Mechanism of complexation of toxic arsenate,selenate, and molybdate with hydrotalcites

Environmental Chemistry Letters - Wastewater from the uranium mining industry contains toxic arsenate (AsO43–), selenate (SeO42–), and molybdate (MoO42–) that can be removed by...     

气凝胶消防服隔热层研制的可行性分析

为了减少火焰环境对消防员的伤害,基于消防服隔热层对消防员生命安全保障的重要性,运用对比描述的方法对现有隔热层进行了分析比较,探究了其优缺点和性能,提出了轻质且具有优异隔热性能是隔热层的发展趋势,通过对气凝胶性能的理论分析和服用性能分析,研究了利用气凝胶材料研制消防服的隔热层,结果表明气凝胶在服装领域应用已经比较广泛,在消防服领域中也已有初步应用,但用气凝胶研制消防服隔热层仍存在着一定的挑战。     

Study on the measurement and the changing trend of the energy use of China’s economic sectors: based on cross-region input-output model

Environmental Science and Pollution Research - The consumption of fossil energy is the major cause of environmental pollution. Effectively reducing the fossil energy use has important significance...     

排污权交易之排放跟踪数据校核研究

本文以排污权交易的核心业务排放跟踪管理为出发点,选择电厂二氧化硫指标进行排放跟踪数据过程校核体系研究,探索进一步提高排污权交易体系中排放数据准确性的机制。     

探析循环经济的发展

发展循环经济是人类对经济发展模式反思后的必然选择,是走可持续发展之路的本质要求。文章简要阐述了中国三种经济模式的特点,并分别与生态系统做了比较;分析了中国循环经济存在的不足,提出了发展循环经济的正确途径和解决方法。     

葫芦岛有色金属集团废气治理对环境空气质量的影响

在研究分析葫芦岛有色金属集团近年来废气治理情况的基础上,根据葫芦岛市工业区环境空气质量监测数据,通过环境空气综合污染指数评价和Spearman秩相关系数评价,分析了废气治理对环境空气质量的影响.     

煤矿酸性矿井水的形成及主要处理技术

酸性矿井水是煤矿区环境地质灾害的一种重要类型。煤矿酸性矿井水是煤矿开采中由于硫铁矿与空气、水接触,在微生物作用下经过一系列地球化学反应产生的一种危害矿井生产、破坏生态环境的有害矿井排水。文章首先分析了酸性矿井水的形成机理,然后从酸性矿井水的危害入手,分析评价酸性矿井水各种处理方法的优缺点,并对酸性矿井水的处理技术进行总结,最后展望酸性矿井水处理的未来发展方向。     

厌氧系统中碱处理对污泥减量的影响

碱解预处理污泥和原污泥按一定比例进行混合后,投入厌氧反应器中进行消化,研究其对污泥减量化的影响。结果表明,该处理既可以提高污泥减量率,又能改善污泥厌氧消化性能,提高污泥产气量。当碱处理污泥和原污泥混合比为1∶3时,在混合初期由于稀释作用和水解中和作用,溶液的pH能迅速恢复到中性。SS减少48%,较对照组提高了10%;SCOD减少约80%,较对照组提高20%,而空白对照组因未发生溶胞作用,各参数值均处于较低水平,降解率也维持在较低水平。     

重金属在水体中的化学状态、危害及其防治对策

本文对目前研究最多的汞、铬、镉、铅和砷等重金属,详细分析了它们在水体中的迁移转化、价态变化、吸附与解吸附作用、吸附和共沉淀作用等动态过程;简要地阐述五种重金属对水体的污染给人体带来的危害;重点讨论了对水体重金属污染采取控制与消除土壤污染源、含重金属工业废水的排放和生物修复技术等防治对策。     

Removal of phosphate from wastewater using alkaline residue

Alkaline residue(AR) was found to be an efficient adsorbent for phosphate removal from wastewater. The kinetic and equilibrium of phosphate removal were investigated to evaluate the performance of modified alkaline residue. After treatment by NaOH(AR-NaOH), removal performance was significantly improved, while removal performance was almost completely lost after treatment by HCl(AR-HCl). The kinetics of the removal process by all adsorbents was well characterized by the pseudo second-order model. The Langmuir model exhibited the best correlation for AR-HCl, while AR was effectively described by Freundlich model. Both models were well fitted to AR-NaOH. The maximum adsorption capacities calculated from Langmuir equation were in following manner: AR-NaOH AR AR-HCl. Phosphate removal by alkaline residue was pH dependent process. Mechanisms for phosphate removal mainly involved adsorption and precipitation, varied with equilibrium pH of solution. For AR-HCl, the acid equilibrium pH( 6.0) was unfavorable for the formation of Ca-P precipitate, with adsorption as the key mechanism for phosphate removal. In contrast, for AR and ARNaOH, precipitation was the dominant mechanism for phosphate removal, due to the incrase on pH( 8.0) after phosphate removal. The results of both XRD and SEM analysis confirmed CaHPO4·2H2O formation after phosphate removal by AR and AR-NaOH.