Role of sugarcane industrial byproducts on soil physicochemical properties and metal accumulation in rice

Environmental Science and Pollution Research - Sugar industry produces a variety of organic byproducts causing disposal as well as environmental issues. This study investigated the safe use of...     

Enzyme-based solutions for textile processing and dye contaminant biodegradation—a review

The textile industry, as recognized conformist and stake industry in the world’s economy, is facing serious environmental challenges. In numerous industries, in practice, various chemical-based processes from initial sizing to final washing are fascinating harsh environment concerns. Some of these chemicals are corrosive to equipment and cause serious damage itself. Therefore, in the twenty-first century, chemical and allied industries quest a paradigm transition from traditional chemical-based concepts to a greener, sustainable, and environmentally friendlier catalytic alternative, both at the laboratory and industrial scales. Bio-based catalysis offers numerous benefits in the context of biotechnological industry and environmental applications. In recent years, bio-based processing has received particular interest among the scientist for inter- and multi-disciplinary investigations in the areas of natural and engineering sciences for the application in biotechnology sector at large and textile industries in particular. Different enzymatic processes such as chemical substitution have been developed or in the process of development for various textile wet processes. In this context, the present review article summarizes current developments and highlights those areas where environment-friendly enzymatic textile processing might play an increasingly important role in the textile industry. In the first part of the review, a special focus has been given to a comparative discussion of the chemical-based “classical/conventional” treatments and the modern enzyme-based treatment processes. Some relevant information is also reported to identify the major research gaps to be worked out in future.     

From socioeconomic disparity to environmental injustice: the relationship between housing unit density and community green space in a medium city in Pakistan

Rapid urbanisation, lack of proactive planning and improper allocation of resources may result in socio-economic disparity among and within cities, causing social unrest and environmental injustice in the neighbourhoods. This study aims to examine whether the planning standards for housing schemes in Pakistan are able to maintain equitable access to green spaces within the cities. Ten residential sites in Sheikhupura city with different housing unit sizes and densities were selected for the study. The supply of urban green infrastructure in housing scheme has been assessed: (i) by comparing the percentage of green spaces, including community parks and open spaces and street landscape; and (ii) by calculating per dwelling unit and per capita share of green spaces. These indicators have been studied against the housing density and population density of the schemes by applying correlation and linear regression models. The results show that all the housing schemes plans provide for similar amounts of green space as a percentage of total area. The per capita share of green spaces is very low in high-density areas, but interestingly, the street landscape has a higher potential to contribute to the overall landscape in high-density neighbourhoods, compensating for low per capita green space. Housing unit density and population density must be incorporated in planning standards so planners can effectively devise a mix of community parks, street landscape and private green spaces to help maintain per capita green spaces, and hence environmental resource equality in different parts of the city.     

Visible-light-driven photocatalytic dual-layer hollow fibre membrane ameliorates the changes of bisphenol A exposure in gastrointestinal tract

Environmental Science and Pollution Research - Various treatments of choice are available to overcome contamination of bisphenol A (BPA) in the environment including membrane technologies; however,...     

Hydrous ferric oxide nanoparticles hosted porous polyethersulfone adsorptive membrane: chromium (VI) adsorptive studies and its applicability for water/wastewater treatment

In this present study, adsorptive membranes for Cr(VI) ion removal were prepared by blending polyethersulfone (PES) with hydrous ferric oxide (HFO) nanoparticles (NPs). The effects of HFO NPs to PES weight ratio (0–1.5) on the physicochemical properties of the resultant HFO/PES adsorptive membranes were investigated with respect to the surface chemistry and roughness as well as structural morphologies using different analytical instruments. The adsorptive performance of the HFO NPs/PES membranes was studied via batch adsorption experiments under various conditions by varying solution pH, initial concentration of Cr(VI), and contact time. The results showed that the membrane made of HFO/PES at a weight ratio of 1.0 exhibited the highest adsorption capacity which is 13.5 mg/g. Isotherm and kinetic studies revealed that the mechanism is best fitted to the Langmuir model and pseudo-second-order model. For filtration of Cr(VI), the best promising membranes showed improved water flux (629.3 L/m² h) with Cr(VI) ion removal of 75%. More importantly, the newly developed membrane maintained the Cr(VI) concentration below the maximum contamination level (MCL) for up to 9 h.

