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为了建立碰撞反应池ICP-MS同时测定地下水中十七种稀土元素分析检测方法,采取内标校正法,选用铑、铟、铼、铋为内标元素,结合优化的仪器条件和碰撞反应池技术,校正分析过程中的干扰和漂移。外标法定量,加标回收对方法进行质量控制。结果表明十七种稀土元素浓度在0.50~50.0μg/L范围内,具有良好的线性关系,标准曲线相关系数r≥0.999 6;方法检出限为0.001~0.036μg/L;在空白溶液和实际水样中分别添加高、中、低三个水平的稀土元素标准溶液测定方法回收率,加标回收率为85.7%~105%,实际水样的相对标准偏差为0.5%~3.5%。碰撞反应池ICP-MS具有灵敏度高、检出限低、干扰少、精密度好、准确度高、谱线相对简单、线性范围宽及多元素同时分析等优点,适用于地下水中稀土元素的测定。 相似文献
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《中国环境管理干部学院学报》2017,(6)
优化ICP-MS的测定参数,选择合适的内标元素,测定了地下水及地表水中11种金属元素的含量。研究结果表明,此法测定水中11种金属元素的标准曲线相关系数(r)值均大于0.999,方法检出限为0.02~0.34μg/L,均低于国家现行标准,相对标准偏差(RSD)低于4%,对质控样的分析结果与标准值吻合,实际样品的加标回收率为95.0%~107.5%。该方法分析速度快、灵敏度高、检出限低,具有较好的精密度和准确度。 相似文献
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微波消解-原子荧光光谱法同时测定土壤中痕量砷和汞 总被引:3,自引:0,他引:3
建立了微波消解—原子荧光光谱法同时测定土壤中痕量砷和汞的方法。通过对消解体系以及灯电流、载气流量、屏蔽气流量等仪器参数进行优化,确定了最佳实验条件。在优化的实验条件下,采用原子荧光光谱法同时测定砷和汞的检出限分别为0.02μg/L和0.01μg/L,线性范围分别为0~40μg/L和0~4μg/L,两元素的加标回收率在92%~102%之间,相对标准偏差砷为0.9%~3.1%,汞为1.5%~3.4%,完全适用于土壤环境样品的检测。 相似文献
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《环境保护与循环经济》2015,(7)
重金属污染问题已经成为近年来危害最大的水污染问题之一。Cd是一种有毒的重金属元素,造成的环境污染受到广泛关注。合成了一种Cd(II)印迹吸附剂来去除水样中的Cd(II),并采用电感耦合等离子体质谱测定水中Cd(II)浓度。研究了水体p H值、洗脱条件、吸附时间以及循环使用次数等影响因素。方法的检出限为0.026μg/L,相对标准偏差为1.46%。为确认实验的准确度,分析了一个已知准确浓度的国家标准样品(GSB07-1185-2000 201422),测定值与标准值基本吻合。地表水样中Cd(II)的加标回收率为98%~101.2%,说明运用Cd(II)印迹吸附剂对水中Cd(II)的去除效果较好,建立的方法准确可靠。 相似文献
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黄志强 《中国环境管理干部学院学报》2013,(4):64-67
采用真空采血管顶空填充柱气相色谱法测定水中三氯甲烷和四氯化碳,结果表明,三氯甲烷在10.0~50.0μg/L,四氯化碳在0.5~4.0μg/L浓度范围内呈良好线性关系,其r值分别为0.9994和0.9998;三氯甲烷和四氯化碳RSD分别在1.64%~2.27%和1.45%~2.40%之间;加标回收率分别在97.0%~103.5%和94.0%~103.2%之间。该方法操作简单,具有较好的灵敏度和准确度,适用于水中三氯甲烷和四氯化碳的检测。 相似文献
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Gabriele Villarini Enrico Scoccimarro Kathleen D. White Jeffrey R. Arnold Keith E. Schilling Joyee Ghosh 《Journal of the American Water Resources Association》2015,51(5):1361-1371
Our improved capability to adapt to the future changes in discharge is linked to our capability to predict the magnitude or at least the direction of these changes. For the agricultural United States Midwest, too much or too little water has severe socioeconomic impacts. Here, we focus on the Raccoon River at Van Meter, Iowa, and use a statistical approach to examine projected changes in discharge. We build on statistical models using rainfall and harvested corn and soybean acreage to explain the observed discharge variability. We then use projections of these two predictors to examine the projected discharge response. Results are based on seven global climate models part of the Coupled Model Intercomparison Project Phase 5 and two representative concentration pathways (RCPs 4.5 and 8.5). There is not a strong signal of change in the discharge projections under the RCP 4.5. However, the results for the RCP 8.5 point to a stronger changing signal related to larger projected increases in rainfall, resulting in increased trends, in particular, in the upper part of the discharge distribution (i.e., 60th percentile and above). Examination of two hypothetical agricultural scenarios indicates that these increasing trends could be alleviated by decreasing the extent of the agricultural production. We also discuss how the methodology presented in this study represents a viable approach to move forward with the concept of return period for engineering design and management in a nonstationary world. 相似文献
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Brian W. Walker 《The Environmentalist》1986,6(1):9-13
Summary The author analyses the problems currently faced by the African continent, recognises six factors which he believes are important in influencing the analysis, and argues that the only secure, renewable asset any country or continent has, is its people. He maintains that people development, rather than the classical economic forms of encouraging development, offers Africa a viable way forward. He then identifies a number of specific issues within such a strategy of investment in human capital.Brian Walker is the President of the International Institute for Environment and Development (IIED), and this address was given at the inaugural meeting of the International Year of Shelter for the Homeless, in London, on 18th April, 1985. A second, earlier, associated address was published inThe Environmentalist 5(3) 167–170. 相似文献
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Rainfall samples were collected during the 2003 and 2004 growing seasons at four agricultural locales across the USA in Maryland, Indiana, Nebraska, and California. The samples were analyzed for 21 insecticides, 18 herbicides, three fungicides, and 40 pesticide degradates. Data from all sites combined show that 7 of the 10 most frequently detected pesticides were herbicides, with atrazine (70%) and metolachlor (83%) detected at every site. Dacthal, acetochlor, simazine, alachlor, and pendimethalin were detected in more than 50% of the samples. Chlorpyrifos, carbaryl, and diazinon were the only insecticides among the 10 most frequently detected compounds. Of the remaining pesticide parent compounds, 18 were detected in fewer than 30% of the samples, and 13 were not detected. The most frequently detected degradates were deethylatrazine; the oxygen analogs (OAs) of the organophosphorus insecticides chlorpyrifos, diazinon, and malathion; and 1-napthol (degradate of carbaryl). Deethylatrazine was detected in nearly 70% of the samples collected in Maryland, Indiana, and Nebraska but was detected only once in California. The OAs of chlorpyrifos and diazinon were detected primarily in California. Degradates of the acetanilide herbicides were rarely detected in rain, indicating that they are not formed in the atmosphere or readily volatilized from soils. Herbicides accounted for 91 to 98% of the total pesticide mass deposited by rain except in California, where insecticides accounted for 61% in 2004. The mass of pesticides deposited by rainfall was estimated to be less than 2% of the total applied in these agricultural areas. 相似文献
