水中总氮测定方法存在问题的研究及改进

碱性过硫酸钾消解紫外分光光度法测定水中总氮采用的消解器皿是玻璃比色管,易造成空白偏高、结果偏低等问题。采用双圆柱状的消解杯对水样进行消解。结果表明,消解杯消解水中总氮,线性相关系数均大于0.999,检出限为0.05 mg/L,相对标准偏差小于5%,相对误差为0.88%~1.00%;改进后的消解器皿具有较好的精密度和准确度,能够更加准确测定水中总氮的含量。     

Comparison on surface properties and desulfurization of MnO2 and pyrolusite blended activated carbon by steam activation

In this study, MnO₂ and pyrolusite were used as the catalysts to prepare modified activated carbon, that is, AC-Mn and AC-P, respectively, from coals by blending method and steam activation. The Brunauer–Emmett–Teller (BET) results indicated that the AC-P had higher surface areas and micropore volumes than the AC-Mn with the same blending ratio. The relative contents of basic functional groups (i.e., C = O, π-π*) on AC-P were slightly lower than those on AC-Mn, while both contained the same main metal species, namely, MnO. The desulfurization results showed that with 3 wt% of blending ratio, AC-Mn3 and AC-P3 had higher sulfur capacities at 220 and 205 mg/g, respectively, which were much higher than for the blank one (149.6 mg/g). Moreover, the AC-P had relatively higher sulfur capacity than the AC-Mn with the same contents of Mn, which might be attributed to the existence of other metals in pyrolusite. After the desulfurization process, MnO were gradually transferred into MnSO₄, and the relative contents of basic functional groups decreased evidently for both AC-Mn3 and AC-P3. The results demonstrated that pyrolusite could be one good alternative to MnO₂ to prepare modified activated carbon for desulfurization.

Implications: MnO₂ and pyrolusite were used as the additives to prepare modified activated carbon from coals by a blending method and by steam activation, that is, AC-Mn and AC-P, respectively. The AC-P had higher surface areas and micropore volumes than the AC-Mn with the same blending ratio. The AC-Mn and AC-P had higher sulfur capacities than a blank one. Moreover, the AC-P had relatively higher sulfur capacity than the AC-Mn with the same contents of Mn. The results demonstrated that pyrolusite could be one good alternative to MnO₂ to prepare modified activated carbon for desulfurizatio.     

基于探索性数据分析的汉丰湖富营养化驱动因子研究

为了探究汉丰湖富营养化驱动因子和营养状况，基于2014年水质监测数据，应用探索性数据分析方法初步研究了汉丰湖水动力条件与环境因子的相关性、水质主成分、相关环境因子熵权和营养健康指数。回归分析结果表明：水位与透明度呈正相关，流量与DO呈负相关，与流速呈负相关的因子为Chla、CODMn、NH+4-N和DTP；主成分分析提取的3个主成分分别反映了营养盐、有机污染以及藻类信息；DO、TN和TP的熵权表明汉丰湖水体的富营养状况受制于耗氧有机污染和氮、磷营养盐；营养健康指数S1>S3>S6（湖心）>S7（湖尾）>S5（湖首）>S4>S2。汉丰湖水体营养状况介于中营养到轻富营养，其中南河营养状态较高，湖心营养程度高于湖首和湖尾。减少有机污染物、营养盐的输入和改善局部水域的水动力条件可抑制藻类生长，有利于防治富营养化。 关键词： 探索性数据分析；汉丰湖；富营养化；驱动因子；水动力条件；主成分；熵权；营养健康指数     

异戊醇低压热解的同步辐射真空紫外光电离质谱研究

作为新兴生物燃料,大分子醇类燃料在低压下的火灾安全基础迫切需要得到深入研究。热解过程作为火灾过程的初始阶段直接控制着火过程,火灾中碳烟颗粒的产生也依赖于热解反应,因此可燃物的低压热解研究在其低压火灾基础研究中具有重要意义。利用同步辐射真空紫外光电离质谱方法研究了异戊醇在0.2atm下的流动反应器热解,探测到了20余种热解产物,包括烯丙基自由基和C_4H_8O、C_5H_8、C_6H_6等同分异构体,并测量了其摩尔分数。基于实验结果,对燃料分解路径和主要产物的生成及消耗路径进行了探讨。与本组之前正戊醇热解实验的对比表明,由于存在支链结构,异戊醇在热解中比正戊醇更容易产生戊烯、丁烯和丙烯,但更少地产生乙烯。此外,异戊醇在热解中能够生成更多的丙炔和丙二烯等环状化合物前驱体,令其苯和1,3-环戊二烯的生成量更高,表明异戊醇比正戊醇更易于生成多环芳烃和碳烟。     

