全文获取类型
收费全文 | 92篇 |
免费 | 5篇 |
国内免费 | 28篇 |
专业分类
安全科学 | 5篇 |
废物处理 | 4篇 |
环保管理 | 5篇 |
综合类 | 50篇 |
基础理论 | 20篇 |
污染及防治 | 29篇 |
评价与监测 | 10篇 |
社会与环境 | 2篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2014年 | 4篇 |
2013年 | 9篇 |
2012年 | 6篇 |
2011年 | 7篇 |
2010年 | 2篇 |
2009年 | 4篇 |
2008年 | 6篇 |
2007年 | 10篇 |
2006年 | 19篇 |
2005年 | 4篇 |
2004年 | 8篇 |
2003年 | 7篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1990年 | 2篇 |
1989年 | 2篇 |
排序方式: 共有125条查询结果,搜索用时 15 毫秒
21.
环境二■英类污染物受到广泛关注,目前常用的二■英类物质检测方法有仪器分析法(高分辨率气相色谱-高分辨率质谱法)和生物检测法。生物检测法具有便捷高效、成本低廉等优点,但其测定值普遍高于仪器分析法,关键原因是生物检测法在前处理阶段未能完全消除非二■英类物质的干扰。改进了传统7-乙氧基-3-异吩恶唑酮-脱乙基酶(EROD)生物检测法的前处理方法,并利用改进后的EROD法与仪器分析法对相同环境样品进行检测,对比分析两种方法得到的二■英毒性当量数据。结果显示,改进后的细分前处理手段结合梨形烧瓶-Mix前处理手段能有效提高二■英类物质的回收率(接近100%),并且改进后的EROD法的检测结果与仪器分析法测定的二■英当量结果相当,说明通过改进前处理方法可以将生物检测法的准确度提高到与仪器分析法一致的水平。研究结论可为生物检测法在环境样品二■英类污染物检测中的应用和推广提供有效的数据参考。 相似文献
22.
23.
Black RR Meyer CP Touati A Gullett BK Fiedler H Mueller JF 《Environment international》2012,38(1):62-66
The Stockholm Convention on Persistent Organic Pollutants includes in its aims the minimisation of unintentional releases of polychlorinated dibenzo-dioxins and dibenzofurans (PCDD/PCDF) and dioxin like PCB (dl-PCB) to the environment. Development and implementation of policies to achieve this aim require accurate national inventories of releases of PCDD/PCDF/dl-PCB. To support this objective, the Conference of Parties established a process to review and update the UNEP Standardized Toolkit for Identification and Quantification of Dioxin and Furan Releases. An assessment of all emission inventories was that for many countries open burning of biomass and waste was identified as the major source of PCDD/PCDF releases. However, the experimental data underpinning the release estimates used were limited in number and, consequently, confidence in the accuracy of the emissions predictions was low. There has been significant progress in measurement technology since the last edition of the Toolkit in 2005. In this paper we reassess published emission factors for release of PCDD/PCDF and dl-PCB to land and air.In total, four types of biomass and 111 emission factors were assessed. It was found that there are no systematic differences in emission factors apparent between biomass types or fire classes. The data set is best described by a lognormal distribution. The geometric mean emission factors (EFs) for releases of PCDD/PCDF to air for the four biomass classes used in the Toolkit (sugarcane, cereal crops, forest and savannah/grass) are 1.6 μg TEQ (t fuel)−1, 0.49 μg TEQ (t fuel)−1, 1.0 μg TEQ (t fuel)−1 and 0.4 μg TEQ (t fuel)−1, respectively. Corresponding EFs for release of PCDD/PCDF to land are 3.0 ng TEQ (kg ash)−1, 1.1 ng TEQ (kg ash)−1, 1.1 ng TEQ (kg ash)−1 and 0.67 ng TEQ (kg ash)−1. There are now also sufficient published data available to evaluate EFs for dl-PCB release to air for sugarcane, forest and grass/savannah; these are 0.03 μg TEQ (t fuel)−1, 0.09 μg TEQ (t fuel)−1 and 0.01 μg TEQ (t fuel)−1, respectively. The average EF for dl-PCB release to land is 0.19 ng TEQ (kg ash)−1. Application of these EFs to national emissions of PCDD/PCDF for global estimates from open burning will lower previous estimates of PCDD/PCDF releases to air and to land by 85% and 90%, respectively. For some countries, the ranking of their major sources will be changed and open burning of biomass will become less significant than previously concluded. 相似文献
24.
25.
Grochowalski A Lassen C Holtzer M Sadowski M Hudyma T 《Environmental science and pollution research international》2007,14(5):326-332
Background The aim of the project was to measure the actual emissions of PCDD/F, PCBs and HCB from 20 selected metallurgical installations
in Poland, in order to update the national inventory of dioxin emission from metallurgical industry for developing a strategy
for dioxins and furans emission abatement from the subject facilities (UNEP 2005).
Methods Sampling methodology used in this work was developed at the Cracow University of Technology because of the complexity of simultaneous
sampling and determining PCDFs, PCDDs, PCB and HCB. For the determination a GC-MS/MS system was used.
Results and Discussion Results from the work indicate that the highest dioxins and PCB concentrations were recorded for iron ore sintering plants
at 1.10–1.32 ng total1 TEQ/Nm3 followed by aluminium scrap melting at 0.03–0.66 ng total TEQ/Nm3. The highest HCB concentrations at 613–1491 ng/Nm3 were also recorded for iron ore sintering plants, whereas at aluminium plants the HCB concentrations were in the range of
only 10.1–22.7 ng/Nm3.
