M. Soliman 《Journal of environmental science and health. Part. B》2013,48(7):575-581
Deltamethrin [(S)-cyano-3-phenoxybenzyl-cis-(1R,3R)-2,2-dimethyl) cyclo–propane carboxylate),1] labelled at gem-dimethyl groups of the cyclopropane ring was applied on two Egyptian soils at a level of 10 mg/kg soil for a laboratory incubation experiment under aerobic and anaerobic conditions. A steady decrease of soil extractable14C-residues, accompanied by a corresponding increase of non- extractable bound 14C-residues was observed over a 90-day incubation period. The percentage of evolved 14CO2 increased with time under aerobic and anaerobic conditions in both soils. The effect of deltamethrin on soil microorganisms as well as the counter effect of microorganisms on the insecticide was also investigated. As the incubation period increased, the inhibitory effect of the insecticide on the microorganisms decreased and the evolution of carbon dioxide depended on the applied dose. The nature of soil methanol soluble residues was determined by chromatographic analysis which revealed the presence of the parent insecticide as the main product in addition to four metabolites: 3-(2′,2′-dibromovinyl)-2,2-dimethylcyclopropane carboxylic acid (II); 3-phenoxybenzaldehyde (III); 3-phenoxybenzoic acid (IV); 3-phenoxybenzyl alcohol (V). 相似文献
17.
Microbial degradation of benzene under anaerobic conditions plays an important role in remediation of contaminated sites but the microorganisms and metabolic pathways involved remain poorly understood. In this study, we evaluated degradation of benzene by a methanogenic enrichment culture obtained from non-contaminated lotus field soil, alone and in the presence of several putative metabolic intermediates, that is, toluene, benzoate and phenol. Using stable isotope (13C) labeled substrate, benzene was shown to be degraded almost completely to equimolar concentrations of methane and carbon dioxide, without detectable accumulation of extracellular metabolites. Concurrently, toluene, benzoate and phenol were also effectively mineralized, but probably by microorganisms other than the benzene degraders. The latter included Hasda-A, which is putative benzene-degrading deltaproteobacterium present in the culture. While toluene and benzoate did not affect benzene degradation, phenol had a moderate inhibitory effect although it was not a major metabolic intermediate of benzene in our culture. Finally, 4-hydroxycoumarin was detected as a compound formed from phenol but further experiments are required to elucidate its relationship to degradation of phenol. 相似文献
18.
《Chemosphere》2010,78(11):1488-1494
Soil respiration measurements are an established method to test the abundance, activity and vitality of the soil microorganisms. However, abnormal progressions of soil respiration curves impede a clear interpretation of the data. The aim of this study was to investigate the changes in the microbial structure during the formation of phenomena like double peaks and terraces by analysis of the PLFA composition (phospholipid fatty acid composition). Moreover, 13C labeled glucose was used as substrate; therefore it was possible to measure δ13C values both within the PLFA fraction as well as within the carbon dioxide evolved during respiration. As contaminants trinitrotoluene, cycloheximide, and hexadecane were used. The results showed that the appearance of double peaks was mainly related to the growth of fungi with the marker 18:2δ9,12 due to a toxic effect of trinitrotoluene and cycloheximide. In contrast, the phenomenon of terrace formation was related to the utilization of hexadecane as a carbon source mainly by bacteria. 相似文献
19.
本文在农药降解菌的富集分离及农药微生物降解的途径,特别在微生物产生的农药降解酶和农药微生物降解基因操作方面对农药微生物降解的研究现状作了简要综述,提出了农药微生物降解的研究趋势。联系地址:中国科学院广州地球化学研究所,广州五山,510640津、环草隆、三氯醋酸、氯苯胺灵等。芽孢杆菌属(Bacillus):DDT、r-BHC、艾氏剂、狄氏剂、异狄氏剂、七氯、苯硫磷、对硫磷、甲基对硫磷、杀螟松、毒杀芬、茅草枯、三氯醋酸、利谷隆、灭草隆、毒旁定。节细菌属(Arthrobacter):DDT、艾氏剂、异狄氏剂、七氯、草多索、马拉硫磷、二嗪农、2,4-D、2甲4氯、茅草枯、三氯醋酸、毒莠定、西玛津、味哺丹[8]。棒状杆菌属(Corynboacterium):DDT、2,4-D、2甲4氯、茅草枯、二硝甲酚、百草枯、草枯醚。无色杆菌属(Achromobacter):DDT、西维因、2,4-D、2甲4氯、2,4,5-T、氯苯胺灵。土壤杆菌属(Agrobacterium):DDT、氯苯胺灵、茅草枯、三氯醋酸、毒莠定。黄杆菌属(Flavobacterium):对硫磷、甲基对硫磷、马拉硫磷、二嗪农、毒死蜱、2,4-D、2甲4氯、 相似文献
20.
重金属与土壤微生物的相互作用及污染土壤修复 总被引:8,自引:1,他引:7
阐述了微生物与重金属间的相互作用 ,指出土壤重金属污染影响微生物活性、生物量 ,且重金属对微生物具有一定的生态毒性。可通过微生物的氧化 还原作用、生物吸附富集和溶解作用 ,达到修复重金属污染土壤的目的。 相似文献