2005-2019年我国重特大安全生产事故特征分析

为探究我国重特大安全生产事故特征,选取2005-2019年国内852起重特大事故作为研究对象,基于Python编程语言针对重特大事故发生的年份、季度、月份、工作日与非工作日、地域特征进行分析.结果表明:2005-2019年,国内重特大安全生产事故起数和死亡人数均在不断下降;第四季度发生重特大事故最多,而第三季度平均每起事故造成的死亡人数最多;重特大事故数量和死亡人数随月份显示出反复波动的趋势,均呈现3个"^",形;工作日期间发生的重特大事故数量最多,非工作日平均事故率最大;国庆节是重特大事故发生最多的节假日;贵州、湖南、山西、云南、河南等省份"十四五"期间需要重点加强安全和应急管理.     

Difference in the net value of ecological services between natural and artificial forests in China

Land degradation is a global problem that seriously threatens human society. However, in China and elsewhere, ecological restoration still largely relies on a traditional approach that focuses only on ecological factors and ignores socioeconomic factors. To improve the effectiveness of ecological restoration and maximize its economic and ecological benefits, a more efficient approach is needed that provides support for policy development and land management and thereby promotes environmental conservation. We devised a framework for assessing the value of ecosystem services that remain after subtracting costs, such as the opportunity costs, costs of forest protection, and costs for the people who are affected by the program; that is, the net value of ecosystem services (NVES). To understand the difference between the value of a resource and the net value of the ecosystem service it provides, we used data on VES, timber sales, and afforestation costs from China's massive national afforestation programs to calculate the net value of forest ecosystem services in China. Accounting for the abovementioned costs revealed an NVES of ¥6.1 × 10¹² for forests in 2014, which was 35.9% less than the value calculated without accounting for costs. As a result, the NVES associated with afforestation was 55.9% less than the NVES of natural forests. In some regions, NVES was negative because of the huge costs of human-made plantations, high evapotranspiration rates (thus, high water opportunity costs), and low forest survival rates. To maximize the ecological benefits of conservation, it is necessary to account for as many costs as possible so that management decisions can be based on NVES, thereby helping managers choose projects that maximize both economic and ecological benefits.     

石家庄市春季大气颗粒物的铅污染特征

为了解石家庄市2016年春季大气颗粒物的铅污染特征及来源,利用单颗粒气溶胶质谱仪(SPAMS),分析了大气中含铅颗粒的化学成分。结果表明: 研究期间大气环境中含铅颗粒数浓度共出现11次跳跃式升高,跳跃时间段内石家庄均处于轻度污染过程。从成分分析来看,含铅颗粒分为纯铅颗粒、Pb与K(Pb-K)、OC(Pb-OC)、Cl(Pb-Cl)、混合颗粒等八大类。观测结果表明:Pb-K颗粒最多,占到含铅颗粒的84.4%；其次为纯铅颗粒,占比为13.0%。与石家庄市污染源谱库比对进行来源解析,得到Pb-K颗粒主要来自生活垃圾焚烧源, 纯铅颗粒主要来自工业源。结合石家庄市大气污染源排放清单和后向气流轨迹分析,推测含铅颗粒可能来自市区西南方向某区县的生活垃圾焚烧企业。     

The associations of air pollution exposure during pregnancy with fetal growth and anthropometric measurements at birth: a systematic review and meta-analysis

Environmental Science and Pollution Research - Fetal growth has been demonstrated to be an important predictor of perinatal and postnatal health. Although the effects of maternal exposure to air...     

显色条件对纳氏试剂分光光度法测定水中氨氮的影响

氨氮是水质监测和评价的重要指标之一。本文探讨了纳氏试剂光度法测定水中氨氮时显色温度和显色时间对测定结果的影响,并从空白测定、显色速率及校准曲线等方面进行了分析,提出了对测定方法的改进建议。