Conclusions The above investigations indicate that secondary aluminium production is the most significant dioxins source, if calculated
as emission factor values. However, iron ore sintering plants are operating at much higher production capacity, causing this
process to become the major source of dioxins, PCB and HCB pollution to the atmosphere in Poland.
Recommendations and Perspectives Based on the performed tests and the environmental reviews of selected plants several recommendations were formulated for
the reduction of generation or of emission of these pollutants from iron ore sintering plants, electric arc furnace steel
production processes, hot-blast furnace operations, secondary aluminium smelting and primary zinc production from zinc cathodes. 相似文献
26.
医疗废物焚烧处置中二恶英的过程控制安全技术 总被引:5,自引:0,他引:5
针对我国目前医疗废物焚烧处置中所存在的问题,根据二恶英生成机理和影响因素,对医疗废物焚烧处置各阶段的二恶英减排控制技术、工况参数设计、工艺设备选择等关键环节进行深入分析。结合分析结果,提出了在医疗废物焚烧前控制中,对医疗废物分类收集、分别处置进行氯源控制;讨论了医疗废物焚烧过程控制中焚烧温度、停留时间、湍流程度、过剩空气系数的最佳工艺参数;指明了医疗废物焚烧后控制中的急冷、脱酸、喷粉、除尘及灰渣处置的最优控制技术。 相似文献
27.
陈小亮 《中国ISO14000认证》2014,(3):26-30
总结分析了中美两国二噁英有关标准的特点。我国二噁英相关的标准体系有待完善,主要集中在重点行业的烟气排放标准方面。美国二噁英相关标准体系较为完善,以风险评估为重点,二噁英排放源涉及的行业划分细致。排放标准分级明显,技术导向明显。通过对比分析指出,我国应继续深化重点行业的烟气排放控制的策略。加强二噁英风险评估的基础性研究工作,以减排技术为基础,强化分级管理的思路,并针对不同排放源细化二噁英的标准。 相似文献
28.
Yu Gang Zhang Qing Huang Jun Cai Zhenxiao Sui Qian 《Frontiers of Environmental Science & Engineering in China》2007,1(1):13-17
As a party of the Stockholm Convention on Persistent Organic Pollutants, China must submit its national implementation plan
(NIP) for this convention. The strategy and action plan for reducing the release of dioxins in China are the most important
components of the NIP. Three problems are key points for developing such strategy and action plan—what are the key sources
for applying the best available technology/best environmental practice (BAT/BEP) to reduce the release of dioxins? How about
the capacity for reducing the dioxins release from the key sources? Where are the areas of priority for applying BAT/BEP?
This paper shows the efforts towards the solution of these problems. The list of key sources covering about half of the total
dioxins release was determined considering four criteria. The capacity of key sources were estimated based on the difference
between the emission factor corresponding to the actual situation in 2004 and that corresponding to the scenario that all
key sources have been applied BAT/BEP to reduce the dioxins release. The priority analysis using the geographical information
system (GIS) tool has revealed that castern provinces should be of high priority in the future reduction activities of dioxins
release in China. 相似文献
29.
HU Zhan-bo Saman Wijesekara R.G. Ronald R. Navarro WU De-yi ZHANG Da-lei Masatoshi Matsumur KONG Hai-nan 《环境科学学报(英文版)》2006,18(5):989-994
Few studies have dealt on the evaluation of volatilization and decomposition reactions of dioxins from sediment by oxygen free pyrolysis. In this study, the performance of pyrolysis on the removal of dioxins from sediment was investigated. Dioxin concentrations of the raw sediment and the solid residues after pyrolysis were analyzed at different conditions. Results showed a removal efficiency of 99.9999% for total dioxins at 800℃ and retention time of 30 min. All the polychlorinated dibenzo-furans (PCDFs) have been removed and were not formed in the solid residues at the retention time range of 30-90 min at 800℃. Close to 100% removal of polychlorinated dibenzo-p-dioxins (PCDDs) was also achieved. Only trace PCDDs were detected in the solid yields at a retention time of 60 min. The highest removal efficiency of polychlorinated biphenyls (PCBs) was more than 99.9994% at a retention time of 30 min. During cooling period following pyrolysis, however, the concentration of total dioxins in solid residues increased 130 times as compared to that of the raw sediment under air atmosphere. This confirmed that some complex reactions do occur to form PCDD/Fs and PCBs from 800 to 400℃ in the presence of oxygen. Oxygen-free atmosphere therefore can prevent formation of dioxin during thermal process thus generating clean solid residues. 相似文献
30.
Experimental study on MSW gasification and melting technology 总被引:1,自引:0,他引:1
XIAO Gang JIN Bao-sheng ZHONG Zhao-ping CHI Yong NI Ming-jiang CEN Ke-f XIAO Rui HUANG Ya-ji HUANG He 《环境科学学报(英文版)》2007,19(11):1398-1403
In order to develop municipal solid waste (MSW) gasification and melting technology, two preliminary experiments and a principle integrated experiment were fulfilled respectively. The gasification characteristics of MSW are studied at 500-750℃ when equivalence ratio (ER) was 0.2-0.5 using a fluidized-bed gasifier. When temperature was 550-700℃ and ER was 0.2-0.4, low heat value (LHV) of syngas reaches 4000-12000 kJ/Nm3. The melting characteristics of fly ash were investigated at 1100-1460℃ using a fixed-bed furnace. It was proved that over 99.9% of dioxins could be decomposed and most heavy-metals could be solidified when temperature was 1100-1300℃. The principle integrated experiment was carried out in a fluidized-bed gasification and swirl-melting system. MSW was gasified efficiently at 550-650℃, swirl-melting furnace maintains at 1200-1300℃ stably and over 95% of fly ash could be caught by the swirl-melting furnace. The results provided much practical experience and basic data to develop MSW gasification and melting technology. 相似文献