Male reproductive toxicity involved in spermatogenesis induced by perfluorooctane sulfonate and perfluorooctanoic acid in Caenorhabditis elegans

Environmental Science and Pollution Research - As a persistent organic pollutant, perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) have gained increasing research attention over...     

氨三乙酸酐改性纤维素对Cd~(2+)的吸附性能

本实验采用氨三乙酸酐改性玉米秸秆纤维素和苎麻纤维素,制备了两种改性纤维素吸附剂NTAA-CS及NTAA-RF,并研究了这两种吸附剂对水中Cd2+的吸附性能.通过元素分析、FTIR及SEM分析发现,纤维材料表面成功引入了氨三乙酸分子中的酯键和氨基基团.在改性纤维素吸附剂投加量为2 g·L-1,Cd2+的初始浓度为200 mg·L-1,p H值为4.0时,NTAA-CS和NTAA-RF对Cd2+的去除率分别为82.6%和90.2%.吸附实验结果表明:改性纤维素吸附剂对Cd2+的吸附是一个快速过程,吸附的最佳p H范围为4.0~7.0.吸附等温线用Langmuir方程的拟合效果优于Freundlich方程.经过5次吸附再生,吸附剂仍可以保持较大的吸附容量.这些结果表明,NTAA-CS和NTAA-RF在去除重金属废水中有较大的应用前景.     

Transformation of hazardous lead into aluminosilicate ceramics: structure evolution and lead leaching

This study investigated crystallization mechanisms for the formation of lead aluminosilicate by sintering lead stabilization with kaolin-based precursors. PbAl2Si2O8 was found to be the only stable lead aluminosilicate in low-PbO system and demonstrates its highly intrinsic resistance to acid attack in leaching test. A three-stage PbAl2Si2O8 formation mechanism was supported by the results of the changing temperature in the system. Amorphization of sintered products was observed in both PbO/kaolinite and PbO/mullite systems at 600–700°C. When the temperature was increased to 750–900°C, the crystallochemical formation of lead aluminosilicates (i.e., Pb4Al4Si3O16, Pb6Al6Si2O21, and PbAl2Si2O8) was observed. Pb4Al4Si3O16 and Pb6Al6Si2O21 were found to be the intermediate phases at 700–900°C. Finally, PbAl2Si2O8 was found to be the only crystallite phase to host Pb at above 950°C. A maximum of 80% and 96.7% Pb can be incorporated into PbAl2Si2O8 in PbO/kaolinite and PbO/mullite systems, respectively, but the final products exhibited different microstructures. To reduce environmental hazard of lead, this strategy demonstrated a preferred mechanism of immobilizing lead into PbAl2Si2O8 structure via kaolin-based precursors.     

2013年春夏季莱州湾海水环境要素特征和富营养化评估

根据2013年5（春季）、8月（夏季）莱州湾海水环境要素的调查资料，采用富营养化指数、潜在性富营养化评价模式和灰色聚类分析方法研究环境要素特征和评估海水富营养化状况。结果表明，无机氮是莱州湾水质的主要污染要素，春夏季的N/P平均值分别为100.76、117.84，潜在性富营养化评价模式结果表明，春夏季各站位的营养级均只包括Ⅳ_P、Ⅵ_P两类，磷限制为莱州湾的营养盐结构特征；富营养化指数评价结果表明，春季和夏季E>1站位比例分别为65%、20%；灰色聚类分析结果表明，春季Ⅱ级、Ⅲ级的站位比例分别为95%、5%，夏季Ⅱ、Ⅲ级的站位比例分别为70%、25%，Ⅱ级中的部分站位具有较大潜在富营养化风险。     

切割砂浆回收工业废水处理絮凝沉淀装置研究及应用

絮凝沉淀装置是工业废水处理过程中用于去除水体中固体悬浮物的装置,论述了目前絮凝沉淀装置的主要种类以及特点,分析了絮凝沉淀装置处理切割砂浆工业废水时存在的主要问题,提出了解决措施,设计了一种新型絮凝沉淀装置,并对其工业应用进行了探讨.     

南京市饮用水源地抗生素污染特征及风险评估

采用固相萃取-液相色谱-串联质谱技术（SPE-HPLC-MS/MS）,对南京市饮用水源地抗生素含量及分布特征进行了分析.结果表明,17个采样点总浓度为0.56~1994.96 ng·L^-1,共检出5种大环内酯类、13种磺胺类、3种四环素类、8种喹诺酮类抗生素,平均浓度为0.30~37.07 ng·L^-1,其中检出浓度最高的抗生素为环丙沙星（CIP）,浓度为317.60 ng·L^-1,检出率最高的抗生素为克林霉素（CLI）,检出率为88.24%.与国内部分河流相比,南京市饮用水源地水体中大环内酯类、四环素类、喹诺酮类抗生素残留浓度处于较高水平.生态风险评估结果表明,点位S7具有最高的联合风险熵值（24.58）,氧氟沙星（OFX）的风险熵值最高,达到13.06;健康风险评估结果表明,9种抗生素对人体健康的风险熵Q_H为1.70×10^-3~9.47,强力霉素（DOX）、诺氟沙星（NOR）、恩诺沙星（ERX）、CIP和OFX对大部分年龄段的人体健康具有高水平风险.     

Integration of chemical and biological methods: A case study of polycyclic aromatic hydrocarbons pollution monitoring in Shandong Peninsula, China

Polycyclic aromatic hydrocarbons(PAHs), as persistent toxic substances(PTS), have been widely monitored in coastal environment, including seawater and sediment. However, scientific monitoring methods, like ecological risk assessment and integrated biomarker response, still need massive researches to verify their availabilities. This study was performed in March, May, August and October of 2018 at eight sites, Yellow River estuary(S1), Guangli Port(S2), Xiaying(S3), Laizhou(S4), Inner Bay(S5), Ou...     

我为故乡的大开发站岗

“手握一杆钢枪,身披万道霞光,我守卫在边防线上,为我们伟大祖国站岗……”我时常唱起这首激情昂扬的哨兵之歌。我是一名地震工作者,20多年如一日,常年值班在地震台站的机房,是保卫祖国建设和人民生命财产安全的防震减灾方队中的普通一兵。     

自贡地震监测设施屡遭破坏

地处四川东南部的自贡市是一个拥有近300万人口的中等工业城市,所处的地理位置又是一个中强震多发地区,无论历史上,还是今天,也无论是自贡的周边地区,还是城市的脚下,都遭受过一些中强地震的袭击。为了监测预防地震,搞好防震减灾工作,省市政府在经济并不宽裕的情况下,投人大量资金,建设了一些地震监测设施和自贡无线遥测地震台网。