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1.
目的比较实验室试验结果与实海挂片结果对B10和H62两种铜合金腐蚀性能评价的异同之处。方法采用线性极化、电化学阻抗、显微形貌观察等,比较两种铜合金在实验室模拟海水中的的腐蚀速率、点蚀倾向,结合反应机理、腐蚀形貌、环境等外部因素,分析导致实验室与实海环境下出现差异的原因。结果除榆林海域外,实海挂片与实验室结果都表明,B10试样的平均腐蚀速率小于H62。B10和H62两种铜合金随温度升高腐蚀速率增大,在实验室和实海情况下表现出一致性,且平均腐蚀速率都随浸泡时间的延长而降低。结论在实海环境中,温度不是影响点蚀的主要因素,微生物等其他环境因素会对点蚀产生较大影响。  相似文献   
2.
采用声电类比的传递矩阵法,本文对消声器插入损失进行了理论探讨,所推导的理论公式准确地反映了整个内燃机排气系统对消声器插入损失的影响,克服了其它学者在研究此问题中的不足,考虑了声源声阻抗对传递损失的影响,对消声器的整体优化设计具有重要的指导意义。  相似文献   
3.
Most native polymers used in processing and application technologies are admittedly disposable from the environment in a biologic manner, but products possess low mechanical strength. One of the paths to increasing this attribute (if feasible) is their cross-linking, which may, however, affect their readiness to biodegradation. In the presented work this condition was observed on the example of waste protein (Hykol B) cross-linking by means of glutardialdehyde and glyoxal. Degree and course of cross-linking were determined through impedance spectroscopy. The objective of this work also was to obtain data for constructing a sensor capable of following the cross-linking course in real time, for potential industrial application of Hykol in continuous production. Impedance spectroscopy proved to be applicable even to this kind of material marked by considerable water content and exhibiting relatively high electric conductivity; so far it had been used only for materials of low conductivity. An aqueous environment inoculated with digested anaerobic sludge from a municipal wastewater treatment plant was selected for modeling anaerobic conditions. The relation was studied between cross-linking degree given by content of cross-linking agent (determined by impedance spectroscopy) and biodegradation degree under anaerobic conditions. It was confirmed that network density as given by quantity of added agent not only reduced breakdown degree but also slowed the course of the process. This fact is particularly obvious with cross-linking by means of glyoxal; network density is thus dependent on type of employed substance, which affect type and structure of created network. That not merely forms an obstacle during polymer swelling and dissolution but also prevents access of bacteria to source of metabolized organic carbon.  相似文献   
4.
In a proton exchange membrane electrolyzer cell (PEMEC), liquid/gas diffusion layer (LGDL) is expected to transport electrons, heat, and reactants/products to and from the catalyst layer with minimum voltage, current, thermal, interfacial, and fluidic losses. In addition, carbon materials, which are typically used in PEM fuel cells (PEMFCs), are unsuitable in PEMECs due to the high ohmic potential and highly oxidative environment of the oxygen electrode. In this study, a set of titanium gas diffusion layers with different thicknesses and porosities are designed and examined coupled with the development of a robust titanium bipolar plate. It has been found that the performance of electrolyzer improves along with a decrease in thickness or porosity of the anode LGDL of titanium woven meshes. The ohmic resistance of anode LGDL and contact resistance between anode LGDL and the anode catalyst play dominant roles in electrolyzer performance, and better performance can be obtained by reducing ohmic resistance. Thin titanium LGDLs with straight-through pores and optimal pore morphologies are recommended for the future developments of low-cost LGDLs with minimum ohmic/transport losses.  相似文献   
5.
目的 研究Al/BN封严涂层在海洋环境下的腐蚀历程。方法 使用扫描电镜(SEM)、X射线衍射(XRD)、电化学等测试方法,对Al/BN封严涂层在盐雾环境中的腐蚀行为、形貌、显微结构、相组成及耐腐蚀等性能进行研究,分析Al/BN封严涂层在盐雾试验中的电化学腐蚀过程。结果 在96 h盐雾试验中,Al/BN封严涂层的腐蚀过程分为2个阶段,分别为孔蚀形成期和孔蚀发展期。在前72 h的盐雾腐蚀时间里,Al/BN封严涂层的腐蚀产物对于孔洞的堵塞越来越严重,自腐蚀电流密度也处于下降状态,表明Al/BN封严涂层的腐蚀产物有效地阻止了腐蚀速度的加剧。在第2阶段,阻抗值有所下降,是因为腐蚀产物龟裂或孔洞内局部酸化造成。结论 Al/BN涂层的腐蚀产物对Al/BN封严涂层的自腐蚀速率有比较大的影响。  相似文献   
6.
