采用1998~2013年卫星遥感影像反演的PM2.5全球高精度产品数据集,结合GIS空间分析、地理加权回归(GWR)以及地理探测器等方法,系统地分析了成渝城市群城市化与PM2.5分布之间的关系。结果表明:(1)1998~2013年成渝城市群城市化速度较快,城市区域的PM2.5均值明显高于非城市区域,说明城市化对PM2.5具有一定的影响;(2)近16 a PM2.5重心与城市重心整体上都向东南方向移动,且两者每年在经度上的波动方向基本相反;(3)夜间灯光数据与PM2.5在空间分布上具有较好的一致性,且1998~2013年两者的GWR全局R2在0.86~0.95之间,相关性显著,研究区内城市化和人类活动对PM2.5的分布具有明显影响;(4)地理探测分析表明不同城市化因子对PM2.5影响差异显著,从2006到2013年城区人口密度和建成区绿化覆盖率逐渐成为成渝城市群PM2.5分布的主要影响因子。 相似文献
Phthalates (PAEs) in drinking water sources such as the Yangtze River in developing countries had aroused widespread concern. Here, the water, suspended particulate matter (SPM), and sediment samples were collected from 15 sites in wet and dry seasons in Zhenjiang, for the determination of six PAEs (DMP, DEP, DIBP, DBP, DEHP, and DOP) using the solid-phase extraction (SPE) or ultrasonic extraction coupled with gas chromatography-mass spectrometry (GC-MS). The total concentrations of six PAEs (Σ6PAEs) spanned a range of 2.65–39.31 μg L?1 in water, 1.97–34.10 μg g?1 in SPM, and 0.93–34.70 μg g?1 in sediment. The partition coefficients (Kd1) of PAEs in water and SPM phase ranged from 0.004 to 3.36 L g?1 in the wet season and from 0.12 to 2.84 L g?1 in the dry season. Kd2 of PAEs in water and sediment phase was 0.001–9.75 L g?1 in the wet season and 0.006–8.05 L g?1 in the dry season. The dominant PAEs were DIBP, DBP, and DEHP in water and SPM, DIBP, DEHP, and DOP in sediment. The concentration of DBP in water exceeded the China Surface Water Standard. The discharge of domestic sewage and industrial wastewater might be the main potential sources of PAEs. The risk quotient (RQ) method used for the risk assessment revealed that DBP (0.01 < RQ < 1) posed a medium risk, while DIBP and DEHP (RQ > 1) posed a high environmental risk in water, DIBP (RQ > 1) also showed a high risk in sediment.