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Environmental assessment in countries in transition: evolution in a changing context 总被引:1,自引:0,他引:1
Cherp A 《Journal of environmental management》2001,62(4):357-374
Over the last fifteen years, Environmental Assessment systems of transitional societies of Central and Eastern Europe and Central Asia have undergone dramatic change from appraisals integrated into centrally planned economies to formal procedures aimed to ensure interdisciplinary analysis of environmental impacts and linked to publicly accountable decision-making. In most Central European nations, EA systems have been radically reformed to approximate the procedures used in developed countries, particularly in the European Union. In contrast, EA in most of the former Soviet republics has been reformed more gradually and is still based on the so-called State Environmental Review procedure inherited from the USSR and substantially different from 'Western' EA. About one-third of the transitional countries (in the Balkans, the Caucasus and Central Asia) have, so far, failed to establish functioning EA systems. Throughout the region, there has been a gap between EA legislation and practice, especially concerning interdisciplinary analysis of environmental impacts, public participation, and utilisation of EA findings in decision-making. A key driving force in the reform of EA systems has been the change in their societal context, the so-called 'process of transition'. Three main policy agendas--environmental protection, reforms of decision-making, and conforming to international requirements--along with the institutional context of EA regulations and practice have influenced both the change of EA systems over time and the regional variations in the patterns of their evolution. This study suggests that an effective reform of an EA system should be context-sensitive, or be 'in gear' with the political and economic transition. Future EA research should consider their changing societal contexts and focused on practical effects of applying EA procedures. 相似文献
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As a result of Structural Adjustment Programme from the 1980s, many developing countries have experienced an increase in resource extraction activities by international and transnational corporations. The work reported here examines the perceived impacts of gold mining at the community level in the Wassa West District of Ghana, Africa and discusses those perceived impacts in the context of globalization processes and growing multinational corporate interest in Corporate Social Responsibility (CSR). Interview data compared community members' perceptions with those of company representatives in three communities. The results indicate that communities held companies responsible for a series of economic, social, and environmental changes. While recognizing some of the benefits brought by the mines, communities felt that the companies did not live up to their responsibility to support local development. Companies responded by denying, dismissing concerns, or shifting blame. Findings from this work show that lack of engagement and action by government agencies at all levels resulted in companies acting in a surrogate governmental capacity. In such situations, managing expectations is key to community-company relations. 相似文献
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Zbigniew Bochniarz 《Natural resources forum》1992,16(1):55-63
Ambitious programmes of reform in Central and Eastern Europe (CEE) are threatened by a serious deterioration of the environment. Large-scale damage of the natural environment in many forms, including water pollution has created development barriers which adversely affect the living conditions of current and future generations. Despite similar patterns of environmental policy in the CEE countries compared with their Western counterparts, neither environmental legislation nor economic incentives have produced any significant improvement in water quality over the last 10–20 years. For that very reason in the transition period, it is necessary to identify existing deficiencies in the system and to build up a mixed system of new institutions of water management, more realistic legislation with a strong enforcement system, and market based incentives for water conservation and protection against pollution. 相似文献
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Yuriko Sakairi 《Natural resources forum》2000,24(4):313-323
This article presents a case study from Mozambique of the electrification of two selected towns under a World Bank financed project. Low-cost electricity services were extended to the two isolated areas after an enabling framework had been created for private sector participation. The World Bank project also demonstrates that the private sector can be attracted to participate in rural electrification schemes even in a poor country. The example shown in this article is one of the few of its kind in SubSaharan Africa. 相似文献