为了消除辐射测试场地供电端口阻抗的差异,本文设计制作了一种共模阻抗稳定网络,可以在供电端口处提供稳定的共模阻抗。文中对该网络的技术参数、元件规格及分布参数控制提出设计方案.经实际制作与量测验证后,该稳定网络可以在30~300MHz的频段内提供稳定的阻抗(50±5?),符合设计方案的目标,利用此网络可有效消除供电端口阻抗差异引起的测试误差。  相似文献   
7.
通过研究不同来源霾颗粒物对大鼠气管上皮细胞(RTE cells)电阻抗变化和细胞自噬因子的影响,评价不同来源霾颗粒物对人体健康风险的差异性.分别将RTE暴露于从居民区(I),高架交通源(Ⅱ)和化工园区(Ⅲ)采集的3种雾霾颗粒物中,统一暴露浓度和时间分别为100mg/L和24h.通过电子细胞基质阻抗检测(ECIS)细胞增长引起的阻抗变化和细胞电损伤恢复时间;通过蛋白免疫印迹测定p62,Atg5,Atg7,Beclin1,LC3B和mTOR蛋白表达量来分析比较不同来源雾霾颗粒物对RTE细胞自噬的影响.结果表明,与空白对照组相比,不同雾霾颗粒物处理组细胞电损伤恢复时间分别延长了34.6%,63.2%和78.0%;p62蛋白表达量差异显著性下降,Atg5,Atg7,Beclin1,LC3B蛋白表达量差异显著性上升.此外,mTOR相关蛋白表达量差异显著性下降,分别下降了4.38%,3.34%和2.36%;p-mTOR蛋白表达量与空白组相比,实验组I下降24.2%,实验组Ⅱ下降37.0%,实验组Ⅲ下降60.9%.由以上结果可知,不同来源雾霾颗粒物对RTE细胞均有一定的毒性损伤作用,能够减小细胞增长速度和削弱细胞修复能力,增强细胞自噬因子蛋白的表达,且化工园区采集的雾霾颗粒物毒性强于居民区和高架交通源.不同来源雾霾颗粒物的细胞毒性存在明显差异,基于细胞电损伤恢复时间的测定以及自噬相关蛋白的检测方法能够为雾霾颗粒物健康风险评价提供一种快速的生物学手段.  相似文献   
8.
Background Biological monitors are increasingly important in 'Biological Early Warning Systems' (BEWS) for monitoring water quality. This study examines the freshwater amphipod Crangonyx pseudogracilis as a potential new indicator species when used in the Multispecies Freshwater Biomonitor (MFB). The MFB is an online continuous biomonitor which uses impedance conversion to record behavioural responses of vertebrates and invertebrates. Methods Four experiments were undertaken to establish: (1) if the electrical field generated by the MFB affected the organisms' behaviour, (2) if defined behaviours and their response to a gradient of ammonium chloride could be detected by the MFB, (3) if there was variation in the behaviour of C. pseudogracilis over a diel cycle, and (4) if behaviour changed significantly in response to a pulse of ammonium chloride. Results and Discussion Results showed no significant effect of the MFB's current on behaviour of C. pseudogracilis. Four behaviours; swimming, walking, grooming and inactivity, were observed and identified in the MFB. In the MFB, each behaviour changed significantly in response to an increasing gradient of ammonium chloride exposure. The MFB also detected increases in nocturnal activity by C. pseudogracilis. The MFB also detected a significant increase in activity after a pulse of ammonium chloride. Conclusion The range of behaviours exhibited by Crangonyx pseudogracilis, together with its ease of culture, suggest future potential of this species as an indicator species for the Multispecies Freshwater Biomonitor. Recommendations and Perspective . Further testing is required over a range of toxicants and concentration gradients to establish threshold responses and the full compliment of behaviours that could be useful in online biomonitoring.  相似文献   
9.
对波高百分比探伤方法的认识,本文将该方法的基本理论、标准规定波幅关系以及在超声探伤中该方法的技术做一概略介绍。  相似文献   
10.
电流探头分析设计   总被引:3,自引:0,他引:3  
分析了电流探头的两大技术指标,传输阻抗及传输阻抗宽频平坦度,并从电流探头物理结构模型出发,构建了电流探头的电路模型,推导出传输阻抗的计算公式,并从电路模型出发,分析了绕线电阻、端接电阻、分布电容对传输阻抗的影响。  相似文献   
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