全文获取类型
收费全文 | 4676篇 |
免费 | 866篇 |
国内免费 | 1589篇 |
专业分类
安全科学 | 734篇 |
废物处理 | 134篇 |
环保管理 | 380篇 |
综合类 | 3809篇 |
基础理论 | 706篇 |
污染及防治 | 497篇 |
评价与监测 | 390篇 |
社会与环境 | 265篇 |
灾害及防治 | 216篇 |
出版年
2024年 | 38篇 |
2023年 | 137篇 |
2022年 | 384篇 |
2021年 | 395篇 |
2020年 | 436篇 |
2019年 | 299篇 |
2018年 | 251篇 |
2017年 | 280篇 |
2016年 | 237篇 |
2015年 | 332篇 |
2014年 | 349篇 |
2013年 | 404篇 |
2012年 | 459篇 |
2011年 | 444篇 |
2010年 | 403篇 |
2009年 | 351篇 |
2008年 | 306篇 |
2007年 | 357篇 |
2006年 | 294篇 |
2005年 | 201篇 |
2004年 | 153篇 |
2003年 | 125篇 |
2002年 | 133篇 |
2001年 | 109篇 |
2000年 | 87篇 |
1999年 | 40篇 |
1998年 | 16篇 |
1997年 | 21篇 |
1996年 | 21篇 |
1995年 | 12篇 |
1994年 | 13篇 |
1993年 | 14篇 |
1992年 | 14篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有7131条查询结果,搜索用时 15 毫秒
1.
Liu Shun Jia Xu Xin Long 《Environmental science and pollution research international》2021,28(16):20157-20173
Environmental Science and Pollution Research - The existing literature on the environmental Kuznets curve (EKC) fails to investigate the spatial attribute of the “pollution halo” effect... 相似文献
2.
Liu Xin Li Shunlong 《Environmental science and pollution research international》2021,28(46):65200-65215
Environmental Science and Pollution Research - Growing environmental pressure urges China to develop in a sustainable and low carbon way, and thus China strives to achieve a carbon peak by 2030 and... 相似文献
3.
分析国内外生态环境科技创新的发展现状,相比较国外以市场机制为导向、以企业为创新主体、政府通过政策和管辖支撑创新的体系特征,我国已形成四大类环境类科创载体,但尚未形成成熟有效的技术成果产业化机制以及市场与政策协同促进科技创新的发展模式。本文根据生态环境科技创新的强政策驱动性、技术验证放大周期长以及集成性强的特点,重点通过环境技术研发、技术成果转化、技术放大与赋能、产业拓展与推广四个方面阐述了生态环境科技创新体系建设的主要环节:环境技术的研发由以科研机构为主的传统自发性研发、企业迭代性研发和联合应用型研发组成;技术成果的转化经历挖掘发现、技术识别与判断、知识产权评估评价后进入已成立的企业或新设公司,在这一过程中,成果转化专业队伍起着至关重要的作用;技术放大与赋能旨在为有创新技术的企业提供科技创新政策、二次研发中试验证、首台套工程案例、投融资等资源的对接,以协助初创企业成长;产业的拓展与推广则通过为解决环境问题形成集成方案、孵化平台为企业背书和产业政策匹配等方式助力企业长期发展。最后从加强专业化创新平台、技术评估体系、成果转化人才培养体系建设以及疏通投融资渠道等方面对中国未来生态环境科技创新发展提出相关建议。 相似文献
4.
Ling R. Zeng Li H. Shi Xin G. Meng J. Xu Gui F. Jia T. Gui 《Journal of environmental science and health. Part. B》2019,54(4):317-325
This study evaluated the hydrolysis and photolysis kinetics of pyraclostrobin in an aqueous solution using ultra-high-performance liquid chromatography–photodiode array detection and identified the resulting metabolites of pyraclostrobin by hydrolysis and photolysis in paddy water using high-resolution mass spectrometry coupled with liquid chromatography. The effect of solution pH, metal ions and surfactants on the hydrolysis of pyraclostrobin was explored. The hydrolysis half-lives of pyraclostrobin were 23.1–115.5?days and were stable in buffer solution at pH 5.0. The degradation rate of pyraclostrobin in an aqueous solution under sunlight was slower than that under UV photolysis reaction. The half-lives of pyraclostrobin in a buffer solution at pH 5.0, 7.0, 9.0 and in paddy water were less than 12?h under the two light irradiation types. The metabolites of the two processes were identified and compared to further understand the mechanisms underlying hydrolysis and photolysis of pyraclostrobin in natural water. The extracted ions obtained from paddy water were automatically annotated by Compound Discoverer software with manual confirmation of their fragments. Two metabolites were detected and identified in the pyraclostrobin hydrolysis, whereas three metabolites were detected and identified in the photolysis in paddy water. 相似文献
5.
