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91.
92.
93.
我国垃圾焚烧二噁(口英)类排放源的初步调查 总被引:2,自引:0,他引:2
1 IntroductionIncinerationisnotthedominantwaytodisposalofmunicipalsolidwaste (MSW)atpresentinChina[1 ].However,moreandmorecitieswithrapiddevelopmentofeconomyareplanningtobuildMSWincinerationfacilities.AccordingtothelatestresultofinvestigationonMSWtreatme… 相似文献
94.
95.
二恶英的生成及污染控制 总被引:3,自引:0,他引:3
介绍了二恶英的性质、毒性、污染源以及排放趋势,重点论述了二恶英的生成影响因素与污染排放控制技术.二恶英的生成影响因素主要有炭源、氯源、温度、催化剂和氧源等.二恶英的污染排放控制技术则介绍了传统的去除技术和一些降解技术. 相似文献
96.
Samples of whole effluent and effluent suspended solids from a kraft pulp mill and sediments and biota from Jackfish Bay, Lake Superior were analyzed for polychlorinated dibenzo-p-dioxins (CDDs) and dibenzofurans (CDFs). Tetra-CDFs (4CDF) were consistently detected in whole effluent at levels ranging between 0.3 and 1.3 ng/L. Effluent suspended solids also contained 4CDFs as well as traces of 4CDD, 5CDF, 8CDF and 8CDD. The horizontal sediment distribution suggests that the effluent was the only active source of 4CDF in the area but that 8CDD originated from a more general source such as the atmosphere. An abrupt appearance of 4CDF in the more recent sections of a core profile taken in the bay suggests that an operational change at the pulp mill resulted in the formation of 4CDFs in the mill effluent some time after 1973. Moderate values of 4CDF and low values of 4CDD were found in samples of the shrimp
confirming the presence of an active source of 4CDF in Jackfish Bay. 相似文献
97.
Levels of PCDDs and PCDFs in products and effluent from the Swedish pulp and paper industry and chloralkali process 总被引:1,自引:0,他引:1
Within the Swedish Dioxin Survey various samples from the pulp and paper industry and the chloralkali process have been analyzed by congener specific analytical methods. In addition to the generally discussed “bleaching pattern” of the tetrachlorinated congeners, these samples also contained higher chlorinated congeners like hexa-CDDs, hepta-CDFs, octa-CDD and octa-CDF. Consequently it is recommended that samples from the pulp industry should be analyzed for all PCDDs and PCDFs (tetra- through octa-). Counted as Nordic Toxic Equivalents (NTEQ), the recycled pulp samples had the highest contamination level followed by TMP, unbleached sulfite and bleached softwood and hardwood. In addition to the bleaching process, various chemicals used in the pulping, bleaching and wastewater treatment can contribute to the contamination. 相似文献
98.
Jimnez Begoa Merino Rubn Abad Esteban Rivera Josep Olie Kees 《Environmental science and pollution research international》2007,14(1):61-68
Background Species that are at high levels of the food web have often been used as bioindicators to evaluate the presence of persistent
contaminants in ecosystems. Most of these species are long-lived, so pollutant burdens may be integrated in some complex way
over time. This makes them particularly sensitive to deleterious effects of Persistent Organic Pollutants (POPs). Birds have
been suggested as useful organisms for monitoring pollutant levels. Traditionally such studies have been carried out with
raptors such as osprey (Pandion haliaetus), peregrine falcon (Falco peregrinus), bald eagle (Haliaetus leucocephalus), etc. In this paper we present the results of a monitoring study conducted on two raptor species, osprey (Pandion haliaetus) and red kite (Milvus milvus), inhabiting a Mediterranean island (Menorca, Spain). These two species have different feeding habits; ospreys prey on fish
and red kites feed on terrestrial species. This study constitutes a good opportunity to investigate if differences in feeding
habits (aquatic vs. terrestrial) influences the contaminants pattern in two species inhabiting the same area.
Methods The study was conducted in a non-destructive way, using only failed eggs, to avoid the damage of the population stability.
