全文获取类型
收费全文 | 707篇 |
免费 | 13篇 |
国内免费 | 84篇 |
专业分类
安全科学 | 43篇 |
废物处理 | 22篇 |
环保管理 | 156篇 |
综合类 | 268篇 |
基础理论 | 130篇 |
环境理论 | 1篇 |
污染及防治 | 117篇 |
评价与监测 | 32篇 |
社会与环境 | 35篇 |
出版年
2023年 | 21篇 |
2022年 | 19篇 |
2021年 | 12篇 |
2020年 | 14篇 |
2019年 | 24篇 |
2018年 | 14篇 |
2017年 | 22篇 |
2016年 | 36篇 |
2015年 | 41篇 |
2014年 | 39篇 |
2013年 | 42篇 |
2012年 | 25篇 |
2011年 | 90篇 |
2010年 | 38篇 |
2009年 | 60篇 |
2008年 | 66篇 |
2007年 | 65篇 |
2006年 | 22篇 |
2005年 | 24篇 |
2004年 | 16篇 |
2003年 | 15篇 |
2002年 | 13篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1999年 | 4篇 |
1998年 | 15篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1978年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有804条查询结果,搜索用时 31 毫秒
1.
Shu-Yii Wu Yong-Fang Liu Ya-Chieh Li Chun-Min Liu 《International Journal of Green Energy》2015,12(10):1025-1030
The CO2 absorption capacities of potassium glycinate, potassium sarcosinate (choline, proline), mono-ethanolamine (MEA), and tri-ethanolamine were evaluated to find the optimal absorbent for separating CO2 from gaseous products by a CO2 purification process. The absorption loading, desorption efficiency, cost, and environmental tolerance were assessed to select the optimal absorbent. MEA was found to be the optimum absorbent for separating the CO2 and H2 mixture in gaseous product. The maximum absorption loading rate was 0.77 mol CO2 per mol MEA at temperature of 20°C and absorbent concentration of 2.5 mol/L, whereas desorption efficiency was 90% by heating for 3 h at 130°C. MEA was found to be an optimal absorbent for the purification process of CO2 during gaseous production. 相似文献
2.
Carbon coated monolith was prepared by sucrose solution 65 wt.% via dip-coating method. Sulfonation of incomplete carbonized carbon coated monolith was carried out in order to synthesize solid acid catalyst. The textural structure characteristics of the solid acid catalyst demonstrated a low surface area and pore volume. Palm fatty acid distillate (PFAD), a by-product of palm oil refineries, was utilized as oil source in biodiesel production. The esterification reaction subjected to different reaction conditions was performed by using the sulfonated carbon coated monolith as heterogeneous catalyst. The sulfonation process had been performed by using vapour of concentrated H2SO4 that was much easier and efficient than liquid phase sulfonation. Total acidity value of carbon coated monolith was measured for unsulfonated sample (0.5 mmol/g) and sulfonated sample (4.2 mmol/g). The effect of methanol/oil ratio, catalyst amount and reaction time were examined. The maximum methyl ester content was 89% at the optimum condition, i.e. methanol/oil molar ratio (15:1), catalyst amount (2.5 wt.% with respect to PFAD), reaction time (240 min) and temperature 80 °C. The sugar catalyst supported on the honeycomb monolith showed comparable reactivity compared with the sugar catalyst powder. However, the catalyst reusability studies showed decrease in FFA% conversion from 95.3% to 68.8% after four cycles as well as the total acidity of catalyst dropped from the value 4.2 to 3.1 mmol/g during these cycles. This might be likely due to the leaching out of SO3H group from the sulfonated carbon coated monolith surface. The leaching of active species reached a plateau state after fourth cycle. 相似文献
3.
王睿彤 《铁路节能环保与安全卫生》2020,(2):28-32
在概述国际和国内碳交易市场发展现状的基础上,从企业获取碳资产途径及开展碳交易基础方面分析企业碳资产开发。探讨铁路企业开展碳资产项目的必要性和可行性,认为国内统一碳市场发展为铁路开发碳资产创造条件、铁路系统具有巨大的碳资产开发潜力、铁路系统相关碳资产开发方法学已较为成熟、改革为铁路碳资产开发提供助力、技术革新为铁路碳资产开发提供支持,进而提出铁路企业开发碳资产项目需解决的问题及建议。 相似文献
4.