以Ti3AlC2为原料,采用HF刻蚀工艺制备出12种Ti3C2纳米层状材料,对其形貌进行了表征,并考察了以其作为光催化剂对废水中Cr(Ⅵ)的处理效果。实验结果表明:HF体积分数为80%、刻蚀时间为48 h时得到的MX-80-48的形貌较好;MX-80-48具有类似石墨烯的二维层状结构,纳米层厚度约20~50 nm,孔径2~10 nm,比表面积14.8 m2/g,在400~700 nm可见光范围内表现出强烈的吸光性;当Cr(Ⅵ)的初始质量浓度为40.00 mg/L、MX-80-48投加量为200 mg/L、pH=2、反应时间4 h(暗反应1 h+光照3 h)时,Cr(Ⅵ)去除率可达100%。 相似文献
6.
建立了土壤和沉积物中8种多溴联苯醚(PBDEs,BDE-28、BDE-47、BDE-99、BDE-100、BDE-153、BDE-154、BDE-183和BDE-209)加速溶剂同时萃取和净化-气相色谱-三重四极杆串联质谱(ASE-GC-MS-MS)的分析方法。通过优化加速溶剂萃取与弗罗里硅土在线净化和串联质谱多反应监测模式的条件,较好地去除基质干扰,并提高了三重四极杆串联质谱定性的准确性及定量的灵敏性。该方法采用改进的色谱柱能同时分析包括高溴代联苯醚BDE-209在内的8种PBDEs,其浓度范围为1~100 ng/mL(BDE-209为10~1 000 ng/mL),线性良好,线性回归系数均大于0.997。方法检出限为0.004~0.1 ng/g,方法回收率为75%~110%,方法精密度为2.4%~15.6%。适于批量处理土壤和沉积物中含有多组分痕量PBDEs的样品。 相似文献
7.
Guochen Zhang Xin Zhao Danni Yang Xia Jiang Wenju Jiang 《Journal of the Air & Waste Management Association (1995)》2018,68(9):958-968
In this study, MnO2 and pyrolusite were used as the catalysts to prepare modified activated carbon, that is, AC-Mn and AC-P, respectively, from coals by blending method and steam activation. The Brunauer–Emmett–Teller (BET) results indicated that the AC-P had higher surface areas and micropore volumes than the AC-Mn with the same blending ratio. The relative contents of basic functional groups (i.e., C = O, π-π*) on AC-P were slightly lower than those on AC-Mn, while both contained the same main metal species, namely, MnO. The desulfurization results showed that with 3 wt% of blending ratio, AC-Mn3 and AC-P3 had higher sulfur capacities at 220 and 205 mg/g, respectively, which were much higher than for the blank one (149.6 mg/g). Moreover, the AC-P had relatively higher sulfur capacity than the AC-Mn with the same contents of Mn, which might be attributed to the existence of other metals in pyrolusite. After the desulfurization process, MnO were gradually transferred into MnSO4, and the relative contents of basic functional groups decreased evidently for both AC-Mn3 and AC-P3. The results demonstrated that pyrolusite could be one good alternative to MnO2 to prepare modified activated carbon for desulfurization.
Implications: MnO2 and pyrolusite were used as the additives to prepare modified activated carbon from coals by a blending method and by steam activation, that is, AC-Mn and AC-P, respectively. The AC-P had higher surface areas and micropore volumes than the AC-Mn with the same blending ratio. The AC-Mn and AC-P had higher sulfur capacities than a blank one. Moreover, the AC-P had relatively higher sulfur capacity than the AC-Mn with the same contents of Mn. The results demonstrated that pyrolusite could be one good alternative to MnO2 to prepare modified activated carbon for desulfurizatio. 相似文献
8.
为了解石家庄市2016年春季大气颗粒物的铅污染特征及来源,利用单颗粒气溶胶质谱仪(SPAMS),分析了大气中含铅颗粒的化学成分。结果表明: 研究期间大气环境中含铅颗粒数浓度共出现11次跳跃式升高,跳跃时间段内石家庄均处于轻度污染过程。从成分分析来看,含铅颗粒分为纯铅颗粒、Pb与K(Pb-K)、OC(Pb-OC)、Cl(Pb-Cl)、混合颗粒等八大类。观测结果表明:Pb-K颗粒最多,占到含铅颗粒的84.4%;其次为纯铅颗粒,占比为13.0%。与石家庄市污染源谱库比对进行来源解析,得到Pb-K颗粒主要来自生活垃圾焚烧源, 纯铅颗粒主要来自工业源。结合石家庄市大气污染源排放清单和后向气流轨迹分析,推测含铅颗粒可能来自市区西南方向某区县的生活垃圾焚烧企业。 相似文献
9.
Fu Li Chen Yi Yang Xinyi Yang Zuyao Liu Sha Pei Lei Feng Baixiang Cao Ganxiang Liu Xin Lin Hualiang Li Xing Ye Yufeng Zhang Bo Sun Jiufeng Xu Xiaojun Liu Tao Ma Wenjun 《Environmental science and pollution research international》2019,26(20):20137-20147
Environmental Science and Pollution Research - Fetal growth has been demonstrated to be an important predictor of perinatal and postnatal health. Although the effects of maternal exposure to air... 相似文献
10.