Eggs were collected during the period 1994–2000. The contaminants examined were dichlorodiphenyltrichloroethanes (DDTs, including
DDT and its main metabolite, DDE), polychlorinated biphenyls (PCBs), including ortho PCBs (PCBs with at least one Chlorine
atom in the ortho position): #28, 52, 95, 101, 123+149, 118, 114, 153, 132+105, 138, 167, 156, 157, 180, 170, 189, 194; and
non ortho PCBs (PCBs with no Chlorine atom in the ortho position): #77, 126, 169 and all the polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) with Chlorine atoms at the 2,3,7 and 8 position (2,3,7,8-substituted
PCDDs and PCDFs). The analysis of organochlorine compounds was performed using a sample treatment based on a Solid Phase Matrix
Dispersion procedure. Ortho PCBs and DDTs were determined by HRGC-μECD; non ortho PCBs and PCDD/Fs were determined by HRGC-HRMS.
Results and Discussion The sum of the ortho PCB congeners analysed ranged from 0.94 to 15.03 μg/g wet weight (ww) for ospreys and from 1.0 to 11.2
μg/g ww for red kites. In both species, PCB congeners #153, #138 and #180 accounted about 75% to total ortho PCB concentrations.
Regarding non ortho PCBs, for ospreys, concentrations ranged from 0.16 to 1.39 ng/g wet weight (ww) and for red kites from
0.12 to 0.51 ng/g ww, being congener #126 the most abundant. Concerning DDTs, concentration for ospreys ranged from 0.07 to
1.03 μg/g ww; and for red kites ranged from 0.90 to 2.10 μg/g ww, representing DDE more than 95% of the total DDTs, which
proves a past use of DDT in the study area. Differences in contaminant levels between species are probably associated to feeding
habits. The fish-eating species presents the highest PCB levels, whereas the terrestrial species exhibits the highest DDT
levels. PCDD/Fs in ospreys were in the range 2.6–14.2 pg/g ww, while in red kites the range was slightly wider (22.2–43.2
pg/g ww), being PCDDs the major contributors in black kites. Ospreys had PCDDs similar to PCDF concentrations. PCDD/F profiles
were mostly influenced by OCDD in both species. Non ortho PCBs were the major contributors to calculated Toxic Equivalent
Quantity (TEQs) in both species.
Conclusion In both species studied, ortho-PCBs could represent a problem of concern since 57% of the eggs exhibited levels higher than
4 μg/g ww, reported as the level that could cause reduced hatchability, embryo mortality, and deformities in birds.
Recommendations and Outlook Results found in this study suggest that a more detailed study to clear up possible deleterious effects of PCBs on the bird
populations studied here should be done.
Section Editor: Prof. Dr. Paola Gramatica (paola.gramatica@uninsubria.it) 相似文献
99.
Domingo JL Schuhmacher M Granero S de Kok HA 《Environmental monitoring and assessment》2001,69(2):175-193
In 1996 and 1997, the levels of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were determined in soil and herbage samples taken from 24 sites in the vicinity of an old municipal solid waste incinerator (Montcada, Barcelona, Spain). To determine the temporal variation in the concentrations of PCDD/Fs, recently 24 soiland 24 herbage samples were again collected at the same sampling points and analyzed for PCDD/F levels. In the currentsurvey, PCDD/F concentrations in soils ranged between 0.06 and127 ng I-TEQ kg-1 (dry matter), with median and mean values of 4.80 and 9.95 ng I-TEQ kg-1 (dry matter), respectively. In turn, the levels of PCDD/Fs in herbage samples ranged from 0.40 to 1.94 ng I-TEQ kg-1 (dry matter), with median and mean values of 0.86 and 0.95 ng I-TEQ kg-1 (dry matter), respectively. The comparison with the data obtained in 1996 and 1997 show that while PCDD/F concentrations in herbage samples decreased substantially during the last two years, no significant differences in the levels of PCDD/Fs in soils were noted. On the other hand, the potential intake of polluted soils from the vicinity of the plant would not imply any significant health risk for the general population living in the area under influence of the facility. 相似文献
100.
Isabel W.C.E. Arends Jan G.P. Born W.Ren Ophorst Peter Mulder Robert Louw 《Chemosphere》1989,18(9-10):1965-1970
Pyrolysis (800–900°C, ca. 5 s) of benzene/HC1 mixtures leads to chlorobenzene (1) even in a reducing environment of H2 and/or CH4. With added oxygen, 1 is formed even at 550°C; such slow combustions also yield chlorinated phenols and dibenzofurans. 相似文献