     

Growth and physiological response of spinach to various lithium concentrations in soil

Environmental Science and Pollution Research - Lithium (Li) exploitation for industrial and domestic use is resulting in a buildup of the element in various environmental components that results in...     

Using GIS tools to detect the land use/land cover changes during forty years in Lodhran District of Pakistan

Environmental Science and Pollution Research - Land use/land cover (LULC) change has serious implications for environment as LULC is directly related to land degradation over a period of time and...     

Environmental factors affecting the frequency of road traffic accidents: a case study of sub-urban area of Pakistan

Road traffic accidents (RTAs) are among the life-threatening issues facing rural as well as sub-/urban communities. Several factors contribute to RTAs ranging from human to technical and natural/environmental impacts. Anthropogenic air pollution and corresponding environmental factors also increase the probability of RTAs. Current study reports the relationship of the weather conditions to RTAs. The study establishes the relevancy of different weather conditions like rainfall, temperature, fog, and wind storm with the incidences of RTAs in rural and urban settings of Vehari, Punjab—Pakistan. The results of the study showed that rainfall, severe coldness, fog, and heat conditions were directly related with the occurrence of RTAs. The percentage of RTAs which occurred due to fog, rainfall, temperature, and other weather-related factors was 34, 25, 21, and 20%, respectively. The age of the driver significantly correlated (R²?=?0.60) with RTAs; the drivers in the age group 40–60 years caused the least RTAs during their drive. Since the smaller vehicles were involved in maximum RTAs, it relates negatively (R²?=?0.82) to vehicles power. Among different vehicles motor bikes were involved in most (42%) of the reported RTAs. Therefore, during severe weather conditions, vehicles with smaller size and young drivers must be dealt with carefully while interacting (crossing, overtaking, and maneuvering) on the roads regardless of rural or urban conditions. Factors including civic sense, traffic education, vehicle size, drivers’ maturity, road conditions, and environmental impacts may be considered while designing traffic rules and traffic aware campaigns specific for developing countries such as Pakistan.

     

Visible light photocatalytic water disinfection and its kinetics using Ag-doped titania nanoparticles

The UN estimated about five million deaths every year due to water-borne diseases, accounting from four billion patients. Keeping in view, the ever increasing health issues and to undermine this statistics, a reliable and sustainable water-treatment method has been developed using visible light for water treatment. titania nanoparticles (NPs) have been synthesized successfully by a more applicable method Viz: liquid impregnation (LI) method. The bacterial death rate by photocatalysis under visible light was studied by employing a typical fluorescent source and was found to follow pseudo first-order reaction kinetics. The nanoparticles were characterized using X-ray diffraction (XRD), scanning electron microscopy, and energy-dispersive X-ray spectroscopy to deduce their size range, surface morphology, and elemental compositions, respectively. Among all the prepared grades, 1 % Ag–TiO₂ was found to be a very effective photocatalytic agent against Escherichia coli. The resulted photoinactivated data were also evaluated by different empirical kinetic models for bacterial inactivation. Hom, Hom-power, Rational, and Selleck models were not able to explain the disinfection kinetics but modified-Hom model fitted best with the experimentally obtained data by producing a shoulder, log-linear, and a tail region.     

Graphene and its derivatives: synthesis,modifications, and applications in wastewater treatment

Graphene was discovered in 2004 and has attracted intensive interests because of its unique mechanical, electric, thermal, optical, and structural properties, which makes graphene a potential candidate for various applications. Graphene is being used as a composite or filler material with metals, metal oxides, and polymers for potential advanced applications in solar cells, lithium-ion batteries, photocatalysis and sensing. These applications depend upon the distinctive properties of graphene, which in turn depend on the adopted synthetic approach. This article reviews the recent developments in synthesis of graphene and related composite materials. The synthesis of graphene through exfoliation, epitaxial growth and direct growth via carbon source, and modification approaches by covalent and noncovalent methodologies are discussed. Graphene-based metal and metal oxide composites for the purification of wastewater using photolytic process are also presented.