林业是重要的碳汇资源,在减缓全球气候变化、改善自然生态环境、促进经济可持续发展等方面有着至关重要的作用。作为林业碳汇的重要实现形式,碳汇造林项目兼具生态保护、促进经济发展与贫困减缓等重要功能,其实施成效究竟如何需要进一步验证。为此,本文从理论上分析了碳汇造林项目对县域经济发展的影响机理,利用2000—2016年四川47个县域的面板数据,采用PSM-DID模型估计了碳汇造林项目对县域经济发展的平均效应和动态效应,并对其影响机理进行了验证。结果显示:①碳汇造林项目的实施显著地促进了地区实际GDP和人均实际GDP的增长,这一结论在进行稳健性检验后依然成立;②囿于项目周期较长,此促进作用在短期内尚不能立竿见影,具有明显的滞后效应,且实施的时间越长,对当地经济发展的促进作用越大;③碳汇造林项目主要通过优化当地产业结构、提高居民储蓄率、提升地区政府财政收支水平等途径促进当地经济发展。因此,为更好地发挥碳汇造林项目对县域经济发展的促进作用,应继续拓展碳汇造林项目的覆盖区域,加大专项投资力度,引导碳汇造林项目向生态脆弱的深度贫困地区倾斜;在更加注重碳汇造林项目的长期效应的同时,应建立完善项目运行的长效稳定机制,防范潜在的自然与市场风险,保障项目对地区经济发展的长期驱动力;加快改善地区的融资环境,鼓励居民和企业将储蓄和融资能力有效转化为投资能力,充分依托碳汇造林项目促进当地经济可持续发展。 相似文献
5.
制药废水组成复杂,污染物浓度高,污水CODcr浓度达10000mg/l,含有大量有毒、有害物质。本中采用催化氧化预处理+水解酸化+UASB+接触氧化+炭滤吸附的工艺流程,通过改善细部参数及改良配套设备设计,提高了各单元去除效率,降低了能耗及处理成本,出水CODcr浓度达到污水综合排放标准. 相似文献
6.
水泥行业二氧化碳排放统计——以贵阳市为例 总被引:1,自引:1,他引:0
本文从水泥行业二氧化碳的排放统计出发,研究二氧化碳排放的重要影响因素、二氧化碳排放的指标体系,从而得出一套水泥行业二氧化碳排放统计的核算方法.以贵阳市为例,从三种不同活动水平的统计数据对水泥行业生产工艺过程中产生的CO2排放量进行估算比较,验证统计核算方法的有效性,为贵阳市乃至全国水泥行业CO2的减排提供一个可行的科学依据. 相似文献
7.
8.
9.
This paper examines the energy and carbon balance of two residential house alternatives; a typical wood frame home using more conventional materials (brick cladding, vinyl windows, asphalt shingles, and fibreglass insulation) and a similar wood frame house that also maximizes wood use throughout (cedar shingles and siding, wood windows, and cellulose insulation) in place of the more typical materials used – a wood-intensive house. Carbon emission and fossil fuel consumption balances were established for the two homes based on the cumulative total of three subsystems: (1) forest harvesting and regeneration; (2) cradle-to-gate product manufacturing, construction, and replacement effects over a 100-year service life; and (3) end-of-life effects – landfilling with methane capture and combustion or recovery of biomass for energy production.The net carbon balance of the wood-intensive house showed a complete offset of the manufacturing emissions by the credit given to the system for forest re-growth. Including landfill methane emissions, the wood-intensive life cycle yielded 20 tons of CO2e emissions compared to 72 tons for the typical house. The wood-intensive home's life cycle also consumed only 45% of the fossil fuels used in the typical house.Diverting wood materials from the landfill at the end of life improved the life cycle balances of both the typical and wood-intensive houses. The carbon balance of the wood-intensive house was 5.2 tons of CO2e permanently removed from the atmosphere (a net carbon sink) as compared to 63.4 of total CO2e emissions for the typical house. Substitution of wood fuel for natural gas and coal in electricity production led to a net energy balance of the wood-intensive house that was nearly neutral, 87.1 GJ energy use, 88% lower than the scenario in which the materials were landfilled.Allocating biomass generation and carbon sequestration in the forest on an economic basis as opposed to a mass basis significantly improves the life cycle balances of both houses. Employing an economic allocation method to the forest leads to 3–5 times greater carbon sequestration and fossil fuel substitution attributable to the house, which is doubled in forestry regimes that remove stumps and slash as fuel. Thus, wood use has the potential to create a significantly negative carbon footprint for a house up to the point of occupancy and even offset a portion of heating and cooling energy use and carbon emissions; the wood-intensive house is energy and carbon neutral for 34–68 years in Ottawa and has the potential to be a net carbon sink and energy producer in a more temperate climate like San Francisco. 相似文献
10.
运用静态箱-预浓缩-气相色谱-质谱法和静态箱-色谱法分别测量了南亚热带鼎湖山针阔叶混交林土壤-大气COS和CO2通量。结果表明,土壤吸收COS,凋落物保留样地COS吸收速率显著高于凋落物去除样地,3月土壤COS吸收速率最高。土壤COS吸收速率与大气COS浓度正相关。土壤COS吸收速率与土壤温度、土壤含水量单独未表现出显著相关性,但凋落物保留样地COS吸收速率与土壤温度和含水量两者共同呈二次多项式相关。凋落物保留样地CO2释放速率高于凋落物去除样地。与土壤COS吸收速率相反,土壤CO2释放速率3月最低,7月最高,主要受温度和土壤含水量的影响。土壤CO2释放速率与土壤温度呈指数相关,与土壤含水量直线相关,多元回归分析表明,土壤CO2释放受温度和含水量的共同影响。土壤COS吸收速率随土壤CO2释放速率的增加而增加,表明两者可能受某些共同因素的影响。 相似文献